摘要:
Pyrogenically prepared, doped zinc oxide powder, wherein the doping component comprises at least one oxide from the group aluminum, gallium, indium, germanium, tin and is present in the doped zinc oxide powder in an amount of from 0.005 to 15 wt. %, and wherein the doped zinc oxide powder is in the form of aggregates of primary particles having a mean maximum diameter of from 30 to 400 nm. It is prepared by oxidation from zinc powder and at least one doping agent, wherein the process zones vaporisation, nucleation, oxidation and quenching are passed through and the doping agent is metered in in the nucleation zone, in which the temperature is below the boiling temperature of zinc. The doped zinc oxide powder can be used in electrically conductive lacquers and coatings.
摘要:
Pyrogenically prepared, doped zinc oxide powder, wherein the doping component comprises at least one oxide from the group aluminum, gallium, indium, germanium, tin and is present in the doped zinc oxide powder in an amount of from 0.005 to 15 wt. %, and wherein the doped zinc oxide powder is in the form of aggregates of primary particles having a mean maximum diameter of from 30 to 400 nm. It is prepared by oxidation from zinc powder and at least one doping agent, wherein the process zones vaporisation, nucleation, oxidation and quenching are passed through and the doping agent is metered in in the nucleation zone, in which the temperature is below the boiling temperature of zinc. The doped zinc oxide powder can be used in electrically conductive lacquers and coatings.
摘要:
Mixed oxide powder containing indium and tin, with a proportion of indium oxide of between 90 and 98 wt. % and a BET surface area of 40 to 120 m2/g, which is in the form of aggregates having an average circumference of less than 500 nm, consists of at least 95% of an indium oxide phase and displays an oxygen content that is lower than the content that theoretically results from In2O3 and SnO2. It is produced by mixing a solution of an indium compound with a solution of a tin compound, atomising this mixture of solutions, pyrolysing the atomised mixture of solutions in a first zone of a reactor and in a second zone of the reactor, following pyrolysis, adding reducing gases to the pyrolysed mixture at one or more points in a quantity such that overall a reducing atmosphere is established in this second zone, and separating the resulting solid from the waste gases in a further, third zone, in which a reducing atmosphere likewise still prevails. It can be used for the production of transparent, electroconductive paints and coatings.
摘要:
Mixed oxide powder containing indium and tin, with a proportion of indium oxide of between 90 and 98 wt. % and a BET surface area of 40 to 120 m2/g, which is in the form of aggregates having an average circumference of less than 500 nm, consists of at least 95% of an indium oxide phase and displays an oxygen content that is lower than the content that theoretically results from In2O3 and SnO2. It is produced by mixing a solution of an indium compound with a solution of a tin compound, atomising this mixture of solutions, pyrolysing the atomised mixture of solutions in a first zone of a reactor and in a second zone of the reactor, following pyrolysis, adding reducing gases to the pyrolysed mixture at one or more points in a quantity such that overall a reducing atmosphere is established in this second zone, and separating the resulting solid from the waste gases in a further, third zone, in which a reducing atmosphere likewise still prevails. It can be used for the production of transparent, electroconductive paints and coatings.
摘要:
Nanoscale, pyrogenically produced zinc oxide having a BET surface area of 10 to 200 m2/g, which is in the form of aggregates of anisotropic primary particles and whereby the aggregates display an average diameter of 50 to 300 nm. It is obtained from zinc powder, which is converted to zinc oxide powder in the four successive reaction zones, evaporation zone, nucleation zone, oxidation zone and quench zone. It can be used in sunscreen formulations.
摘要:
Zinc silicon oxide particles with a core-shell structure which have a Zn/Si ratio of from 2 to 75, in atom %/atom %, whose fraction of Zn, Si and O is at least 99% by weight, based on the zinc silicon oxide particles, which have a BET surface area of from 10 to 60 m2/g, a weight-averaged primary particle diameter of from 10 to 75 nm an average aggregate area of less than 40 000 nm2 and an average aggregate diameter (ECD) of less than 200 nm, whose core is crystalline and consists of aggregated primary particles of zinc oxide and whose shell surrounds the aggregated zinc oxide primary particles and consists of one or more compounds containing the elements Si and O. Dispersion, coating composition and sunscreen formulation comprise the zinc silicon oxide particles.
摘要:
Process for preparing a mixed metal oxide powder, in which oxidizable starting materials are evaporated and oxidized, the reaction mixture is cooled after the reaction and the pulverulent solids are removed from gaseous substances, wherein as starting materials, at least one pulverulent metal and at least one metal compound, the metal and the metal component of the metal compound being different and the proportion of metal being at least 80% by weight based on the sum of metal and metal component from metal compound, together with one or more combustion gases, are fed to an evaporation zone of a reactor, where metal and metal compound are evaporated completely under nonoxidizing conditions, subsequently, the mixture flowing out of the evaporation zone is reacted in the oxidation zone of this reactor with a stream of a supplied oxygen-containing gas whose oxygen content is at least sufficient to oxidize the starting materials and combustion gases completely.
摘要:
Process for preparing a mixed metal oxide powder, in which oxidizable starting materials are evaporated and oxidized, the reaction mixture is cooled after the reaction and the pulverulent solids are removed from gaseous substances, wherein as starting materials, at least one pulverulent metal and at least one metal compound, the metal and the metal component of the metal compound being different and the proportion of metal being at least 80% by weight based on the sum of metal and metal component from metal compound, together with one or more combustion gases, are fed to an evaporation zone of a reactor, where metal and metal compound are evaporated completely under nonoxidizing conditions, subsequently, the mixture flowing out of the evaporation zone is reacted in the oxidation zone of this reactor with a stream of a supplied oxygen-containing gas whose oxygen content is at least sufficient to oxidize the starting materials and combustion gases completely.
摘要:
Process for preparing a metal oxide powder, in which starting materials are evaporated and oxidized, wherein a metal melt in the form of droplets and one or more combustion gases are fed to the evaporation zone of a reactor, where the metal melt is evaporated completely under nonoxidizing conditions, subsequently, the mixture flowing out of the evaporation zone is reacted in the oxidation zone of this reactor with a stream of a supplied oxygen-containing gas whose oxygen content is at least sufficient to oxidize the metal and the combustion gases completely.
摘要:
Pyrogenically prepared zinc oxide powder having a BET surface area of from 10 to 200 m2/g, which is in the form of aggregates, the aggregates being composed of particles having different morphologies, and 0-10% of the aggregates being in a circular form, 30-50% being in an ellipsoidal form, 30-50% being in a linear form and 20-30% being in a branched form. It is prepared by reacting a starting mixture containing zinc vapour, a combustible gas and steam or a mixture of steam and carbon dioxide in a flame with an oxygen-containing gas in an oxidation zone, cooling the hot reaction mixture in a quenching zone and separating the solid material from the gas stream, the amount of oxygen in the oxidation zone being greater than the amount necessary for the complete oxidation of the combustible gas and the zinc vapour. The zinc oxide powder can be used as a constituent of sun protection compositions for protection against UV radiation.