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29 条记录 (耗时 0.053 秒)

    Process for preparing diesters of dicarboxylic acids
    3.
    发明授权
    Process for preparing diesters of dicarboxylic acids 失效
    二羧酸二酯的制备方法

    公开(公告)号：US4138580A

    公开(公告)日：1979-02-06

    申请号：US837850

    申请日：1977-09-29

    申请人： Sumio Umemura ,  Kanenobu Matsui ,  Yoshinari Ikeda ,  Katsuro Masunaga

    发明人： Sumio Umemura ,  Kanenobu Matsui ,  Yoshinari Ikeda ,  Katsuro Masunaga

    IPC分类号： C07C67/38 ,  C07C69/34

    CPC分类号： C07C67/38 ,  C07C2101/14

    摘要： A process for preparing a diester of a dicarboxylic acid having two more carbon atoms than the unsaturated hydrocarbon used as a starting material, which comprises subjecting an unsaturated hydrocarbon, carbon monoxide and an alcohol to reaction in the presence of a platinum group metal in combination with one or more compounds selected from the group consisting of nitric acid, a nitrogen oxide and an ester of nitrous acid.

    摘要翻译： 一种制备具有比用作原料的不饱和烃多两个碳原子的二羧酸的二酯的方法，该方法包括使不饱和烃，一氧化碳和醇在铂族金属存在下反应，结合 一种或多种选自硝酸，氮氧化物和亚硝酸酯的化合物。

    Process for preparing aliphatic monocarboxylic acid ester of hydroxymethyl-substituted monoaromatic compound
    5.
    发明授权
    Process for preparing aliphatic monocarboxylic acid ester of hydroxymethyl-substituted monoaromatic compound 失效
    制备羟甲基取代的单芳族化合物的脂族一元羧酸酯的方法

    公开(公告)号：US4224456A

    公开(公告)日：1980-09-23

    申请号：US908732

    申请日：1978-05-23

    申请人： Sumio Umemura ,  Kanenobu Matsui ,  Kunitoshi Koga ,  Mineo Kuniyoshi

    发明人： Sumio Umemura ,  Kanenobu Matsui ,  Kunitoshi Koga ,  Mineo Kuniyoshi

    IPC分类号： C07C69/035 ,  B01J23/00 ,  C07B61/00 ,  C07C69/025 ,  C07C69/12 ,  C07C69/157 ,  C07C67/05

    CPC分类号： C07C67/035

    摘要： Disclosed is a vapor phase catalytic oxidation process for preparing an aliphatic carboxylic acid ester of a monoaromatic compound having 1 to 2 hydroxymethyl substituents, such as benzyl acetate, p-methylbenzyl acetate, p-xylylenediacetate, benzyl propionate and benzyl butyrate. A gaseous feed comprised of a benzene compound having 1 to 2 methyl substituents, an aliphatic monocarboxylic acid having 2 to 4 carbon atoms and molecular oxygen is contacted with an improved catalyst. The metal ingredients of the catalyst consist essentially of (a) palladium, (b) arsenic and (c) at least one metal selected from alkali metals and alkali earth metals, and the atomic ratio of palladium:arsenic:the alkali or alkali earth metal is 1:0.05-4:0.1-10.

    摘要翻译： 公开了一种用于制备具有1至2个羟甲基取代基的单芳族化合物的脂肪族羧酸酯的气相催化氧化方法，例如乙酸苄酯，乙酸对甲基苄酯，对二甲苯基二乙酸酯，丙酸苄酯和丁酸苄酯。 由具有1至2个甲基取代基的苯化合物，具有2至4个碳原子的脂族单羧酸和分子氧组成的气态进料与改进的催化剂接触。 催化剂的金属成分基本上由（a）钯，（b）砷和（c）至少一种选自碱金属和碱土金属的金属，钯：砷的原子比：碱金属或碱土金属 为1：0.05-4：0.1-10。

    Process for preparing phenol
    6.
    发明授权
    Process for preparing phenol 失效
    酚的制备方法

    公开(公告)号：US4338471A

    公开(公告)日：1982-07-06

    申请号：US217116

    申请日：1980-12-17

    申请人： Sumio Umemura ,  Ryozo Kitoh ,  Taizo Uda

    发明人： Sumio Umemura ,  Ryozo Kitoh ,  Taizo Uda

    IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J23/50 ,  B01J23/66 ,  B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C27/00 ,  C07C37/58 ,  C07C39/04 ,  C07C67/00

    CPC分类号： C07C37/58 ,  B01J23/50 ,  B01J23/66 ,  B01J27/1817 ,  Y02P20/52

    摘要： Benzene is catalytically oxidized in the vapor phase with oxygen in the presence of an alcohol to be converted to phenol. The catalyst used is represented by the formula: M.sub.a Ag.sub.b P.sub.c O.sub.d wherein M is selected from zinc, titanium, zirconium, tin, bismuth and vanadium, Ag is silver, P is phosphorus and O is oxygen, and a=1, b=0.005.about.5 and c=0 to 6. Phenol is obtained at an enhanced yield even though the catalytic oxidation is carried out at a relatively low temperature as compared with conventional catalytic oxidation processes.

    摘要翻译： 苯在气相中用醇在醇的存在下催化氧化以转化成苯酚。 所用的催化剂由下式表示：MaAgbPcOd其中M选自锌，钛，锆，锡，铋和钒，Ag是银，P是磷，O是氧，a = 1，b = 0.005，DIFFERENCE 5和 c = 0〜6。与常规催化氧化方法相比，即使催化氧化在相对低的温度下进行，也以提高的产率获得酚。

    Ammoxidation catalyst for the production of acrylonitrile from propylene and process for producing the same
    7.
    发明授权
    Ammoxidation catalyst for the production of acrylonitrile from propylene and process for producing the same 失效
    用于从丙烯生产丙烯腈的氨氧化催化剂及其制备方法

    公开(公告)号：US4290922A

    公开(公告)日：1981-09-22

    申请号：US134053

    申请日：1980-03-26

    申请人： Sumio Umemura ,  Kyoji Ohdan ,  Mikio Hidaka ,  Toshio Kurafuji

    发明人： Sumio Umemura ,  Kyoji Ohdan ,  Mikio Hidaka ,  Toshio Kurafuji

    IPC分类号： B01J23/88 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J21/06 ,  B01J23/24

    CPC分类号： B01J23/8872 ,  B01J23/8876 ,  B01J23/8877 ,  B01J23/8878 ,  C07C253/26 ,  Y02P20/52

    摘要： A catalyst for the ammoxidation of propylene to prepare acrylonitrile with a high yield thereof comprising an oxide composition of the empirical formula (I)Mo.sub.a Co.sub.b Ni.sub.c Fe.sub.d Bi.sub.e V.sub.f Ca.sub.g K.sub.h X.sub.i Si.sub.j O.sub.k (I)wherein X is zirconium and/or chromium, the subscripts a, b, c, d, e, f, g, h, i and j respectively denote the number of the respective atoms of the elements, when a=10, b=0 to 8, c=0 to 8, (b+c)=2 to 10, d=0.3 to 7, e=0.01 to 3, f=0.01 to 2, g=0.01 to 5, h=0.05 to 0.5, i=0 to 2, j=10 to 50, and the subscript k denotes the number of oxygen atoms which satisfies the average valency of the elements other than oxygen and the ratio a:k being in a range of 10:30 to 80, which catalyst is prepared by preparing an aqueous slurry containing respective element-containing compounds, by spray drying the aqueous slurry to prepare a dried solid precursory catalyst and, finally, by calcining the precursory catalyst as a temperature of from 500.degree. to 750.degree. C. to provide an activated catalyst.

    摘要翻译： 用于丙烯氨氧化以制备丙烯腈的高产率的催化剂，其包含经验式（I）的氧化物组合物，其中X是锆和/或铬，下标a，b，c，d，e的MoaCobNicFedBieVfCagKhXiSijOk（I） 当a = 10，b = 0〜8，c = 0〜8，（b + c）= 2〜10时，f，g，h，i，j分别表示各元素的原子数，d = 0.3〜7，e = 0.01〜3，f = 0.01〜2，g = 0.01〜5，h = 0.05〜0.5，i = 0〜2，j = 10〜50，下标k表示氧数 原子，其满足除氧之外的元素的平均化合价，a:k的比例在10:30至80的范围内，该催化剂通过制备含有各含元素化合物的含水浆料，通过喷雾干燥水溶液 浆料以制备干燥的固体前体催化剂，最后通过在500℃至750℃的温度下煅烧前体催化剂以提供活化的催化剂。

    Method for the catalytical preparation of acrylonitrile
    8.
    发明授权
    Method for the catalytical preparation of acrylonitrile 失效
    丙烯腈催化制备方法

    公开(公告)号：US4070390A

    公开(公告)日：1978-01-24

    申请号：US732361

    申请日：1976-10-14

    申请人： Sumio Umemura ,  Kyoji Ohdan ,  Tokuo Matsuzaki ,  Taizo Uda ,  Mikio Hidaka ,  Yasuo Nakamura ,  Masao Tsuruoka

    发明人： Sumio Umemura ,  Kyoji Ohdan ,  Tokuo Matsuzaki ,  Taizo Uda ,  Mikio Hidaka ,  Yasuo Nakamura ,  Masao Tsuruoka

    IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/88 ,  B01J23/887 ,  B01J27/00 ,  B01J27/057 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C120/14

    CPC分类号： C07C253/26 ,  B01J23/8877 ,  B01J27/0576 ,  B01J2523/00 ,  Y02P20/52

    摘要： Acrylonitrile can be produced in a high yield by the catalytical ammoxidation of propylene at an elevated temperature, preferably of 330.degree. to 470.degree. C, in the presence of a new type of catalyst consisting of an oxide composition of the empirical formula: Mo.sub.a Co.sub.b Fe.sub.c Bi.sub.d X.sub.e O.sub.f wherein X denotes at least one atom of an element selected from vanadium and tellurium and wherein the ratio a:b:c:d:e:f is in a range of 10:3 to 10:1 to 7:0.1 to 0.7:0.01 to 1:34.6 to 54.1, said catalyst being prepared by providing an aqueous mixture containing molybdenum-, cobalt- and iron-containing compounds, bismuth-containing compound, and vanadium-or tellurium-containing compound, converting the aqueous mixture into a dried solid mixture and calcining the solid mixture at a temperature of at least 500.degree. C.

    摘要翻译： 丙烯腈可以通过在升高的温度下，优选在330℃至470℃的丙烯的催化氨氧化反应，在新型催化剂的存在下，由经验式的氧化物组合物：MoaCobFecBidXeOf，其中X 表示选自钒和碲中的元素的至少一个原子，其中a:b:c:d:e:f的比率在10:3至10:1至7:0.1至0.7:0.01至1的范围内 ：34.6至54.1，所述催化剂通过提供含有含钼，钴和铁的化合物，含铋化合物和含钒或碲化合物的水性混合物制备，将含水混合物转化成干燥的固体混合物， 在至少500℃的温度下煅烧固体混合物

    Catalytic oxidative process for producing maleic anhydride
    10.
    发明授权
    Catalytic oxidative process for producing maleic anhydride 失效
    用于生产马来酸酐的催化氧化方法

    公开(公告)号：US4110350A

    公开(公告)日：1978-08-29

    申请号：US816916

    申请日：1977-07-19

    申请人： Sumio Umemura ,  Kyoji Ohdan ,  Fumihiko Sakai ,  Yasuo Bando ,  Harumi Ikezawa

    发明人： Sumio Umemura ,  Kyoji Ohdan ,  Fumihiko Sakai ,  Yasuo Bando ,  Harumi Ikezawa

    IPC分类号： B01J23/16 ,  B01J23/22 ,  B01J23/847 ,  B01J27/198 ,  C07C51/25 ,  C07D307/60

    CPC分类号： C07C51/25 ,  B01J23/16 ,  B01J23/22 ,  B01J23/8472 ,  B01J27/198 ,  C07C51/252

    摘要： Unsaturated hydrocarbons having 4 to 6 carbon atoms are catalytically oxidized into maleic anhydride by using a catalyst, which consists essentially of oxides of (A) vanadium, (B) phosphorus, (C) titanium and (D) optionally at least one element selected from sodium, calcium, magnesium, iron, zirconium, boron, manganese, silver and molybdenum in the atomic ratios defined by the following formulaVP.sub.a Ti.sub.b X.sub.c O.sub.dwherein X is the element (D) set forth above and a=1.0 to 5.0, b=2.0 to 12.0 and c=0 to 1.0, and which catalyst is prepared by calcining a mixture of a vanadium-containing compound and titanium dioxide at a temperature of 650.degree. C. to 1,500.degree. C., incorporating into the mixture a phosphorus-containing compound and optionally the element "X"-containing compound and, then, heating the resulting mixture.

    摘要翻译： 具有4-6个碳原子的不饱和烃通过使用催化剂催化氧化成马来酸酐，所述催化剂基本上由（A）钒，（B）磷，（C）钛和（D​​）的氧化物组成，任选地至少一种选自 钠，钙，镁，铁，锆，硼，锰，银和钼，其原子比由下列化学式定义：VPaTibXcOd WHEREIN X是上述元素（D），a = 1.0至5.0，b = 2.0至12.0 并且c = 0至1.0，并且通过在650℃至1500℃的温度下煅烧含钒化合物和二氧化钛的混合物来制备该催化剂，将含磷化合物和任选地 含有元素“X”的化合物，然后加热所得混合物。