摘要:
A process for preparing graft polymers from a polymer is based on conjugated diene units and a graft which is a thiol derivative. The process has an absence of solvent and any radical initiator. The graft polymer can be advantageously be used as additive for a bitumen/polymer composition and in particular permits thermoreversible cross-linking.
摘要:
A process for preparing graft polymers from a polymer is based on conjugated diene units and a graft which is a thiol derivative. The process has an absence of solvent and any radical initiator. The graft polymer can be advantageously be used as additive for a bitumen/polymer composition and in particular permits thermoreversible cross-linking.
摘要:
A graft polymer PG includes a polymer backbone P and at least one side graft G linked to the polymer backbone, the graft G having the general formula (1): in which R1 and R2 represent, separately from one another, straight or branched, unsaturated or saturated hydrocarbon groups, such that the total number of carbon atoms in groups R1 and R2 is between 2 and 110; X represents an amide, amino-acid, urea or urethane function, the graft G being linked to the polymer backbone P via the sulphur atom. The graft polymer PG is a polymer that allows thermoreversible cross-linking and can be used in many fields such as coatings, paints, thermoplastics, adhesives, lubricants, fuels, inks, cements, construction materials, rubbers and bitumens. The graft polymer PG can be used in particular for thermoreversibly cross-linking bitumen/polymer compositions and thus for reducing coating, spreading and/or compaction temperatures during the production of bituminous coated materials.
摘要:
The use in a bituminous composition of an organogelator molecule of the following general formula (I) is disclosed below: where: A is a hydrocarbon group which can be straight or branched, saturated or unstaurated, acyclic, cyclic or polycyclic, having 3 to 92 carbon atoms, resulting from the polymerization of lateral chains of at least one unsaturated fatty acid, X is an NH group or an oxygen atom O, R1 is a group chosen from: a straight or branched hydrocarbon group with 2 to 40 carbon atoms, optionally including one or more heteroatoms and optionally including one or more unsaturations, or an aromatic group, substituted or otherwise, R2 is a group selected among: a hydrogen atom, a straight or branched hydrocarbon group with 1 to 40 carbon atoms, including one or more heteroatoms and optionally including one or more unsaturations, or an aromatic group, substituted or otherwise; m and n are, separately from one another, an integer ranging from 1 to 4, p is an integer ranging from 0 to 4, q is an integer ranging from 1 to 4 or a combination of the values, Y is a group including a hydrogen bond donor such as the NH grouping and a hydrogen bond acceptor such as the C═O grouping, to improve the resistance thereof to aggressive chemical agents, in particular to hydrocarbons such as gasolines, diesels and/or kerosenes.
摘要:
The use in a bituminous composition of an organogelator molecule of the following general formula (I) is disclosed below: where: A is a hydrocarbon group which can be straight or branched, saturated or unsaturated, acyclic, cyclic or polycyclic, having 3 to 92 carbon atoms, resulting from the polymerization of lateral chains of at least one unsaturated fatty acid, X is an NH group or an oxygen atom O, R1 is a group chosen from: a straight or branched hydrocarbon group with 2 to 40 carbon atoms, optionally including one or more heteroatoms and optionally including one or more unsaturations, or an aromatic group, substituted or otherwise, R2 is a group selected among: a hydrogen atom, a straight or branched hydrocarbon group with 1 to 40 carbon atoms, including one or more heteroatoms and optionally including one or more unsaturations, or an aromatic group, substituted or otherwise; m and n are, separately from one another, an integer ranging from 1 to 4, p is an integer ranging from 0 to 4, q is an integer ranging from 1 to 4 or a combination of the values, Y is a group including a hydrogen bond donor such as the NH grouping and a hydrogen bond acceptor such as the C═O grouping, to improve the resistance thereof to aggressive chemical agents, in particular to hydrocarbons such as gasolines, diesels and/or kerosenes.
摘要:
The present disclosure relates to the use of 2 to 6% by mass of Fischer-Tropsch waxes in a cross-linked bitumen/polymer composition for improving the cross-linked bitumen/polymer composition's resistance to aggressive chemical agents.
摘要:
The present disclosure relates to the use of at least one fatty acid derivative of general formula (1) in a bituminous composition for improving their resistance to aggressive chemical agents, and in particular to hydrocarbons, such as gasolines, gas oils and/or kerosenes, general formula (1) being: with, when n is equal to 0, an X group chosen from the NH2 or NHR3 groups and when n is equal to 1, an X group which represents the —NH—(CH2)m—NH— group, the R1, R2, R3 groups being, independently of each other, saturated or unsaturated, linear or branched hydrocarbon groups with 8 to 24 carbon atoms, m being between 1 and 8.
摘要:
The disclosure includes the use in a bituminous composition of an organogelator derivative which has a molar mass no higher than 2,000 g/mol and includes at least one hydrogen bonds donor D, at least one hydrogen bonds acceptor A and at least one compatibilizer agent C in the bitumen, the compatibilizer agent C including a group selected among: at least one straight hydrocarbon chain including at least 4 carbon atoms, or at least one aliphatic cycle of 3 to 8 atoms, or at least one aromatic cycle, or at least one aliphatic or partly aromatic, or even entirely aromatic, condensed polycyclic system, each cycle including 5 or 6 atoms taken alone or as a mixture, to improve the resistance to aggressive chemical agents, in particular to hydrocarbons, such as gasolines, diesels and/or kerosenes, excluding N,N′-ethylene bis(stearamide) and excluding fatty-chains polyamines obtained by reacting polyalkylene fatty-chains polyamines of general formula (I) R—NH—(CH2—CH2—CH2—NH)n—H wherein R is a linear hydrocarbon chain, saturated and/or unsaturated, of 8 to 22 carbon atoms, n being an integer from 1 to 5, with formic acid.
摘要:
The disclosure includes a process for preparing cross-linked bitumen/polymer compositions without adding a cross-linking agent, the process comprising contacting at least one bitumen with at least one polymer, and subjecting a mixture of the bitumen and the polymer to electromagnetic wave radiation in a high frequency and/or microwave range.
摘要:
The present disclosure relates to a mother solution free from oil of petroleum origin including at least one oil of vegetable and/or animal origin, from 20% to 50% by mass of polymer, with respect to the mass of the mother solution, with or without at least one cross-linking agent, the oil of vegetable and/or animal origin being acid, with an acid value measured according to the standard NF EN ISO 660 including between 50 and 300 mg KOH/g. This mother solution with a very high concentration of polymer is stable and does not gel and can therefore be diluted and used for preparing cross-linked bitumen/polymer compositions, then bituminous mixes.
摘要翻译:本公开内容涉及一种无石油原油的母溶液,包括至少一种植物和/或动物来源的油,相对于母液的质量为20〜50质量% 没有至少一种交联剂,植物和/或动物来源的油是酸,具有根据标准NF EN ISO 660测量的酸值,包括50-300mg KOH / g。 具有非常高浓度聚合物的母溶液是稳定的并且不凝胶,因此可以稀释并用于制备交联沥青/聚合物组合物,然后沥青混合物。