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公开(公告)号:US09487445B2
公开(公告)日:2016-11-08
申请号:US14762149
申请日:2014-03-24
Applicant: TDK CORPORATION
Inventor: Hidesada Natsui , Taku Masai , Sanshiro Aman
IPC: C04B35/47 , C04B35/475 , H01B3/12 , H01L41/43 , H01L41/187 , C01G49/00 , C04B35/26 , C04B35/462 , C04B35/00
CPC classification number: C04B35/475 , C01G49/00 , C01G49/0036 , C01P2002/34 , C04B35/00 , C04B35/26 , C04B35/462 , C04B35/47 , C04B2235/3201 , C04B2235/3213 , C04B2235/3232 , C04B2235/3298 , C04B2235/5445 , C04B2235/5454 , C04B2235/6562 , C04B2235/765 , C04B2235/768 , H01B3/12 , H01L41/187 , H01L41/1878 , H01L41/43
Abstract: A novel ceramic composition having a high relative dielectric constant. A ceramic composition includes a unit cell having at least two crystal structures selected from the group made of a monoclinic crystal, a tetragonal crystal, an orthorhombic crystal, and a rhombohedral crystal, characterized in that when the crystal structures are represented by the symmetry notation according to the Glazer method, namely xn1yn2zn3, n1, n2, and n3 are at least one selected from the group made of + and −, or at least two selected from the group made of 0, +, and −. By using this ceramic composition, a novel ceramic composition having a high relative dielectric constant can be obtained.
Abstract translation: 具有高相对介电常数的新型陶瓷组合物。 陶瓷组合物包括具有选自由单斜晶体,四方晶体,正交晶体和菱方晶构成的组中的至少两种晶体结构的晶胞,其特征在于,当晶体结构由对称符号表示时 对于Glazer方法,即,xn1yn2zn3,n1,n2和n3是从由+和 - 构成的组中选择的至少一个,或者选自由0,+和 - 组成的组中的至少两个。 通过使用该陶瓷组合物,可以获得具有高相对介电常数的新型陶瓷组合物。
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公开(公告)号:US10003009B2
公开(公告)日:2018-06-19
申请号:US14633649
申请日:2015-02-27
Applicant: TDK CORPORATION
Inventor: Masahito Furukawa , Yoshikazu Shimura , Taku Masai , Satoshi Wada
IPC: H01L41/187 , H01L41/083
CPC classification number: H01L41/1873 , H01L41/083 , H01L41/1871
Abstract: A composite piezoelectric ceramic includes a compact of crystal particles including at least one of potassium niobate (KNbO3) and sodium niobate (NaNbO3) and optionally further including lithium niobate (LiNbO3), and a layer containing barium titanate (BaTiO3) that is disposed on the surface of the compact while forming a heterojunction with the compact. A piezoelectric device includes the composite piezoelectric ceramic.
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公开(公告)号:US09831418B2
公开(公告)日:2017-11-28
申请号:US14610321
申请日:2015-01-30
Applicant: TDK CORPORATION
Inventor: Taku Masai , Masahito Furukawa , Hiroki Katoh
IPC: H01L41/187 , H01L41/18 , H01L41/08 , H01L41/083 , H01L41/316
CPC classification number: H01L41/1878 , C04B35/475 , C04B2235/3201 , C04B2235/3206 , C04B2235/3241 , C04B2235/3262 , C04B2235/327 , H01L41/0805 , H01L41/083 , H01L41/18 , H01L41/316
Abstract: The present invention aims to provide a piezoelectric composition and a piezoelectric element. In the piezoelectric composition, the main component is represented by the following formula with a perovskite type structure, (Bi(0.5x+y+z)Na0.5x)m(Ti(x+0.5y)Mg0.5yMez)O3 wherein, 0.05≦x≦0.7, 0.01≦y≦0.7, 0.01≦z≦0.6, 0.75≦m≦1.0, x+y+z=1 and the transition metal element Me is any one or more selected from the group consisting of Mn, Cr, Fe and Co.
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公开(公告)号:US09537083B2
公开(公告)日:2017-01-03
申请号:US14201515
申请日:2014-03-07
Applicant: TDK CORPORATION
Inventor: Taku Masai , Masamitsu Haemori , Masahito Furukawa , Junichi Yamazaki , Kouhei Ohhashi
IPC: H01L41/187 , C04B35/475 , H01L41/08 , H01L41/316
CPC classification number: H01L41/1878 , C04B35/475 , H01L41/0805 , H01L41/316
Abstract: Provided is a piezoelectric composition containing a major component that is a perovskite-type oxide which is represented by the general formula ABO3, which contains no Pb, and which has A-sites containing Bi, Na, and K and B-sites containing Ti. The Ti is partly substituted with a transition metal element Me that is at least one selected from the group consisting of Mn, Cr, Fe, and Co. The content of Bi and the transition metal element Me in the perovskite-type oxide, which is the major component, is 6 mole percent to 43 mole percent in terms of Biu1MeO3.
Abstract translation: 本发明提供一种压电组合物,其含有主要成分为钙钛矿型氧化物,其由不含Pb的通式ABO3表示,具有含有Bi,Na,K的A位点和含有Ti的B位点。 Ti部分被选自Mn,Cr,Fe和Co中的至少一种的过渡金属元素Me所取代。钙钛矿型氧化物中Bi和过渡金属元素Me的含量为 主要组分按Biu1MeO3计为6摩尔%至43摩尔%。
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公开(公告)号:US09437807B2
公开(公告)日:2016-09-06
申请号:US14674466
申请日:2015-03-31
Applicant: TDK CORPORATION
Inventor: Yuko Saya , Taku Masai , Masahito Furukawa , Masamitsu Haemori
IPC: H01L41/187 , C04B35/475 , H01L41/083 , H01L41/08
CPC classification number: H01L41/1878 , B32B18/00 , C04B35/475 , C04B35/6261 , C04B35/62655 , C04B35/62675 , C04B35/638 , C04B2235/3201 , C04B2235/3206 , C04B2235/3217 , C04B2235/3232 , C04B2235/3272 , C04B2235/3298 , C04B2235/442 , C04B2235/449 , C04B2235/6562 , C04B2235/6565 , C04B2235/768 , C04B2235/785 , C04B2235/786 , C04B2237/346 , C04B2237/68 , C04B2237/704 , C23C14/08 , H01L41/0805 , H01L41/083
Abstract: The present invention aims to provide a piezoelectric composition and a piezoelectric element containing the piezoelectric composition. In the piezoelectric composition, the main component contains a substance represented by the following formula with a perovskite structure, (Bi(0.5x+y+z)Na0.5x)m(Ti(x+0.5y)Mg0.5yAlkzCo(1−k)z)O3 0.15≦x≦0.7, 0.28≦y≦0.75, 0.02≦z≦0.30, 0.17≦k≦0.83, 0.75≦m≦1.0, and x+y+z=1.
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公开(公告)号:US09324931B2
公开(公告)日:2016-04-26
申请号:US13893865
申请日:2013-05-14
Applicant: TDK CORPORATION
Inventor: Masahito Furukawa , Tomohisa Azuma , Taku Masai
IPC: H01L41/187 , C04B35/00 , H01L41/047 , H01L41/08 , H01L41/313
CPC classification number: H01L41/0477 , H01L41/0815 , H01L41/1873 , H01L41/313
Abstract: A piezoelectric device includes a first electrode film, a piezoelectric film disposed on the first electrode film, and a second electrode film disposed on the piezoelectric film. At least one of the first and second electrode films is composed of an alloy, and a main component of the alloy is a metal selected from the group consisting of Ti, Al, Mg, and Zn. The piezoelectric film has a main composition represented by (K1-x-y-w-vNaxLiyBawSrv)m(Nb1-z-uTazZru)O3 (1), where x, y, z, w, v, u, and m in formula (1) satisfy 0.4
Abstract translation: 压电装置包括第一电极膜,设置在第一电极膜上的压电膜和设置在压电膜上的第二电极膜。 第一电极膜和第二电极膜中的至少一个由合金构成,合金的主要成分为选自Ti,Al,Mg,Zn的金属。 压电膜具有由(K1-xyw-vNaxLiyBawSrv)m(Nb1-z-uTazZru)O3(1)表示的主要组成,其中式(1)中的x,y,z,w,v,u和m满足 0.4
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公开(公告)号:US10710932B2
公开(公告)日:2020-07-14
申请号:US16357860
申请日:2019-03-19
Applicant: TDK CORPORATION
Inventor: Daisuke Ohtsu , Taku Masai , Liu Hailong , Liang Liping
IPC: C04B35/468 , C04B35/47 , C04B35/453 , H01G4/12 , C04B35/475
Abstract: The object of the present invention is to provide the dielectric composition having good specific permittivity, high DC breakdown voltage and AC breakdown voltage, small dielectric loss and heat generating property, and good temperature property even though lead is not substantially used. A dielectric composition of the first aspect includes a, Ca, Bi, Ti, and Sr, wherein the dielectric composition includes two phases having different Sr characteristic X ray intensities when a characteristic X ray intensity derived from Sr is measured by EPMA, and when Sr1 represents the characteristic X ray intensity derived from Sr of a first phase measured by EPMA and Sr2 represents the characteristic X ray intensity derived from Sr of a second phase measured by EPMA, a ratio (Sr2/Sr1) of Sr2 with respect to Sr1 satisfies 2 or larger. A dielectric composition of the second aspect includes Ba, Ca, Bi, Ti, and Sr, wherein the dielectric composition includes three phases having different Sr characteristic X ray intensities when a characteristic X ray intensity derived from Sr is measured by EPMA, and when Sr1 represents the characteristic X ray intensity derived from Sr of a first phase measured by EPMA, Sr2 represents the characteristic X ray intensity derived from Sr of a second phase measured by EPMA, and Sr3 represents the characteristic X ray intensity derived from Sr of a third phase measured by EPMA, an intensity ratio (Sr1/Sr3) of Sr1 with respect to Sr3 is 0.6 or less and an intensity ratio (Sr2/Sr3) of Sr2 with respect to Sr3 is 1.4 or more.
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公开(公告)号:US09780294B2
公开(公告)日:2017-10-03
申请号:US14535880
申请日:2014-11-07
Applicant: TDK CORPORATION
Inventor: Taku Masai , Keisuke Teranishi , Masahito Furukawa
IPC: H01L41/18 , H01L41/187 , C04B35/475 , H01L41/08 , H01L41/083 , H01L41/273 , H01L41/316
CPC classification number: H01L41/1878 , H01L41/0805 , H01L41/083 , H01L41/273 , H01L41/316
Abstract: The present invention aims to provide an excellent piezoelectric composition and an excellent piezoelectric element if the piezoelectric properties especially a high spontaneous polarization and a sufficiently high resistivity, the low pollution, the environment and the ecology are considered. In the piezoelectric composition, the main component contains the substance represented by the following formula with a perovskite-typed structure, (Bi(0.5x+y+z)Na0.5x)m(Tix+0.5yMg0.5yAlz)O3. Wherein, 0.01≦x≦0.8, 0.2≦y≦0.8, 0.01≦z≦0.6, 0.75≦m≦1.0, and x+y+z=1.
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公开(公告)号:US08956547B2
公开(公告)日:2015-02-17
申请号:US13755354
申请日:2013-01-31
Applicant: TDK Corporation
Inventor: Taku Masai , Masahito Furukawa
IPC: C04B35/00 , H01L41/00 , H01L41/187 , C04B35/475 , C04B35/626 , H01L41/316
CPC classification number: H01L41/1873 , C04B35/475 , C04B35/62675 , C04B2235/3201 , C04B2235/3241 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3298 , C04B2235/6562 , C04B2235/6565 , C04B2235/768 , C04B2235/785 , C04B2235/786 , H01L41/187 , H01L41/316
Abstract: A piezoelectric compound having no occurrence of segregation or uneven structures as well as a piezoelectric element having excellent piezoelectric properties. The piezoelectric composition includes a main component that is a perovskite-typed oxide represented by formula of ABO3, wherein, one site includes Bi, Na, and another site includes Ti, and part of the Ti is substituted by transition metal element Me (Me is at least one element selected from the group consisting of Mn, Cr, Fe and Co), according to the conversion of BiMeO3, the content ratio of Bi and the transition metal element Me accounts for 6˜43 mol % relative to the whole perovskite-typed oxides as the main component.
Abstract translation: 不产生偏析或不均匀结构的压电化合物以及压电性能优异的压电元件。 压电组合物包括主要成分,其为由ABO 3的式表示的钙钛矿型氧化物,其中,一个位点包含Bi,Na,另一个位置包括Ti,并且部分Ti被过渡金属元素Me取代(Me是 选自Mn,Cr,Fe和Co中的至少一种元素),根据BiMeO3的转化率,Bi和过渡金属元素Me的含量比例相对于整个钙钛矿结构为6〜43摩尔% 以氧化物为主要成分。
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