公开(公告)号：US20210284805A1

公开(公告)日：2021-09-16

申请号：US17191422

申请日：2021-03-03

Applicant: The Regents of the University of California

Inventor： Rachel A. Segalman ,  Craig J. Hawker ,  Raphaele Clement ,  Javier Read de Alaniz ,  Nicole Michenfelder-Schauser ,  Peter Richardson ,  Andrei Nikolaev ,  Caitlin Sample ,  Hengbin Wang

IPC: C08G77/32 ,  C08G77/28 ,  C08G77/20 ,  H01M10/0565

Abstract: A composition of matter useful in an electrolyte, comprising a polymer including: a repeat unit, the repeat unit including a backbone section; and a side chain attached to the backbone section, wherein the side chain includes a ligand moiety configured to ionically bond to a lithium ion. The polymer has a glass transition temperature (e.g., less than room temperature) wherein the polymer is in a solid state during operation of a lithium ion battery comprising an electrolyte including the polymer.

公开(公告)号：US09158200B2

公开(公告)日：2015-10-13

申请号：US14153355

申请日：2014-01-13

Applicant: The Regents of the University of California

Inventor： Damien Montarnal ,  Craig J. Hawker ,  Edward J. Kramer ,  Glenn H. Fredrickson

IPC: G03F7/004 ,  G03F7/40 ,  G03F7/075 ,  C08K5/092 ,  C08L53/00 ,  H01L21/311

CPC classification number: C09D183/12 ,  C08K5/092 ,  C08L53/00 ,  G03F7/0002 ,  G03F7/075 ,  G03F7/11 ,  G03F7/40 ,  H01L21/3105 ,  H01L21/31144

Abstract: The invention provides compositions and methods for inducing and enhancing order and nanostructures in organosilicon block copolymers compositions by including certain organic additives in such compositions that include one or more moieties comprising a hydrogen bond acceptor or a hydrogen bond donor. Such block copolymer compositions may be used, for example, as a mask for lithographic patterning as is used, for example, during various stages of semiconductor device fabrication.

Abstract translation: 本发明提供了通过在包含一个或多个包含氢键受体或氢键给体的部分的组合物中包含某些有机添加剂来提供有机硅嵌段共聚物组合物中诱导和增强有序和纳米结构的组合物和方法。 这种嵌段共聚物组合物可以用作例如用于例如在半导体器件制造的各个阶段期间使用的用于光刻图案的掩模。

公开(公告)号：US20130248833A1

公开(公告)日：2013-09-26

申请号：US13850040

申请日：2013-03-25

Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

Inventor： Craig J. Hawker ,  Michael L. Chabinyc ,  Sung-Yu Ku ,  Maxwell J. Robb

IPC: H01L51/00

CPC classification number: H01L51/0043 ,  C08G61/126 ,  C08G2261/126 ,  C08G2261/1412 ,  C08G2261/3223 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/414 ,  C08G2261/74 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  H01L51/0036 ,  H01L51/0053 ,  H01L51/42 ,  H01L51/50 ,  Y02E10/549 ,  Y02P70/521

Abstract: The invention provides methods for making and using end-functionalized conjugated polymers. Embodiments of the invention comprise performing a coupling polymerization in the presence of AA monomers, BB monomers and an end capping compound that can react with a monomer and which is selected to include a functional group. The functional end groups can, for example, comprise polymers or small molecules selected for their ability to produce conjugated polymers that self-assemble into thermodynamically ordered structures. In certain embodiments of the invention, nano-scale morphology of such conjugated polymer compositions can be driven by the phase separation of two covalently bound polymer blocks. These features make the use of conjugated polymers an appealing strategy for exerting control over active layer morphology in semiconducting polymer materials systems.

Abstract translation: 本发明提供了制备和使用端官能化共轭聚合物的方法。 本发明的实施方案包括在AA单体，BB单体和可与单体反应并且被选择为包括官能团的封端化合物的存在下进行偶联聚合。 功能性端基可以例如包含聚合物或小分子，这些聚合物或小分子被选择用于产生自组装成热力学有序结构的共轭聚合物的能力。 在本发明的某些实施方案中，这种共轭聚合物组合物的纳米级形态可以通过两个共价结合的聚合物嵌段的相分离来驱动。 这些特征使共轭聚合物成为在半导体聚合物材料体系中对活性层形态进行控制的有吸引力的策略。

公开(公告)号：US10280342B2

公开(公告)日：2019-05-07

申请号：US14908956

申请日：2014-07-30

Applicant: The Regents of the University of California

Inventor： Herbert J. Waite ,  B. Kollbe Ahn ,  Craig J. Hawker ,  Jinhwa Heo ,  Taegon Kang

IPC: C08F12/24 ,  C07C33/30 ,  C09J143/04 ,  C07F7/18 ,  C08F30/08 ,  C08F16/26 ,  C09J125/18 ,  C09J129/02 ,  C07C33/20 ,  C07C33/26 ,  C07C33/025 ,  C07C39/19 ,  C07C39/20 ,  C08F220/30 ,  C09J4/06

Abstract: A compound of formula (I): can be used as a monomer for making an underwater adhesive polymer. The compound of formula (I) can be prepared using eugenol as a starting material.

公开(公告)号：US10228619B2

公开(公告)日：2019-03-12

申请号：US15476470

申请日：2017-03-31

Applicant: The Regents of the University of California ,  Rohm and Haas Electronic Materials LLC ,  Dow Global Technologies LLC

Inventor： Craig J. Hawker ,  Zachariah Allen Page ,  Peter Trefonas, III ,  Anatoliy N. Sokolov ,  John Kramer ,  David S. Laitar ,  Sukrit Mukhopadhyay ,  Benjaporn Narupai ,  Christian Wilhelm Pester

IPC: G03F7/027 ,  H01L51/50 ,  C08F293/00 ,  C08F220/34 ,  G03F7/16 ,  G03F7/20 ,  C09K11/06 ,  H01L51/00 ,  C09K11/02

Abstract: Disclosed herein is an article comprising a substrate; a first region having a first brush polymer chemically bonded to the substrate; where the first brush polymer comprises repeat units of a first ethylenically unsaturated monomer and a second ethylenically unsaturated monomer; where the first ethylenically unsaturated monomer comprises a first electroactive moiety and where the second ethylenically unsaturated monomer comprises a second electroactive moiety that is different from the first electroactive moiety; where at least one of the first electroactive moiety or the second electroactive moiety is an emitter moiety and where the repeat units of the first ethylenically unsaturated monomer are covalently bonded to repeat units of the second ethylenically unsaturated monomer.

公开(公告)号：US09315637B2

公开(公告)日：2016-04-19

申请号：US14573491

申请日：2014-12-17

Applicant: The Regents of the University of California

Inventor： Damien Montarnal ,  Yingdong Luo ,  Craig J. Hawker ,  Edward J. Kramer ,  Glenn H. Frederickson

IPC: C08F293/00 ,  C08G81/00 ,  C08G81/02 ,  C09D153/00 ,  B05D3/10 ,  B44C1/22 ,  G03F1/00 ,  G03F7/00

CPC classification number: C08G81/024 ,  B05D3/107 ,  B44C1/227 ,  C09D153/00 ,  G03F1/00 ,  G03F7/0002 ,  Y10T428/31663

Abstract: Junction-functionalized block copolymers can be used in forming nanostructures. A junction-functionalized block copolymer can include a first polymer block joined to a second polymer block by a junction, where the junction includes one or more electrostatically charged moieties. The block copolymer can include a moiety of formula (I): A-J-B  (I) where A is a first polymer block, B is a second polymer block, where the A block and the B block are chemically dissimilar, and J is a junction linking the A block to the B block, and including one or more electrostatically charged moieties.

Abstract translation: 结型官能化嵌段共聚物可用于形成纳米结构。 连接官能化嵌段共聚物可以包括通过结连接到第二聚合物嵌段的第一聚合物嵌段，其中连接包括一个或多个静电荷部分。 嵌段共聚物可以包括式（I）的部分：AJB（I）其中A是第一聚合物嵌段，B是第二聚合物嵌段，其中A嵌段和B嵌段是化学上不相似的，J是连接 B嵌段的A嵌段，并且包括一个或多个静电荷部分。

公开(公告)号：US20140099580A1

公开(公告)日：2014-04-10

申请号：US14050098

申请日：2013-10-09

Applicant: The Regents of the University of California

Inventor： Craig J. Hawker ,  Brett P. Fors ,  Justin E. Poelma

IPC: G03F7/20 ,  G03F7/004

CPC classification number: G03F7/20 ,  G03F7/0037 ,  G03F7/004 ,  G03F7/027 ,  G03F7/16

Abstract: The invention disclosed herein provides highly efficient methods and materials useful for surface patterning via polymerization reactions. In particular, by using a light-mediated radical polymerization procedure, brush formation from a surface can be regulated spatially by controlling the area of irradiation. In embodiments of the invention, polymer chain length (and/or film thickness) can be effectively controlled by either the amount of time a surface is irradiated with light (temporal control) or by the intensity of light allowed to reach the surface. Such light-mediated control allows artisans to use the disclosed processes to form complex 3-dimensional structures on a variety of surfaces. Moreover, the simplicity of the disclosed polymerization processes allows them to be adapted for use in a wide range of technologies.

Abstract translation: 本文公开的本发明提供了用于通过聚合反应进行表面图案化的高效方法和材料。 特别地，通过使用光介导的自由基聚合方法，可以通过控制照射面积在空间上调节表面的刷子形成。 在本发明的实施方案中，可以通过用光照射表面的时间量（时间控制）或允许到达表面的光的强度来有效地控制聚合物链长度（和/或膜厚度）。 这种光介导的控制允许工匠使用所公开的方法在各种表面上形成复杂的三维结构。 此外，所公开的聚合方法的简单性允许它们适用于广泛的技术。

公开(公告)号：US20190002787A1

公开(公告)日：2019-01-03

申请号：US16025741

申请日：2018-07-02

Applicant: The Regents of the University of California

Inventor： Bas van Ravensteijn ,  Raghida Bou Zerdan ,  Watanabe Takumi ,  Dongjin Seo ,  Nicholas Cadirov ,  Jeffrey Gerbec ,  Craig J. Hawker ,  Jacob Israelachvili ,  Matthew E. Helgeson

IPC: C10M155/02 ,  C08G83/00 ,  C10M169/04 ,  C10M101/02

Abstract: Disclosed herein are star-shaped macromolecular structures comprising a hyper-branched silicon containing core grafted with a well-defined and controllable number of alkyl (methyl)acrylate (co)polymer arms. The presence of the robust inorganic core provides additional resilience against mechanical degradation and therefore enhanced additive life time. Control over the additive architecture was complemented by tunability of the length of the grafted polymers by making use of controlled radical based polymerization techniques. The performance of these novel inorganic-organic star-shaped hybrids were compared to traditional fully organic lubricant additives. Detailed analysis revealed the multi-functional character of the hybrids by simultaneously performing as bulk viscosity modifiers, boundary lubricant, and wear protectants while being dispersed in a commercially available base oil for automotive lubrication purposes.

公开(公告)号：US20150376455A1

公开(公告)日：2015-12-31

申请号：US14849289

申请日：2015-09-09

Applicant: The Regents of the University of California

Inventor： Damien Montarnal ,  Craig J. Hawker ,  Edward J. Kramer ,  Glenn H. Fredrickson

IPC: C09D183/12 ,  C08K5/092

CPC classification number: C09D183/12 ,  C08K5/092 ,  C08L53/00 ,  G03F7/0002 ,  G03F7/075 ,  G03F7/11 ,  G03F7/40 ,  H01L21/3105 ,  H01L21/31144

Abstract: The invention provides compositions and methods for inducing and enhancing order and nanostructures in organosilicon block copolymers compositions by including certain organic additives in such compositions that include one or more moieties comprising a hydrogen bond acceptor or a hydrogen bond donor. Such block copolymer compositions may be used, for example, as a mask for lithographic patterning as is used, for example, during various stages of semiconductor device fabrication.

Abstract translation: 本发明提供了通过在包含一个或多个包含氢键受体或氢键给体的部分的组合物中包含某些有机添加剂来提供有机硅嵌段共聚物组合物中诱导和增强有序和纳米结构的组合物和方法。 这种嵌段共聚物组合物可以用作例如用于例如在半导体器件制造的各个阶段期间使用的用于光刻图案的掩模。

公开(公告)号：US20150136233A1

公开(公告)日：2015-05-21

申请号：US14546282

申请日：2014-11-18

Applicant: The Regents of the University of California

Inventor： Hengbin Wang ,  Johannes Sprafke ,  Laura Neumann ,  Craig J. Hawker ,  Ming Wang

IPC: H01L51/00

CPC classification number: H01L51/0047 ,  H01L51/0003 ,  H01L51/4253 ,  H01L2251/552 ,  Y02E10/549

Abstract: The instant application teaches methods, compositions and devices useful in forming an active layer in photovoltaic cell devices. In typical embodiments of the invention, the active layer in photovoltaic cell devices is formed by selecting and combining certain constellations of complimentary donor and acceptor compounds.

Abstract translation: 本申请教导了可用于在光伏电池器件中形成有源层的方法，组合物和器件。 在本发明的典型实施例中，光伏电池器件中的有源层通过选择和组合互补供体和受体化合物的某些星座形成。