Abstract:
A sheet like article produced from a polyurethane resin has a carbonate group and an oxycarbonyl group as ester groups and has uniform, elegant surface quality, a flexible, highly crease recoverable texture, and high resistance to light and hydrolysis, and also provided is a production method therefore. The sheet like article is produced by adding, as a binder, a polyurethane resin that meets requirements (I) and (II) to a fibrous base material formed mainly of ultrafine fibers: (I) a polyurethane resin such that the polyurethane resin contains, in its interior, an oxycarbonyl group and a carbonate group as ester groups; (II) a polyurethane resin such that the sum of the content of the urethane group and the content of the urea group in the polyurethane resin is 7.0 to 11.0 mass %.
Abstract:
A garment serves for easy removal of dirt adhering to the screen of a smart watch, wristwatch, etc. worn by the user. The garment is one used as long-sleeved outerwear provided with a sheet-like article formed of ultrafine fibers with an average monofilament diameter of 0.1 μm or more and 7 μm or less and attached to the inside and/or outside of a cuff.
Abstract:
A sheet material includes a polymeric elastomer and a fiber-entangled body including, as a constituent element, a nonwoven fabric including ultrafine fibers having an average single fiber diameter of 1.0 μm or more and 10.0 μm or less. The ultrafine fibers include a polyester-based resin including a black pigment (a1). The black pigment (a1) has an average particle diameter of 0.05 μm or more and 0.20 μm or less and has a coefficient of variation (CV) of the average particle diameter of 75% or less. The polymeric elastomer includes a polyurethane including a black pigment (b). The sheet material has a nap coverage of 70% or more and 100% or less on a surface having a nap.
Abstract:
The present invention provides a sheet-like material in which a plant-derived raw material of low environmental impact is used. The invention also provides a sheet-like material that ideally has a uniform and refined nap and a sheet-like material that is strong, has excellent shape stability, is lightweight and is very pliable. This sheet-like material is characterized in being made of nonwoven fabric that is made of polyester microfiber containing a 1,2-propanediol-derived component in an amount prescribed in the present application and a polyurethane elastomer resin containing structural monomers prescribed in the present application. This sheet-like material is also made of a base sheet, in which a nonwoven fabric that has microfibers as the main component is laminated and unified with a woven or knitted material, and an elastomer resin, and is characterized in that the woven or knitted material is configured from fibers containing polyester as the main component and that 1-500 ppm of a 1,2-propanediol-derived component are contained in the polyester.
Abstract:
A composite sheet material includes a skin sheet and a woven fabric, wherein the skin sheet is formed by impregnating an elastic polymer into a base material consisting of an entangled fiber network, such as a nonwoven fabric, and wherein the composite sheet material has high thermal resistance and high formability suitable for integral molding. The composite sheet material is a composite sheet material including a skin sheet attached with a woven fabric through an adhesive resin layer, wherein the skin sheet is made of an entangled fiber network including ultra-fine fibers with an average single fiber diameter of 0.1 to 8 μm and of an elastic polymer, and wherein the woven fabric includes polyester fibers in which the polyester contains a 1,2-propanediol-derived component at a concentration of 1 to 500 ppm.
Abstract:
An automobile instrument panel surface material includes a microfiber having an average single fiber diameter of 0.3 to 7 μm; and polyurethane, the automobile instrument panel surface material having nap formed of the microfiber, the automobile instrument panel surface material having, of light fastnesses measured according to a light fastness measurement method of JIS L 0843:2006 under conditions of a xenon arc intensity of 110 MJ/m2, a fading by gray scale evaluation of grade 3.5 or higher, the automobile instrument panel surface material having a glass haze of 10.0% or less as measured according to a glass haze evaluation method of ISO 6452:2007 under conditions of a heating temperature of 100° C. and a heating time of 20 hours.
Abstract:
Provided is an environmentally friendly process for producing a sheet-shaped material having both an elegant, napped appearance and a soft texture, which qualities have not been achieved concurrently, and also exhibiting good abrasion resistance. The process of the present invention for producing a sheet-shaped material includes the successive steps of (a) adding a polyvinyl alcohol having a degree of saponification of 98% or more and a degree of polymerization of 800 to 3,500 to a fibrous substrate in an amount of 0.1 to 50% by mass relative to the total mass of fibers in the fibrous substrate; (b) adding a waterborne polyurethane to the fibrous substrate with the added polyvinyl alcohol; and (c) removing the polyvinyl alcohol from the fibrous substrate with the added waterborne polyurethane.
Abstract:
A sheet like article produced from a polyurethane resin has a carbonate group and an oxycarbonyl group as ester groups and has uniform, elegant surface quality, a flexible, highly crease recoverable texture, and high resistance to light and hydrolysis, and also provided is a production method therefore. The sheet like article is produced by adding, as a binder, a polyurethane resin that meets requirements (I) and (II) to a fibrous base material formed mainly of ultrafine fibers: (I) a polyurethane resin such that the polyurethane resin contains, in its interior, an oxycarbonyl group and a carbonate group as ester groups; (II) a polyurethane resin such that the sum of the content of the urethane group and the content of the urea group in the polyurethane resin is 7.0 to 11.0 mass %.
Abstract:
The present invention provides a conjugated fiber suitable for use as a crimped fiber capable of producing an artificial leather having highly dense texture and good quality. The present invention also provides a base body for an artificial leather and an artificial leather produced by using such conjugated fiber. The conjugated fiber of the present invention includes a conjugated fiber comprising a readily soluble polyester component and a less readily soluble component, and the readily soluble polyester component comprises a copolymerized polyester having 5 to 10% by mole of 5-sodium sulfoisophthalate copolymerized therewith and the readily soluble polyester component contains a polyalkylene glycol. The polyalkylene glycol is in the form of streaks extending in longitudinal direction of the fiber in the longitudinal cross section of the conjugated fiber.
Abstract:
A sheet material has good mechanical properties, flexibility, lightweight properties, and quality, and also relates to a production method therefor. The sheet material includes, as constitutional components, an elastic polymer and nonwoven fabric composed mainly of ultrafine hollow fiber with an average monofilament diameter in the range of 0.05 to 10 μm, the ultrafine hollow fiber containing 2 to 60 hollows.