摘要:
This invention provides a coating method comprising the steps of applying to an electroconductive substrate a cationic electrophoretic primer which contains a binder resin having in its molecule a functional group capable of reacting with an isocyanate group under a curing condition to form a primer coat, applying to the primer coat a surfacer or topcoating containing a hydroxyl-containing resin and polyisocyanate compound to form a surfacer coat or topcoat and curing the two coats at the same time at a temperature between room temperature and about 130.degree. C.
摘要:
A process for forming a composite coated film, which comprises coating a cationically electrodepositing paint composed mainly of a cationic resin having a functional group capable of reacting with isocyanate groups on the surface of a substrate, then coating an organic solvent-base paint containing a polyisocyanate compound and capable of forming a coated film having a static glass transition temperature of 0.degree. to -75.degree. C. on the surface of the electrodeposited paint film, and then coating a top coat paint.
摘要:
A cationic electrodeposition coating composition for forming a multilayer film, said composition comprising(A) an epoxy-type cationic electrodepositable resin which is an addition-reaction product formed between an epoxy resin and a basic amino compound, having a surface tension of 40 to 60 dynes/cm and being capable of forming a cathodically depositable aqueous bath by neutralization with an acid,(B) a non-ionic, non-selfcurable, film-forming resin having a surface tension of 25 to 45 dynes/cm, and(C) a blocked polyisocyanate compound as a curing agent,the weight ratio of resin (A) to resin (B) being from 60:40 to 98:2, and the surface tension of resin (A) being at least 5 dynes/cm higher than that of resin (B), and resin (A), resin (B) and the polyisocyanate compound (C) having substantially no ethylenically double bond.
摘要:
A cationically electrodepositable finely divided gelled polymer obtained by emulsion-polymerizing, in the presence of a water-soluble or water-dispersible cationic resin, a monomer component (A) comprising(a) a polymerizable unsaturated vinylsilane monomer having a vinylic double bond and a hydrolyzable akloxysilane group,(b) a polymerizable monomer having at least two radically polymerizable unsaturated groups in the molecule,(c) a polymerizable unsaturated monomer having a vinylic double bond and a hydroxyl group, and(d) other polymerizable unsaturated monomer, and a cationically electrodepositable finely divided gelled polymer obtained by emulsion-polymerizing, in the presence of the above finely divided gelled polymer, a monomer component (B) comprising(e) a blocked mono- or polyisocyanate in which the at least one isocyanate group in the molecule is blocked with a radically polymerizable monohydroxy compound,(f) a polymerizable unsaturated monomer having a vinylic double bond and a hydroxyl group, and(g) other polymerizable unsaturated monomer, said cationically electrodepositable finely divided gelled polymer having a core-sheath structure consisting of a core of the polymerization product of the monomer component (A) and a sheath of the polymerization product of the monomer component (B).
摘要:
A composite paint film formed on a steel sheet of an automotive vehicle body. The composite paint film comprises an electrodeposition paint film (I) coated on the steel sheet, and an intermediate coat paint film (II) coated on the first paint film. The electrodeposition paint film is formed of an epoxy-based cationic electrodeposition paint composition and has a minimum melt viscosity not less than 0.2 during hardening. The epoxy-based cationic electrodeposition paint composition includes an amine-added epoxy resin (1) of the type which may be hardened with a blocked isocyanate, a colloidal silica-containing gelled particulate (2), and an alkyltin ester compound of a liquid aliphatic carboxylic acid. The above-mentioned colloidal silica-containing gelled particulate is formed by dispersing a mixture of an acrylic copolymer having a hydrolizable alkoxysilane group and a cationic group and a cationic acidic colloidal silica in water to carry out a cross-linking reaction in particles of the colloidal silica. The second paint film (II) has a hardening starting time ranging from 15 to 20 minutes.
摘要:
A resin composition for a cationically electrodepositable paint comprising(A) a resin having hydroxyl groups and cationic groups,(B) an epoxy resin having at least 2 epoxy functional groups each of which comprises an epoxy group directly bound to an alicyclic ring and/or bridged alicyclic ring on average per molecule, and(C) a finely divided gelled polymer as principal components, wherein said finely divided gelled polymer is obtained by emulsion polymerizing(C-1) a polymerizable monomer containing at least two radically polymerizable unsaturated groups in the molecule, and(C-2) a radically polymerizable unsaturated monomer other than the one mentioned in (C-1), abovein the presence of a reactive emulsifier containing an allyl group in the molecule.
摘要:
A coating method, which comprises(i) applying to a substrate a multilayer film-forming cationic electrodeposition paint composed of(A) a cationic electrodepositable epoxy resin having a surface tension of 40 to 60 dynes/cm and being able to form a cathodically electrodepositable aqueous bath by neutralization with an acid, and(B) a nonionic film-forming resin having a surface tension of 25 to 45 dynes/cm, the weight ratio of resin (A) to resin (B) being from 60:40 to 98:2 and the surface tension of resin (A) being greater than that of resin (B), and curing the coated film by heating,(ii) applying a water-base or organic solvent-base colored paint as a first top coat, and(iii) applying as a second top coat a powder paint capable of forming a transparent film which may be colored.
摘要:
A resin composition for cationically electrodepositable paint comprising, as principal components, (A) a resin containing a hydroxyl group and a cationic group, (B) an epoxy resin containing, per molecule, on the average at least 2 epoxy group-containing functional groups with an epoxy group bound to an alicyclic skeleton and/or a bridged alicyclic skeleton, and (C) a finely divided gelled polymer, said finely divided gelled polymer (C) being obtained by, in the first step, emulsion polymerizing (I) a monomer component composed of(a) a polymerizable unsaturated vinylsilane monomer containing a vinylic double bond and a hydrolyzable alkoxysilane group,(b) a polymerizable monomer containing at least two radically polymerizable unsaturated groups in a molecule,(c) a polymerizable unsaturated monomer containing a vinylic double bond and a hydroxyl group, and(d) the other polymerizable unsaturated monomer using a cationic reactive emulsifying agent containing an allyl group in a molecule; and in the second step, emulsion polymerizing (II) a monomer component composed of(e) a blocked monoisocyanate or polyisocyanate in which at least one isocyanate group in a molecule is blocked with a radically polymerizable monohydroxy compound,(f) a polymerizable unsaturated monomer containing a vinylic double bond and a hydroxyl group, and(g) the other polymerizable unsaturated monomer in the presence of the aqueous finely divided gelled polymer obtained in the first step, said polymer having a core-sheath structure in which the polymerized product of the monomer component (I) is a core and the polymerized product of the monomer component (II) is a sheath (shell).
摘要:
A cationic electrodeposition coating composition comprising[A] a neutralization product or a quaternary ammonium salt of a comb-shaped copolymer obtained by copolymerizing (a) 3 to 90 parts by weight of an ethylenically unsaturated monomer having a hydrocarbon chain with at least 8 carbon atoms at the molecular ends, (b) 1 to 50 parts by weight of at least one cationic (meth)acrylic monomer selected from the group consisting of aminoalkyl (meth)acrylates, aminoalkyl (meth)acrylamides (meth)acrylates containing a quaternary ammonium salt group and (meth)acrylamides containing a quaternary ammonium salt group, (c) 1 to 60 parts by weight of an alpha,beta-ethylenically unsaturated monomer other than the monomer (b), and (d) 0 to 95 parts by weight of an alpha,beta-ethylenically unsaturated monomer other than the monomers (a), (b) and (c),[B] a cationic epoxy resin capable of being dissolved or dispersed in water, and[C] a pigment.
摘要:
Document data stored in a document storage area are extracted line by line to analyze the structure of the document data. The document layout information is extracted from the analysis result. The extracted layout information is stored, as learning data, in a document layout information learning area. In format conversion, the document data to be output, which is extracted in the same manner as described above, is converted on the basis of the learning data. Document data having a consistent layout is output to a CRT or a printer in accordance with the converted layout information.