公开(公告)号：US4347383A

公开(公告)日：1982-08-31

申请号：US147194

申请日：1980-05-06

申请人： Tomiya Isshiki ,  Tetsuo Tomita ,  Shuzabu Sakaguchi ,  Toshiaki Kohzaki ,  Osamu Aoki ,  Norio Takeda ,  Yoshiyuki Aoki

发明人： Tomiya Isshiki ,  Tetsuo Tomita ,  Shuzabu Sakaguchi ,  Toshiaki Kohzaki ,  Osamu Aoki ,  Norio Takeda ,  Yoshiyuki Aoki

IPC分类号： C07C255/67 ,  C07C109/16

CPC分类号： C07C251/88

摘要： A process for producing a benzophenone-azine which comprises reacting the corresponding benzophenone-imine with molecular oxygen or benzophenone with ammonia and molecular oxygen in the presence of a catalyst selected from the group consisting of metals, metal oxides and alloys of two or more metals, particularly copper or copper alloy-containing catalyst, is disclosed.

摘要翻译： 一种二苯甲酮 - 吖嗪的制备方法，其包括使相应的二苯甲酮 - 亚胺与分子氧或二苯甲酮与氨和分子氧在选自金属，金属氧化物和两种或更多种金属的合金的催化剂存在下反应， 特别是含铜或含铜合金的催化剂。

公开(公告)号：US4727190A

公开(公告)日：1988-02-23

申请号：US918656

申请日：1986-10-14

申请人： Takanari Nawata ,  Shuzabu Sakaguchi ,  Toshiaki Kohzaki ,  Osamu Aoki ,  Norio Takeda ,  Yoshiyuki Aoki ,  Masafumi Shimpo

发明人： Takanari Nawata ,  Shuzabu Sakaguchi ,  Toshiaki Kohzaki ,  Osamu Aoki ,  Norio Takeda ,  Yoshiyuki Aoki ,  Masafumi Shimpo

IPC分类号： C09B17/00 ,  B01J27/122 ,  C01B21/16 ,  C07B61/00 ,  C07C249/16 ,  C07C251/88 ,  C07C109/16

CPC分类号： C07C251/88 ,  C01B21/16

摘要： A process for continuously preparing benzophenone-azines comprising oxidizing benzophenone-imines with molecular oxygen or a molecular oxygen-containing gas in the presence of a copper halide catalyst is disclosed. The oxidation reaction is carried out in a multistage system under an oxygen partial pressure gradually decreasing from the former stage to the latter stage and at a conversion gradually decreasing from the former stage to the latter stage, while controlling the conversion so that the molar ratio of the benzophenone-imines to the copper halide in the final stage be maintained at 1 or more. By the process, the continuous reaction can stably be performed at a high conversion of the benzophenone-imines without involving insolubilization and sedimentation of the catalyst.

摘要翻译： 公开了一种连续制备二苯甲酮吖嗪的方法，包括在卤化铜催化剂存在下用分子氧或含分子氧气体氧化二苯甲酮 - 亚胺。 氧化反应在多级体系​​中，在从前一阶段到后一阶段逐渐降低的氧分压下进行，并且转化率从前一阶段逐渐降低到后一阶段，同时控制转化率，使得 在最后阶段将二苯甲酮 - 亚胺与卤化铜保持在1以上。 通过该方法，连续反应可以稳定地在二苯甲酮 - 亚胺的高转化率下进行，而不会引起催化剂的不溶解和沉淀。

公开(公告)号：US4239741A

公开(公告)日：1980-12-16

申请号：US955166

申请日：1978-10-27

申请人： Tomiya Isshiki ,  Tetsuo Tomita ,  Toshiaki Kozaki ,  Osamu Aoki ,  Mitsuo Abe ,  Norio Takeda ,  Mitsuo Miura ,  Yoshiyuki Aoki ,  Takao Kondo ,  Kaoru Tsuyuki

发明人： Tomiya Isshiki ,  Tetsuo Tomita ,  Toshiaki Kozaki ,  Osamu Aoki ,  Mitsuo Abe ,  Norio Takeda ,  Mitsuo Miura ,  Yoshiyuki Aoki ,  Takao Kondo ,  Kaoru Tsuyuki

IPC分类号： C01B21/16 ,  C01B21/54

CPC分类号： C01B21/16

摘要： Hydrazine sulfate having a relatively large particle diameter and a high purity is produced by hydrolysis of benzophenoneazines by sulfuric acid having a concentration of 75% by weight or less in an amount of 1.1 times by mole or more the stoichiometric amount in a very high conversion and a high yield with less operational loss.

摘要翻译： 通过以非常高的转化率使化学计量量为1.1倍摩尔以上的浓度为75重量％以下的硫酸水解二苯甲酮酮而产生具有较大粒径且高纯度的硫酸肼， 产量高，运营损失少。

公开(公告)号：US4751326A

公开(公告)日：1988-06-14

申请号：US684419

申请日：1984-12-20

申请人： Takanari Nawata ,  Shuzabu Sakaguchi ,  Toshiaki Kohzaki ,  Osamu Aoki ,  Norio Takeda ,  Masafumi Shimpo

发明人： Takanari Nawata ,  Shuzabu Sakaguchi ,  Toshiaki Kohzaki ,  Osamu Aoki ,  Norio Takeda ,  Masafumi Shimpo

IPC分类号： C07B61/00 ,  B01J27/00 ,  B01J27/32 ,  C07C67/00 ,  C07C241/00 ,  C07C251/88 ,  C07C109/04

CPC分类号： C07C251/88 ,  B01J27/32 ,  Y02P20/584

摘要： An improved process for producing benzophenone-azine in which a catalyst can be removed, recovered and recycled is disclosed. The process comprises the steps of:(a) oxidizing benzophenone-imine with molecular oxygen in the presence of cuprous chloride catalyst to produce an oxidation reaction mixture containing benzophenone-azine;(b) contacting the oxidation reaction mixture obtained in step (a) with an aqueous solution containing ammonium chloride and hydrochloric acid to decompose the remaining benzophenone-imine substantially without causing decomposition of the produced benzophenone-azine and simultaneously to extract the catalyst from the oxidation reaction mixture;(c) separating the oxidation reaction mixture containing benzophenone-azine after the extraction in step (b) to recover benzophenone-azine as a solution;(d) neutralizing the catalyst-containing aqueous solution separated after the extraction step (b) with ammonia and then contacting the neutralized catalyst-containing aqueous solution with benzophenone-imine to extract the catalyst into benzophenone-imine; and(e) separating the benzophenone-imine solution containing the catalyst obtained after extraction in step (d) from the aqueous layer and recycling said solution to step (a) to reuse as a catalyst for step (a), without isolating the catalyst from said benzophenone-imine solution.

摘要翻译： 公开了可以除去，回收和回收催化剂的二苯甲酮 - 吖嗪的改进方法。 该方法包括以下步骤：（a）在氯化亚铜催化剂存在下用分子氧氧化二苯甲酮 - 亚胺以产生含有二苯甲酮 - 吖嗪的氧化反应混合物; （b）将步骤（a）中获得的氧化反应混合物与含有氯化铵和盐酸的水溶液接触，基本上分解剩余的二苯甲酮 - 亚胺，而不会引起生成的二苯甲酮 - 吖嗪的分解，同时从催化剂中提取催化剂 反应混合物; （c）在步骤（b）中提取后分离含有二苯甲酮 - 吖嗪的氧化反应混合物，以二苯甲酮 - 吖嗪为溶液回收; （d）用氨中和提取步骤（b）后分离的含催化剂的水溶液，然后使中和的含有催化剂的水溶液与二苯甲酮 - 亚胺接触，将催化剂萃取到二苯甲酮 - 亚胺中; 和（e）将步骤（d）中提取后得到的含有催化剂的二苯甲酮 - 亚胺溶液从水层中分离出来，并将所述溶液再循环到步骤（a）中以再利用作为步骤（a）的催化剂，而不将催化剂从 称二苯甲酮 - 亚胺溶液。

公开(公告)号：US4130586A

公开(公告)日：1978-12-19

申请号：US827791

申请日：1977-08-25

申请人： Tomiya Isshiki ,  Tetsuo Tomita ,  Mitsuo Abe ,  Norio Takeda

发明人： Tomiya Isshiki ,  Tetsuo Tomita ,  Mitsuo Abe ,  Norio Takeda

IPC分类号： C07B61/00 ,  C07C67/00 ,  C07C241/00 ,  C07C251/24 ,  C07C119/00

摘要： An imine compound is produced by reacting a benzophenone with ammonia in the presence of 0.01 to 10% by weight of a carboxylic acid as a catalyst at a reaction temperature of 50.degree. to 350.degree. C on the basis of benzophenone. Ammonia is fed to the reaction system continuously under a pressure of 2 to 15 atmospheres. A solvent may be used for the reaction. The catalyst carboxylic acid can be readily recovered and reused without any influence of water formed by the reaction and brings about no problem of corrosion to reactor apparatus.

摘要翻译： 在二苯甲酮的基础上，在50〜350℃的反应温度下，在0.01〜10重量％的羧酸作为催化剂的存在下，使二苯甲酮与氨反应生成亚胺化合物。 在2〜15个大气压的压力下，连续向反应体系供给氨。 反应可以使用溶剂。 催化剂羧酸可以容易地回收和重复使用而不受反应形成的水的任何影响，并且不会对反应器设备产生腐蚀的问题。

公开(公告)号：US4083869A

公开(公告)日：1978-04-11

申请号：US831264

申请日：1977-09-07

申请人： Tomiya Isshiki ,  Tetsuo Tomita ,  Mitsuo Abe ,  Norio Takeda ,  Mitsuo Miura

发明人： Tomiya Isshiki ,  Tetsuo Tomita ,  Mitsuo Abe ,  Norio Takeda ,  Mitsuo Miura

IPC分类号： C07B61/00 ,  B01J21/00 ,  B01J21/02 ,  B01J21/06 ,  B01J23/00 ,  B01J23/14 ,  B01J23/16 ,  B01J23/74 ,  B01J25/00 ,  C07C67/00 ,  C07C241/00 ,  C07C251/24 ,  C07C119/00

CPC分类号： Y02P20/52

摘要： An imine compound is produced in high yield by reacting a benzophenone with ammonia in the presence of 0.01 to 100% by weight of an oxide of at least one of metals selected from the group consisting of metals of the second to fifth periods of Group III to V of the periodic Table, and iron as a catalyst at a reaction temperature of 150.degree. to 250.degree. C on the basis of benzophenone. Ammonia is fed to the reaction system continuously under a pressure of 2 to 15 atmospheres. A solvent may be used for the reaction. The catalyst metal oxide can be readily recovered and reused without any influence of water formed by the reaction.

摘要翻译： 通过使二苯甲酮与氨反应，在0.01至100重量％的至少一种金属的氧化物存在下，以高产率制备亚胺化合物，所述金属选自第III至第5周期的金属组， V，在二苯甲酮的基础上，在150〜250℃的反应温度下使用铁作为催化剂。 在2〜15个大气压的压力下，连续向反应体系供给氨。 反应可以使用溶剂。 催化剂金属氧化物可以容易地回收和再利用，而不受反应形成的水的任何影响。

公开(公告)号：US07381979B2

公开(公告)日：2008-06-03

申请号：US11472387

申请日：2006-06-22

申请人： Tsutomu Yamashita ,  Shigeji Kaneko ,  Hiroshi Saga ,  Norio Takeda

发明人： Tsutomu Yamashita ,  Shigeji Kaneko ,  Hiroshi Saga ,  Norio Takeda

IPC分类号： A61N5/00 ,  A61N5/01

CPC分类号： A61N5/1081 ,  A61N5/10 ,  A61N2005/1087

摘要： A rotating irradiation apparatus includes a rotating gantry 3 including a front ring 19 and a rear ring 20 and is provided with a beam delivery device 11 and an irradiation device 4. The beam delivery device 11 delivers an ion beam used for particle radiotherapy. Radial support devices 61A and 61B support the front ring 19 and radial support devices 61A and 61B support the rear ring 20. Each radial support device includes a linear guide 41, an upper support structure disposed above the linear guide 41, and a lower support structure disposed below the linear guide 41. The upper support structure is movably mounted on the lower support structure and is movable in the direction of the rotational axis of the rotating gantry 3.

摘要翻译： 旋转照射装置包括旋转机架3，其包括前环19和后环20，并且设置有射束输送装置11和照射装置4.射束输送装置11输送用于粒子放射治疗的离子束。 径向支撑装置61A和61B支撑前环19，并且径向支撑装置61A和61B支撑后环20.每个径向支撑装置包括线性导向件41，设置在线性导向件41上方的上支撑结构，以及 下支撑结构设置在线性引导件41的下方。上支撑结构可移动地安装在下支撑结构上并且可沿旋转机架3的旋转轴线的方向移动。

公开(公告)号：US06411641B1

公开(公告)日：2002-06-25

申请号：US09370926

申请日：1999-08-10

申请人： Kazushi Shirai ,  Norio Takeda

发明人： Kazushi Shirai ,  Norio Takeda

IPC分类号： H01S308

CPC分类号： G02F1/093 ,  H01S3/0064 ,  Y10S372/703

摘要： A high-energy laser Faraday rotator is used in an optical system in which the Faraday rotator absorbs laser light energy of more than 20 mW. The Faraday rotator includes a bismuth-substituted rare-earth iron garnet single crystal film grown as a Faraday rotator by using a liquid phase epitaxial method, and non-magnetic substrate having a side surface on which the bismuth-substituted rare-earth iron garnet single crystal film is formed.

摘要翻译： 高能激光法拉第旋转器用于其中法拉第转子吸收大于20mW的激光能量的光学系统中。 法拉第旋转器包括通过使用液相外延法生长为法拉第旋转器的铋取代的稀土铁石榴石单晶膜和具有铋取代的稀土铁石榴石单面的侧表面的非磁性基板 形成晶体膜。

公开(公告)号：US5925474A

公开(公告)日：1999-07-20

申请号：US939446

申请日：1997-09-29

申请人： Kazushi Shirai ,  Norio Takeda

发明人： Kazushi Shirai ,  Norio Takeda

IPC分类号： G02F1/09 ,  C30B29/28 ,  G02B1/02 ,  G02F1/00 ,  H01F10/24 ,  H01F41/28 ,  G11B5/66

CPC分类号： H01F10/245 ,  G02F1/0036 ,  H01F41/28 ,  Y10S428/90 ,  Y10T428/26

摘要： A BIG film for a Faraday rotator is provided with a first antireflection film on the front surface and a second antireflection on the back surface. The first and second antireflection films differ in material or thickness and therefore differ in color. The difference in color makes it possible to visually distinguish the front surface from the back surface. The antireflection films of different colors may be applied to a BIG film with a square hysteresis which retains its magnetic saturation after an external magnetic field has been removed.

摘要翻译： 用于法拉第旋转器的大片膜在前表面上设置有第一抗反射膜，在背面上设置第二抗反射膜。 第一和第二抗反射膜的材料或厚度不同，因此颜色不同。 颜色的差异使得可以在视觉上区分前表面和后表面。 不同颜色的防反射膜可以施加到具有平方滞后的BIG膜，其在去除外部磁场之后保持其磁饱和。

公开(公告)号：US5866092A

公开(公告)日：1999-02-02

申请号：US867535

申请日：1997-06-02

申请人： Tsuguo Fukuda ,  Norio Takeda

发明人： Tsuguo Fukuda ,  Norio Takeda

IPC分类号： G02F1/09 ,  C01F17/00 ,  C30B15/00 ,  C30B25/18 ,  C30B29/28

CPC分类号： C30B29/28 ,  C30B15/00 ,  G02F1/0036

摘要： A garnet crystal for growing a substrate is used for manufacturing a magneto-optic element. The garnet crystal is grown by the Czochralski method and has a chemical structure represented by Gd.sub.8-(x+y) Yb.sub.x Ga.sub.y O.sub.12 wherein x has the range 1.0.ltoreq.x.ltoreq.3.0, y has the range 2.5.ltoreq.y.ltoreq.4.5, and (x+y) has the range 5.0.ltoreq.(x+y).ltoreq.6.5. The method of manufacturing the garnet crystal for growing a magneto-optic element includes the steps of: preparing a mixture of gadolinium oxide, ytterbium oxide, and gallium oxide in a crucible by mixing the oxides together in a weight ratio such that the atomic ratio is Gd:Yb:Ga=3:p:q wherein p has the range 1.0.ltoreq.p.ltoreq.3.0 and q has the range 2.0.ltoreq.q.ltoreq.4.5; heating the mixture to make a melt of the mixture; and growing a garnet from the melt of the mixture by the Czochralski method.

摘要翻译： 用于生长衬底的石榴石晶体用于制造磁光元件。 石榴石晶体通过Czochralski法生长，并具有由Gd8-（x + y）YbxGayO12表示的化学结构，其中x的范围为1.0≤x≤3.0，y的范围为2.5≤y< = 4.5，（x + y）的范围为5.0