公开(公告)号：US4622366A

公开(公告)日：1986-11-11

申请号：US676209

申请日：1984-11-28

申请人： Takanobu Sugo ,  Jiro Okamoto ,  Isao Ishigaki ,  Akio Katakai

发明人： Takanobu Sugo ,  Jiro Okamoto ,  Isao Ishigaki ,  Akio Katakai

IPC分类号： C08F8/00 ,  B01J20/22 ,  B01J20/26 ,  C01G43/00 ,  C02F1/28 ,  C08F2/54 ,  C08F8/32 ,  C08F291/00 ,  C08F291/18 ,  C08F292/00

CPC分类号： C08F8/32

摘要： A uranium adsorbing material made of a graft polymer with a graft ratio of 20 to 100% which contains amidoxime groups and cation exchange groups in a molar ratio of 1:1 to 20:1 and a process for preparing said material are herein disclosed.

摘要翻译： 本发明公开了一种由接枝比例为20〜100％的接枝聚合物制成的铀吸附材料，该接枝聚合物含有摩尔比为1：1〜20：1的偕胺肟基和阳离子交换基团。

公开(公告)号：US06863812B2

公开(公告)日：2005-03-08

申请号：US10427942

申请日：2003-05-02

申请人： Takanobu Sugo ,  Akio Katakai ,  Noriaki Seko

发明人： Takanobu Sugo ,  Akio Katakai ,  Noriaki Seko

IPC分类号： B01J20/26 ,  B01J20/28 ,  B01J20/32 ,  C02F1/28 ,  C22B60/02 ,  D06M14/28 ,  B01D15/00

CPC分类号： B01J20/28023 ,  B01J20/26 ,  B01J20/28033 ,  B01J20/28052 ,  B01J20/3242 ,  C02F1/285 ,  C02F2101/006 ,  C02F2101/20 ,  C02F2103/08 ,  C22B3/24 ,  C22B60/0204 ,  D06M14/28 ,  Y02P10/234 ,  Y10T428/31504 ,  Y10T442/20

摘要： A collector is disclosed that is made of a polyolefin fiber having amidoxime groups and that is capable of efficient adsorptive recovery of useful metals such as uranium, vanadium, cobalt and titanium which are dissolved in small quantities in seawater. In the presence of a polymerizable monomer having a hydrophilic group, a polymerizable monomer having a cyano group is grafted to a polyolefin fiber by radiation-initiated graft polymerization to form both a hydrophilic group and a cyano group in the same graft side chains, and the cyano groups in the graft side chains are reacted with hydroxylamine to be converted to amidoxime groups, thereby producing a collector capable of recovering dissolved metals from seawater.

摘要翻译： 公开了一种由具有偕胺肟基团的聚烯烃纤维制成的收集器，其能够有效地吸附在海水中少量溶解的有用金属如铀，钒，钴和钛。 在具有亲水基团的可聚合单体的存在下，通过辐射引发的接枝聚合将具有氰基的可聚合单体接枝到聚烯烃纤维上，以在相同的接枝侧链上形成亲水基团和氰基，并且 接枝侧链中的氰基与羟胺反应以转化为偕胺肟基，从而产生能够从海水中回收溶解的金属的收集器。

公开(公告)号：US06852233B1

公开(公告)日：2005-02-08

申请号：US09926382

申请日：2000-04-25

申请人： Takanobu Sugo ,  Akio Katakai ,  Noriaki Seko ,  Shin Hasegawa ,  Kunio Fujiwara ,  Hiroshi Nagai ,  Hideo Kawazu ,  Kazuyoshi Takeda ,  Satoshi Konishi ,  Hideyuki Misawa ,  Takashi Kawakami ,  Junichi Kanno ,  Keiji Hasegawa ,  Masaji Akahori

发明人： Takanobu Sugo ,  Akio Katakai ,  Noriaki Seko ,  Shin Hasegawa ,  Kunio Fujiwara ,  Hiroshi Nagai ,  Hideo Kawazu ,  Kazuyoshi Takeda ,  Satoshi Konishi ,  Hideyuki Misawa ,  Takashi Kawakami ,  Junichi Kanno ,  Keiji Hasegawa ,  Masaji Akahori

IPC分类号： B01D15/00 ,  B01J20/26 ,  B01J20/28 ,  B01J20/32 ,  B01J20/34 ,  C02F1/28 ,  C22B3/02 ,  C22B3/24 ,  C02F1/42

CPC分类号： B01J20/28033 ,  B01D15/00 ,  B01J20/26 ,  B01J20/28004 ,  B01J20/28023 ,  B01J20/28052 ,  B01J20/3242 ,  B01J20/3475 ,  C02F1/28 ,  C02F2101/20 ,  C22B3/02 ,  C22B3/24 ,  Y02P10/234

摘要： An object of the present invention is to provide a structure of a metal collecting material for use in seawater or river water or industrial wastewater to give the most excellent adsorption efficiency. Another object of the present invention is to provide a process for efficiently separating and recovering valuable metals or noxious metals from a metal collecting material having collected said valuable metals from seawater or noxious metals from river water or wastewater with the least possible waste generation.A metal collector according to an aspect of the present invention is formed by stacking at least partially alternate layers of a fibrous metal collecting material with a spacer for introducing a liquid to be treated into said collecting material, wherein the area of spacer side faces represents 25-75% of the total area of collecting material side faces and spacer side faces in the side faces of the stack. A process for eluting and recovering a metal from a metal collecting material according to another aspect of the present invention comprises the steps: (1) contacting the metal collecting material having absorbed a metal with a dilute eluent, (2) contacting the metal collecting material with an eluent more concentrated than in step 1 to recover the metal into the eluent; and (3) contacting a metal resorbing material with the eluate from step 2 to resorb the metal.

摘要翻译： 本发明的目的是提供用于海水或河水或工业废水中的金属收集材料的结构，以获得最佳的吸附效率。 本发明的另一个目的是提供一种从金属收集材料有效地分离和回收有价值的金属或有毒金属的方法，所述金属收集材料从海水中收集所述有价值的金属或从具有最少可能的废物产生的河水或废水中吸收有毒金属。 根据本发明的一个方面的集电器是通过将纤维状金属收集材料的至少部分交替的层与用于将待处理的液体引入所述收集材料的间隔件而形成的，其中间隔件侧面的面积代表25-75 在堆叠的侧面中的收集材料侧面和间隔件侧面的总面积的百分比。 根据本发明的另一方面的从金属收集材料中洗脱和回收金属的方法包括以下步骤：（1）使吸收有金属的金属收集材料与稀释的洗脱液接触，（2）使金属收集材料 洗脱液比步骤1更浓，将金属回收到洗脱液中; 和（3）将金属吸收材料与来自步骤2的洗脱液接触以吸收金属。

公开(公告)号：US06586099B1

公开(公告)日：2003-07-01

申请号：US10266642

申请日：2002-10-09

申请人： Takanobu Sugo ,  Akio Katakai ,  Noriaki Seko

发明人： Takanobu Sugo ,  Akio Katakai ,  Noriaki Seko

IPC分类号： B01D1500

CPC分类号： B01J20/28023 ,  B01J20/26 ,  B01J20/28033 ,  B01J20/28052 ,  B01J20/3242 ,  C02F1/285 ,  C02F2101/006 ,  C02F2101/20 ,  C02F2103/08 ,  C22B3/24 ,  C22B60/0204 ,  D06M14/28 ,  Y02P10/234 ,  Y10T428/31504 ,  Y10T442/20

摘要： A collector is disclosed that is made of a polyolefin fiber having amidoxime groups and that is capable of efficient adsorptive recovery of useful metals such as uranium, vanadium, cobalt and titanium which are dissolved in small quantities in seawater. In the presence of a polymerizable monomer having a hydrophilic group, a polymerizable monomer having a cyano group is grafted to a polyolefin fiber by radiation-initiated graft polymerization to form both a hydrophilic group and a cyano group in the same graft side chains, and the cyano groups in the graft side chains are reacted with hydroxylamine to be converted to amidoxime groups, thereby producing a collector capable of recovering dissolved metals from seawater.

摘要翻译： 公开了一种由具有偕胺肟基团的聚烯烃纤维制成的收集器，其能够有效地吸附在海水中少量溶解的有用金属如铀，钒，钴和钛。 在具有亲水基团的可聚合单体的存在下，通过辐射引发的接枝聚合将具有氰基的可聚合单体接枝到聚烯烃纤维上，以在相同的接枝侧链中形成亲水基团和氰基，并且 接枝侧链中的氰基与羟胺反应以转化为偕胺肟基，从而产生能够从海水中回收溶解的金属的收集器。

公开(公告)号：US06333078B1

公开(公告)日：2001-12-25

申请号：US09460511

申请日：1999-12-14

申请人： Takanobu Sugo ,  Akio Katakai ,  Noriaki Seko

发明人： Takanobu Sugo ,  Akio Katakai ,  Noriaki Seko

IPC分类号： B05D306

CPC分类号： B01J20/28023 ,  B01J20/26 ,  B01J20/28033 ,  B01J20/28052 ,  B01J20/3242 ,  C02F1/285 ,  C02F2101/006 ,  C02F2101/20 ,  C02F2103/08 ,  C22B3/24 ,  C22B60/0204 ,  D06M14/28 ,  Y02P10/234 ,  Y10T428/31504 ,  Y10T442/20

摘要： A collector is disclosed that is made of a polyolefin fiber having amidoxime groups and that is capable of efficient adsorptive recovery of useful metals such as uranium, vanadium, cobalt and titanium which are dissolved in small quantities in seawater. In the presence of a polymerizable monomer having a hydrophilic group, a polymerizable monomer having a cyano group is grafted to a polyolefin fiber by radiation-initiated graft polymerization to form both a hydrophilic group and a cyano group in the same graft side chains, and the cyano groups in the graft side chains are reacted with hydroxylamine to be converted to amidoxime groups, thereby producing a collector capable of recovering dissolved metals from seawater.

摘要翻译： 公开了一种由具有偕胺肟基团的聚烯烃纤维制成的收集器，其能够有效地吸附在海水中少量溶解的有用金属如铀，钒，钴和钛。 在具有亲水基团的可聚合单体的存在下，通过辐射引发的接枝聚合将具有氰基的可聚合单体接枝到聚烯烃纤维上，以在相同的接枝侧链中形成亲水基团和氰基，并且 接枝侧链中的氰基与羟胺反应以转化为偕胺肟基，从而产生能够从海水中回收溶解的金属的收集器。

公开(公告)号：US20080271277A1

公开(公告)日：2008-11-06

申请号：US12081819

申请日：2008-04-22

申请人： Norihito Mizote ,  Akio Katakai ,  Masao Tamada

发明人： Norihito Mizote ,  Akio Katakai ,  Masao Tamada

IPC分类号： B60S1/38 ,  C08L51/04 ,  C08F2/46

CPC分类号： C08J7/18 ,  B60S1/38 ,  B60S2001/3829 ,  C08J2321/00

摘要： A rubber product for wiping, a rubber for a wiper blade, a method for producing a rubber for a wiper blade, and a wiper unit. The rubber product for wiping, for example, includes a hydrophilic gel-like surface treatment layer coated on at least a wiping surface of the rubber product, wherein the wiping surface is softer due to water absorption when moistened than when dried.

摘要翻译： 用于擦拭的橡胶制品，刮水片用橡胶，刮水片用橡胶的制造方法以及刮水装置。 用于擦拭的橡胶制品例如包括涂覆在橡胶制品的至少擦拭表面上的亲水性凝胶状表面处理层，其中当润湿时的擦拭表面比干燥时更吸湿。

公开(公告)号：US08227522B2

公开(公告)日：2012-07-24

申请号：US11826288

申请日：2007-07-13

申请人： Norihito Mizote ,  Akio Katakai ,  Masao Tamada

发明人： Norihito Mizote ,  Akio Katakai ,  Masao Tamada

IPC分类号： C08F4/46 ,  C08J3/28 ,  B60S1/06 ,  B60S1/38

CPC分类号： B60S1/38 ,  B60S2001/3829 ,  C08F253/00 ,  C08F279/02 ,  C08J3/28 ,  C08L51/04 ,  C08L2666/02

摘要： A surface-modified blade rubber includes a surface modified by being subjected to irradiation treatment that generates radical active sites in the blade rubber and polymerization for graft polymerization starting from a generated radical active site. A method for modifying a blade rubber surface includes subjecting rubber of a blade rubber to irradiation treatment that generates radical active sites and polymerization for graft polymerization starting from a generated radical active site.

摘要翻译： 表面改性的刮板橡胶包括通过经受辐照处理而改性的表面，其在所述刮片橡胶中产生自由基活性位点，并且从所产生的活性位点开始接枝聚合的聚合。 用于改变叶片橡胶表面的方法包括：从所产生的活性部位开始，对刮片橡胶的橡胶进行产生自由基活性部位的辐射处理和接枝聚合的聚合。

公开(公告)号：US20080016644A1

公开(公告)日：2008-01-24

申请号：US11826288

申请日：2007-07-13

申请人： Norihito Mizote ,  Akio Katakai ,  Masao Tamada

发明人： Norihito Mizote ,  Akio Katakai ,  Masao Tamada

IPC分类号： B60S1/38 ,  C08F2/46

CPC分类号： B60S1/38 ,  B60S2001/3829 ,  C08F253/00 ,  C08F279/02 ,  C08J3/28 ,  C08L51/04 ,  C08L2666/02

摘要： A surface-modified blade rubber includes a surface modified by being subjected to irradiation treatment that generates radical active sites in the blade rubber and polymerization for graft polymerization starting from a generated radical active site. A method for modifying a blade rubber surface includes subjecting rubber of a blade rubber to irradiation treatment that generates radical active sites and polymerization for graft polymerization starting from a generated radical active site.

摘要翻译： 表面改性的刮板橡胶包括通过经受辐照处理而改性的表面，其在所述刮片橡胶中产生自由基活性位点，并且从所产生的活性位点开始接枝聚合的聚合。 用于改变叶片橡胶表面的方法包括：从所产生的活性部位开始，对刮片橡胶的橡胶进行产生自由基活性部位的辐射处理和接枝聚合的聚合。

公开(公告)号：US4332657A

公开(公告)日：1982-06-01

申请号：US94882

申请日：1979-11-16

申请人： Keizo Makuuchi ,  Akio Katakai ,  Miyuki Hagiwara ,  Tsutomu Yamamoto ,  Hiroyuki Nakayama ,  Tohru Takagi

发明人： Keizo Makuuchi ,  Akio Katakai ,  Miyuki Hagiwara ,  Tsutomu Yamamoto ,  Hiroyuki Nakayama ,  Tohru Takagi

IPC分类号： C08F220/56 ,  C08F2/46 ,  C08F2/54 ,  C09D125/08 ,  C09D133/02 ,  C09D133/06 ,  C09D133/26 ,  C08L33/08 ,  C08L33/10

CPC分类号： C09D133/26 ,  C08F2/46 ,  C09D125/08 ,  C09D133/066 ,  Y10S522/912 ,  Y10T428/26 ,  Y10T428/31699

摘要： An emulsion composition for use in baking paint prepared by emulsion polymerization with ionizing radiation of a monomer mixture comprising (1) at least one acrylamide selected from the group consisting of N-methylolacrylamide and N-alkoxymethylacrylamide, (2) a radical polymerizable ethylenic unsaturated monomer having a hydroxyl group, and (3) a radical polymerizable ethylenic unsaturated monomer other than (1) and (2) above.

摘要翻译： 一种用于通过使用单体混合物的电离辐射的乳液聚合制备的烘烤涂料中的乳液组合物，其包含（1）至少一种选自N-羟甲基丙烯酰胺和N-烷氧基甲基丙烯酰胺的丙烯酰胺，（2）可自由基聚合的烯属不饱和单体 具有羟基，（3）除上述（1）和（2）以外的自由基聚合性烯属不饱和单体。