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公开(公告)号：US08663493B2
公开(公告)日：2014-03-04
申请号：US13202240
申请日：2010-04-20
IPC分类号： C04B35/495 , H01L41/187 , H01L41/24
CPC分类号： H01L41/1871 , C04B35/495 , C04B35/6262 , C04B2235/3208 , C04B2235/3215 , C04B2235/3251 , C04B2235/3262 , C04B2235/3298 , C04B2235/5445 , C04B2235/6027 , C04B2235/656 , C04B2235/76 , C04B2235/77 , C04B2235/787 , H01L41/27 , H01L41/43
摘要： Provided is an oriented piezoelectric material with satisfactory sintering property free of Pb that is a hazardous substance, and a water-soluble alkaline ion, and a production method therefor. To this end, provided is a compound, including a tungsten bronze structure metal oxide, in which: the tungsten bronze structure metal oxide contains at least metal elements of Ba, Bi, Ca, and Nb, the metal elements satisfying the following conditions in terms of molar ratio; and has a C-axis orientation. The compound shows Ba/Nb=a: 0.363
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公开(公告)号：US08518290B2
公开(公告)日：2013-08-27
申请号：US12509043
申请日：2009-07-24
申请人： Takayuki Watanabe , Takanori Matsuda , Hiroshi Saito , Hiroshi Funakubo , Nobuhiro Kumada , Takashi Iijima , Bong-Yeon Lee
发明人： Takayuki Watanabe , Takanori Matsuda , Hiroshi Saito , Hiroshi Funakubo , Nobuhiro Kumada , Takashi Iijima , Bong-Yeon Lee
IPC分类号： C04B35/495 , C04B35/00 , H01L41/187 , H01L41/18 , C09K5/00
CPC分类号： H01L41/187 , C04B35/495 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3289 , C04B2235/3298 , C04B2235/3852 , C04B2235/72 , C04B2235/76 , C04B2235/761 , C04B2235/77 , C04B2235/785
摘要： Provided is a piezoelectric material which includes a compound free of lead and alkali metal and has a good piezoelectric property. The piezoelectric material where tungsten bronze structure oxides being free of lead and alkali metal and represented by AxB10O30 and A′x′B′10O30 are combined to form a morphotropic phase boundary has good piezoelectric property. The AxB10O30 is b(Ba5−5αBi10α/3Nb10O30)+(1−b)(Ba4Ag2Nb10O30) (0≦b≦1 and 0
摘要翻译： 提供一种压电材料，其包含不含铅和碱金属的化合物，并具有良好的压电性能。 钨青铜结构氧化物不含铅和碱金属并由AxB10O30和A'x'B'10O30表示的压电材料组合形成具有良好压电性能的光子相。 AxB10O30是b（Ba5-5alphaBi10alpha / 3Nb10O30）+（1-b）（Ba4Ag2Nb10O30）（0 @ b @ 1和0≤0.4），A'x'B'10O30是c（Sr5Nb10O30）+ d （Ca5Nb10O30）+ e（Ba5Nb10O30）（0 @ c @ 0.8,0 @ d @ 0.4,0.1 @ e @ 0.9和c + d + e = 1）。
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公开(公告)号：US20110297870A1
公开(公告)日：2011-12-08
申请号：US13202240
申请日：2010-04-20
CPC分类号： H01L41/1871 , C04B35/495 , C04B35/6262 , C04B2235/3208 , C04B2235/3215 , C04B2235/3251 , C04B2235/3262 , C04B2235/3298 , C04B2235/5445 , C04B2235/6027 , C04B2235/656 , C04B2235/76 , C04B2235/77 , C04B2235/787 , H01L41/27 , H01L41/43
摘要： Provided is an oriented piezoelectric material with satisfactory sintering property free of Pb that is a hazardous substance, and a water-soluble alkaline ion, and a production method therefor. To this end, provided is a compound, including a tungsten bronze structure metal oxide, in which: the tungsten bronze structure metal oxide contains at least metal elements of Ba, Bi, Ca, and Nb, the metal elements satisfying the following conditions in terms of molar ratio; and has a C-axis orientation. The compound shows Ba/Nb=a: 0.363
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公开(公告)号：US20100025618A1
公开(公告)日：2010-02-04
申请号：US12509043
申请日：2009-07-24
申请人： Takayuki Watanabe , Takanori Matsuda , Hiroshi Saito , Hiroshi Funakubo , Nobuhiro Kumada , Takashi Iijima , Bong-Yeon Lee
发明人： Takayuki Watanabe , Takanori Matsuda , Hiroshi Saito , Hiroshi Funakubo , Nobuhiro Kumada , Takashi Iijima , Bong-Yeon Lee
IPC分类号： H01L41/18
CPC分类号： H01L41/187 , C04B35/495 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3289 , C04B2235/3298 , C04B2235/3852 , C04B2235/72 , C04B2235/76 , C04B2235/761 , C04B2235/77 , C04B2235/785
摘要： Provided is a piezoelectric material which includes a compound free of lead and alkali metal and has a good piezoelectric property. The piezoelectric material where tungsten bronze structure oxides being free of lead and alkali metal and represented by AxB10O30 and A′x′B′10O30 are combined to form a morphotropic phase boundary has good piezoelectric property. The AxB10O30 is b(Ba5−5αBi10α/3Nb10O30)+(1−b)(Ba4Ag2Nb10O30) (0≦b≦1 and 0
摘要翻译： 提供一种压电材料，其包含不含铅和碱金属的化合物，并具有良好的压电性能。 钨青铜结构氧化物不含铅和碱金属并由AxB10O30和A'x'B'10O30表示的压电材料组合形成具有良好压电性能的光子相。 AxB10O30是b（Ba5-5alphaBi10alpha / 3Nb10O30）+（1-b）（Ba4Ag2Nb10O30）（0 <= b <= 1和0 <α<= 0.4），A'x'B'10O30是c（Sr5Nb10O30 ）+ d（Ca5Nb10O30）+ e（Ba5Nb10O30）（0≤c≤0.8,0≤d≤0.4,0.1≤e≤0.9，c + d + e = 1）。
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公开(公告)号：US08702885B2
公开(公告)日：2014-04-22
申请号：US13638356
申请日：2011-04-15
CPC分类号： H01L41/43 , B28B1/008 , B28B1/26 , B28B11/12 , B32B18/00 , C01G25/006 , C01G33/006 , C04B35/4682 , C04B35/495 , C04B35/6261 , C04B2235/3208 , C04B2235/3215 , C04B2235/3251 , C04B2235/3262 , C04B2235/3298 , C04B2235/5436 , C04B2235/5445 , C04B2235/6027 , C04B2235/605 , C04B2235/76 , C04B2235/77 , C04B2235/787 , C04B2237/345 , H01L41/1871
摘要： A method of manufacturing ceramics includes: placing, on a base material, a first slurry in which a metal oxide powder is dispersed; applying a magnetic field to the first slurry to solidify the first slurry, thereby forming an under coat layer made of a first compact; placing, on the under coat layer, a second slurry containing a metal oxide powder constituting the ceramics; applying a magnetic field to the second slurry to solidify the second slurry, thereby forming a second compact to obtain a laminated body of the second compact and the under coat layer; and obtaining the ceramics made of the second compact by removing the under coat layer from the laminated body of the second compact and the under coat layer and then sintering the second compact, or sintering the laminated body of the second compact and the under coat layer and then removing the under coat layer.
摘要翻译： 制造陶瓷的方法包括：在基材上放置分散有金属氧化物粉末的第一浆料; 向第一浆料施加磁场以固化第一浆料，由此形成由第一压块制成的底涂层; 在下涂层上放置含有构成陶瓷的金属氧化物粉末的第二浆料; 向第二浆料施加磁场以固化第二浆料，从而形成第二压块以获得第二压块和下涂层的层压体; 通过从第二压块和下涂层的层叠体中除去下涂层，然后烧结第二压块，或者烧结第二压块和下涂层的层压体，从而获得由第二压模制成的陶瓷， 然后除去底涂层。
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公开(公告)号：US20130029181A1
公开(公告)日：2013-01-31
申请号：US13638356
申请日：2011-04-15
CPC分类号： H01L41/43 , B28B1/008 , B28B1/26 , B28B11/12 , B32B18/00 , C01G25/006 , C01G33/006 , C04B35/4682 , C04B35/495 , C04B35/6261 , C04B2235/3208 , C04B2235/3215 , C04B2235/3251 , C04B2235/3262 , C04B2235/3298 , C04B2235/5436 , C04B2235/5445 , C04B2235/6027 , C04B2235/605 , C04B2235/76 , C04B2235/77 , C04B2235/787 , C04B2237/345 , H01L41/1871
摘要： A method of manufacturing ceramics includes: placing, on a base material, a first slurry in which a metal oxide powder is dispersed; applying a magnetic field to the first slurry to solidify the first slurry, thereby forming an under coat layer made of a first compact; placing, on the under coat layer, a second slurry containing a metal oxide powder constituting the ceramics; applying a magnetic field to the second slurry to solidify the second slurry, thereby forming a second compact to obtain a laminated body of the second compact and the under coat layer; and obtaining the ceramics made of the second compact by removing the under coat layer from the laminated body of the second compact and the under coat layer and then sintering the second compact, or sintering the laminated body of the second compact and the under coat layer and then removing the under coat layer.
摘要翻译： 制造陶瓷的方法包括：在基材上放置分散有金属氧化物粉末的第一浆料; 向第一浆料施加磁场以固化第一浆料，由此形成由第一压块制成的底涂层; 在下涂层上放置含有构成陶瓷的金属氧化物粉末的第二浆料; 向第二浆料施加磁场以固化第二浆料，从而形成第二压块以获得第二压块和下涂层的层压体; 通过从第二压块和下涂层的层叠体中除去下涂层，然后烧结第二压块，或者烧结第二压块和下涂层的层压体，从而获得由第二压模制成的陶瓷， 然后除去底涂层。
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公开(公告)号：US07931821B2
公开(公告)日：2011-04-26
申请号：US12639473
申请日：2009-12-16
申请人： Hiroshi Saito , Takanori Matsuda , Kaoru Miura , Kenji Takashima , Masaki Azuma , Takashi Iijima , Hiroshi Funakubo , Soichiro Okamura , Nobuhiro Kumada , Satoshi Wada
发明人： Hiroshi Saito , Takanori Matsuda , Kaoru Miura , Kenji Takashima , Masaki Azuma , Takashi Iijima , Hiroshi Funakubo , Soichiro Okamura , Nobuhiro Kumada , Satoshi Wada
IPC分类号： C04B35/495 , C04B35/00
CPC分类号： H01L41/187 , C01B21/0821 , C01P2002/34 , C01P2002/77 , C04B35/58 , C04B35/58014 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3232 , C04B2235/3236 , C04B2235/3244 , C04B2235/3287 , C04B2235/3293 , C04B2235/3298 , C04B2235/3418 , C04B2235/3873 , C04B2235/3886 , C04B2235/3895 , C04B2235/465 , C04B2235/6025 , C04B2235/761 , C04B2235/765 , C04B2235/768 , C04B2235/787 , H01L41/43
摘要： An oxynitride piezoelectric material, which exhibits ferroelectricity and has good piezoelectric properties, and a method of producing the oxynitride piezoelectric material. The oxynitride piezoelectric material includes a tetragonal perovskite-type oxynitride represented by the following general formula (1): A1−xBix+δ1B1−yB′y+δ2O3−zNz (1), where A represents a divalent element, B and B′ each represent a tetravalent element, x represents a numerical value of 0.35 or more to 0.6 or less, y represents a numerical value of 0.35 or more to 0.6 or less, z represents a numerical value of 0.35 or more to 0.6 or less, and δ1 and δ2 each represent a numerical value of −0.2 or more to 0.2 or less, in which the A includes at least one kind selected from Ba, Sr, and Ca and the B and the B′ each include at least one kind selected from Ti, Zr, Hf, Si, Ge, and Sn.
摘要翻译： 表现出铁电性并且具有良好的压电性能的氮氧化合物压电材料以及氮氧化合物压电材料的制造方法。 氮氧化物压电材料包括由以下通式（1）表示的四方晶系钙钛矿型氧氮化物：A1-xBix +δ1B1-yB'y +δ2O3-zNz（1）其中A表示二价元素，B和B'各自 表示四价元素，x表示0.35以上且0.6以下的数值，y表示0.35以上且0.6以下的数值，z表示0.35以上且0.6以下的数值，δ表示 δ2分别表示-0.2以上0.2以下的数值，其中A包含选自Ba，Sr，Ca中的至少一种，B和B'分别为选自Ti， Zr，Hf，Si，Ge和Sn。
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公开(公告)号：US20100155647A1
公开(公告)日：2010-06-24
申请号：US12639473
申请日：2009-12-16
申请人： Hiroshi Saito , Takanori Matsuda , Kaoru Miura , Kenji Takashima , Masaki Azuma , Takashi Iijima , Hiroshi Funakubo , Soichiro Okamura , Nobuhiro Kumada , Satoshi Wada
发明人： Hiroshi Saito , Takanori Matsuda , Kaoru Miura , Kenji Takashima , Masaki Azuma , Takashi Iijima , Hiroshi Funakubo , Soichiro Okamura , Nobuhiro Kumada , Satoshi Wada
IPC分类号： H01L41/187
CPC分类号： H01L41/187 , C01B21/0821 , C01P2002/34 , C01P2002/77 , C04B35/58 , C04B35/58014 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3232 , C04B2235/3236 , C04B2235/3244 , C04B2235/3287 , C04B2235/3293 , C04B2235/3298 , C04B2235/3418 , C04B2235/3873 , C04B2235/3886 , C04B2235/3895 , C04B2235/465 , C04B2235/6025 , C04B2235/761 , C04B2235/765 , C04B2235/768 , C04B2235/787 , H01L41/43
摘要： Provided are an oxynitride piezoelectric material which exhibits ferroelectricity and has good piezoelectric properties and a method of producing the oxynitride piezoelectric material. The oxynitride piezoelectric material includes a tetragonal perovskite-type oxynitride represented by the following general formula (1): A1-xBix+δ1B1-yB′y+δ2O3-zNz (1) where A represents a divalent element, B and B′ each represent a tetravalent element, x represents a numerical value of 0.35 or more to 0.6 or less, y represents a numerical value of 0.35 or more to 0.6 or less, z represents a numerical value of 0.35 or more to 0.6 or less, and δ1 and δ2 each represent a numerical value of −0.2 or more to 0.2 or less, in which the A includes at least one kind selected from Ba, Sr, and Ca and the B and the B′ each include at least one kind selected from Ti, Zr, Hf, Si, Ge, and Sn.
摘要翻译： 本发明提供一种表现出铁电性并且具有良好的压电性能的氮氧化合物压电材料以及制造氮氧化合物压电材料的方法。 氮氧化物压电材料包括由以下通式（1）表示的四方晶系钙钛矿型氧氮化物：A1-xBix +δ1B1-yB'y +δ2O3-zNz（1）其中A表示二价元素，B和B'各自表示 四价元素，x表示0.35以上且0.6以下的数值，y表示0.35以上且0.6以下的数值，z表示0.35以上且0.6以下的数值，δ1和δ2 各自表示-0.2以上至0.2以下的数值，其中A包括选自Ba，Sr和Ca中的至少一种，B和B'各自包含选自Ti，Zr中的至少一种 ，Hf，Si，Ge和Sn。
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公开(公告)号：US08547001B2
公开(公告)日：2013-10-01
申请号：US13202212
申请日：2010-03-30
IPC分类号： H01L41/08
CPC分类号： C30B29/24 , B82Y30/00 , C04B35/26 , C04B35/2666 , C04B35/2675 , C04B35/4682 , C04B35/6263 , C04B2235/3215 , C04B2235/3236 , C04B2235/3255 , C04B2235/3274 , C04B2235/3275 , C04B2235/3291 , C04B2235/3298 , C04B2235/5454 , C04B2235/6027 , C04B2235/605 , C04B2235/656 , C04B2235/762 , C04B2235/768 , C04B2235/77 , C04B2235/787 , C30B28/00 , C30B30/04 , H01L41/1878 , H01L41/43
摘要： To provide a piezoelectric ceramic containing BiFeO3 having a {110} plane orientation in a pseudo-cubic form, which is suited for the domain engineering, the piezoelectric ceramic includes a perovskite-type metal oxide represented by the following general formula (1), and has a {110} plane orientation in a pseudo-cubic form: xBiFeO3-(1−x)ABO3 General Formula (1) where A and B each represent one kind or more of metal ions; A represents a metal ion having a valence of 1, 2 or 3; and B represents a metal ion having a valence of 3, 4, or 5, provided that x is within a range of 0.3≦x≦1.
摘要翻译： 为了提供一种适用于领域工程的具有假立方形{110}面取向的BiFeO 3的压电陶瓷，压电陶瓷包括由以下通式（1）表示的钙钛矿型金属氧化物，和 具有假立方形的{110}平面取向：xBiFeO3-（1-x）ABO3一般式（1）其中A和B各自表示一种或多种金属离子; A表示化合价为1,2或3的金属离子; 并且B表示具有3,4或5价的金属离子，条件是x在0.3 @ x @的范围内。
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公开(公告)号：US20110298336A1
公开(公告)日：2011-12-08
申请号：US13202212
申请日：2010-03-30
IPC分类号： H01L41/187 , H01L41/04 , B29C70/00 , B29C35/08 , B29C67/04
CPC分类号： C30B29/24 , B82Y30/00 , C04B35/26 , C04B35/2666 , C04B35/2675 , C04B35/4682 , C04B35/6263 , C04B2235/3215 , C04B2235/3236 , C04B2235/3255 , C04B2235/3274 , C04B2235/3275 , C04B2235/3291 , C04B2235/3298 , C04B2235/5454 , C04B2235/6027 , C04B2235/605 , C04B2235/656 , C04B2235/762 , C04B2235/768 , C04B2235/77 , C04B2235/787 , C30B28/00 , C30B30/04 , H01L41/1878 , H01L41/43
摘要： To provide a piezoelectric ceramic containing BiFeO3 having a {110} plane orientation in a pseudo-cubic form, which is suited for the domain engineering, the piezoelectric ceramic includes a perovskite-type metal oxide represented by the following general formula (1), and has a {110} plane orientation in a pseudo-cubic form: xBiFeO3-(1-x)ABO3 General Formula (1) where A and B each represent one kind or more of metal ions; A represents a metal ion having a valence of 1, 2 or 3; and B represents a metal ion having a valence of 3, 4, or 5, provided that x is within a range of 0.3≦x≦1.
摘要翻译： 为了提供一种适用于领域工程的具有假立方形{110}面取向的BiFeO 3的压电陶瓷，压电陶瓷包括由以下通式（1）表示的钙钛矿型金属氧化物，和 具有假立方形的{110}平面取向：xBiFeO3-（1-x）ABO3通式（1）其中A和B各自表示一种或多种金属离子; A表示化合价为1,2或3的金属离子; 并且B表示具有3,4或5价的金属离子，条件是x在0.3≤n1E的范围内; x和nlE; 1。
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