公开(公告)号：US5618621A

公开(公告)日：1997-04-08

申请号：US453476

申请日：1995-05-30

申请人： Kinji Hasegawa ,  Takeo Asai ,  Mitsumasa Ono ,  Yoji Murakami

发明人： Kinji Hasegawa ,  Takeo Asai ,  Mitsumasa Ono ,  Yoji Murakami

IPC分类号： B32B27/36 ,  C09J7/02

CPC分类号： B32B27/36 ,  Y10T428/28 ,  Y10T428/2878 ,  Y10T428/31786

摘要： A biaxially oriented laminated polyester film comprising (A) a first layer formed from a first copolyester which is composed of ethylene terephthalate unit as a main recurring unit, and (B) a second layer formed from a polyester composition containing (B1) a second copolyester which is composed of ethylene terephthalate unit as a main recurring unit and (B2) a third (co)polyester which is composed of butylene terephthalate unit as a main recurring unit and is contained in an amount of 1 to 40% by weight or (B3) a filler having an average particle diameter of 2.5 .mu.m or less and is contained in an amount of 5 to 80% by weight in place of the third (co)polyester (B3), the second layer being to constitute a surface to be bonded onto a metal surface when the laminated film is laminated on the metal sheet. This composition can give metal cans, e.g., beverage cans and food cans, excellent in heat resistance, resistance to embrittlement under retort treatment, favor retention, impact resistance and anticorrosive properties.

摘要翻译： 一种双轴取向叠层聚酯薄膜，包括（A）由作为主要重复单元的对苯二甲酸乙二醇酯单元构成的第一共聚酯形成的第一层和（B）由聚酯组合物形成的第二层，所述聚酯组合物含有（B1）第二共聚酯 由作为主要重复单元的对苯二甲酸乙二醇酯单元构成，（B2）由作为主要重复单元的对苯二甲酸丁二醇酯单元构成的含有1〜40重量％的（B2）的第（共）聚酯， ）平均粒径为2.5μm以下的填料，代替第三（共）聚酯（B3）而含有5〜80重量％的填料，第二层构成表面 当层压膜层压在金属板上时，粘合到金属表面上。 该组合物可以给出金属罐，例如饮料罐和食品罐，其耐热性优异，在蒸煮处理下耐脆性，有利于保留，耐冲击性和耐腐蚀性。

公开(公告)号：US5814385A

公开(公告)日：1998-09-29

申请号：US617759

申请日：1996-03-15

申请人： Takeo Asai ,  Kinji Hasegawa ,  Mitsumasa Ono

发明人： Takeo Asai ,  Kinji Hasegawa ,  Mitsumasa Ono

IPC分类号： B32B27/36 ,  B32B1/02 ,  B32B15/08 ,  B32B27/08

CPC分类号： B32B27/36 ,  Y10T428/1355 ,  Y10T428/24355 ,  Y10T428/24975 ,  Y10T428/25 ,  Y10T428/31786

摘要： A laminated polyester film comprising an aromatic copolyester layer having a surface roughness of 2 to 13 nm and a polyester layer having a surface roughness (Ra) of at least 15 nm. This laminated polyester film has improved impact resistance particularly at low temperatures and improved taste-retaining property while retaining the excellent moldability, heat resistance, retort sterilization resistance and flavor-retaining property possessed by copolyester films.

摘要翻译： PCT No.PCT / JP94 / 01185 Sec。 371日期：1996年3月15日 102（e）1996年3月15日PCT PCT 1994年7月19日PCT公布。 公开号WO96 / 02387 日期：1996年2月1日，包括表面粗糙度为2〜13nm的芳香族共聚酯层和表面粗糙度（Ra）为15nm以上的聚酯层的层压聚酯膜。 该层压聚酯薄膜特别是在低温下具有改善的耐冲击性，并且在保持共聚酯薄膜所具有的优异的成型性，耐热性，耐蒸煮灭菌性和香味保持性的同时，具有改善的保持性。

公开(公告)号：US5686510A

公开(公告)日：1997-11-11

申请号：US339876

申请日：1994-11-10

申请人： Takeo Asai ,  Kinji Hasegawa ,  Mitsumasa Ono

发明人： Takeo Asai ,  Kinji Hasegawa ,  Mitsumasa Ono

IPC分类号： B29C55/12 ,  B29K67/00 ,  B29L7/00 ,  B32B15/08 ,  B32B15/09 ,  B32B27/36 ,  C08J5/18 ,  C08K3/00 ,  C08K3/22 ,  C08K3/36 ,  C08L67/00 ,  C08L67/02 ,  B32B27/06

CPC分类号： C08J5/18 ,  B32B15/08 ,  B32B27/36 ,  C08K3/22 ,  C08K3/36 ,  C08J2367/02 ,  Y10T428/1355 ,  Y10T428/31681 ,  Y10T428/31786

摘要： A biaxially oriented polyester film made of a polyester composition, (A) which polyester composition comprises (a) an aromatic copolyester having a melting point of 210-245.degree. C., (b) first inert fine solid particles having an average particle diameter of 0.05 to 0.6 .mu.m, and (c) second inert fine solid particles having an average particle diameter of 0.3 to 2.5 .mu.m, the ratio of the average particle diameter of the second inert fine solid particles to the average particle diameter of the first inert fine solid particles being at least 2.5, and the amounts of the components (b) and (c) being 0.01 to 3% by weight and 0.001 to 0.2% by weight, respectively, based on the total weight of the components (a), (b) and (c); (B) which polyester film has a plane orientation coefficient of 0.08 to 0.16; and, (C) which polyester film shows excellent moldability when laminated onto a metal sheet and subjected to deep drawing. A can for drinks, foods, etc. having excellent heat resistance and flavor-retaining property can be produced from a metal sheet onto which the above biaxially oriented polyester film is laminated.

摘要翻译： 一种由聚酯组合物制成的双轴取向聚酯膜，（A）该聚酯组合物包含（a）熔点为210-245℃的芳族共聚酯，（b）平均粒径为 0.05〜0.6μm，和（c）平均粒径为0.3〜2.5μm的第二惰性细粒固体颗粒，第二惰性微粒固体颗粒的平均粒径与第一惰性微粒固体颗粒的平均粒径之比 细固体颗粒为至少2.5，并且组分（b）和（c）的量分别为基于组分（a）的总重量的0.01至3重量％和0.001至0.2重量％ （b）和（c）; （B）该聚酯薄膜的平面取向系数为0.08〜0.16; 和（C）当层压到金属片上并进行深冲压时，该聚酯膜显示出优异的成型性。 可以由层叠上述双轴取向聚酯膜的金属板制造具有优异的耐热性和香味保持性的饮料，食品等的罐。

公开(公告)号：US5885689A

公开(公告)日：1999-03-23

申请号：US735207

申请日：1996-10-22

申请人： Kinji Hasegawa ,  Takeo Asai ,  Mitsumasa Ono ,  Takafumi Kudo

发明人： Kinji Hasegawa ,  Takeo Asai ,  Mitsumasa Ono ,  Takafumi Kudo

IPC分类号： B32B15/08 ,  B65D65/40 ,  C08J5/18 ,  B32B27/08 ,  B32B27/20 ,  B32B27/36

CPC分类号： C08J5/18 ,  B32B15/08 ,  C08J2367/02 ,  Y10S428/91 ,  Y10T428/1355 ,  Y10T428/24355 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/24975 ,  Y10T428/25 ,  Y10T428/269 ,  Y10T428/31681 ,  Y10T428/31786

摘要： A laminated polyester film for use as a film to be laminated on a metal plate, which comprises (A) a first layer formed of (a1) a first aromatic copolyester prepared in the presence of a germanium compound as a polymerization catalyst, which contains terephthalic acid as the main dicarboxylic acid component and ethylene glycol as the main glycol component and which has a melting point in the range of from 210.degree. to 245.degree. C. and a glass transition temperature of at least 60.degree. C., the first layer having (a2) a surface roughness (Ra) in the range of from 2 to 13 nm, and (B) a second layer formed of (b1) a polyester composition obtained by melt-mixing 90 to 45% by weight of a second aromatic copolyester which is composed, as a main recurring unit, of ethylene terephthalate, is produced in the presence of a germanium compound as a polymerization catalyst and has a melting point in the range of from 210.degree. to 252.degree. C. and 10 to 55% by weight of a third aromatic polyester which is composed, as a main recurring unit, of tetramethylene terephthalate and has a melting point in the range of from 180.degree. to 223.degree. C., the second layer having (b2) a surface roughness (Ra) of 15 to 50 nm; and (C) which exhibits excellent moldability when a metal plate laminated therewith is deep-drawn.

摘要翻译： 一种用作层压在金属板上的膜的叠层聚酯膜，其包含（A）由（a1）在作为聚合催化剂的锗化合物存在下制备的第一芳族共聚酯形成的第一层，所述第一芳族共聚酯含有对苯二甲酸 酸作为主要二羧酸组分和乙二醇作为主要二醇组分，其熔点范围为210-245℃，玻璃化转变温度为至少60℃，第一层具有 （a2）表面粗糙度（Ra）在2〜13nm的范围内，（B）由（b1）聚酯组合物形成的第二层，所述聚酯组合物通过将90〜45重量％的第二芳族共聚酯 在作为聚合催化剂的锗化合物存在下制备作为主要重复单元的对苯二甲酸乙二醇酯，其熔点范围为210〜252℃，10〜55％的熔点为 第三种芳族聚酯的重量 作为主要重复单元形成对苯二甲酸丁二醇酯，其熔点在180〜223℃的范围内，第二层的（b2）表面粗糙度（Ra）为15〜50nm; 和（C），当其层压的金属板被深拉时，其成型性优异。

公开(公告)号：US5384354A

公开(公告)日：1995-01-24

申请号：US119100

申请日：1993-09-15

申请人： Kinji Hasegawa ,  Takeo Asai ,  Yoji Murakami

发明人： Kinji Hasegawa ,  Takeo Asai ,  Yoji Murakami

IPC分类号： B29C55/12 ,  B32B15/08 ,  C08J5/18 ,  C08L67/02 ,  C08K3/08 ,  C08K3/26 ,  C08K3/34

CPC分类号： C08J5/18 ,  B29C55/12 ,  B32B15/08 ,  C08L67/02 ,  B29K2067/00 ,  B29K2105/16 ,  C08J2367/02 ,  Y10T428/31681

摘要： The present invention provides a polyester film for processing of a metal sheet, which shows excellent molding-processability when it is laminated onto a metal sheet and the laminated metal sheet is made into a can by deep drawing or the like and which is suitable and useful for production of a metal can having excellent heat resistance, impact resistance and flavor-retaining property.A polyester film used for lamination onto a metal sheet for processing of said metal sheet, characterized in that the film is formed from 99 to 60% by weight of a copolyester, as the component A, having an ethylene terephthalate unit as the main recurring unit and having a melting point of 210 to 245.degree. C. and 1 to 40% by weight of a polybutylene terephthalate or a copolyester, as the component B, having a butylene terephthalate unit as the main recurring unit and having a melting point of 180 to 223.degree. C., and further comprising a lubricant having an average particle diameter of 2.5 .mu.m or less; and that the film has a plane orientation coefficient of 0.08 to 0.16, a heat shrinkage at 150.degree. C. of 10% or less and a density of less than 1.385 g/cm.sup.3 : and use thereof.

摘要翻译： PCT No.PCT / JP93 / 00041 Sec。 371日期：1993年9月15日 102（e）1993年9月15日PCT 1993年1月14日PCT PCT。 出版物WO93 / 14152 日期：1993年7月22日。本发明提供一种金属板的加工用聚酯膜，其在层压在金属板上时成型加工性优异，层压金属板通过深冲制成罐， 并且适用于制造具有优异的耐热性，耐冲击性和香味保持性的金属罐。 一种用于层压在金属片上以用于加工所述金属片的聚酯膜，其特征在于，该膜由共聚酯99重量％至60重量％作为组分A，其具有对苯二甲酸乙二醇酯单元作为主要重复单元 熔点为210〜245℃，1〜40重量％的聚对苯二甲酸丁二醇酯或共聚酯作为成分B，以对苯二甲酸丁二醇酯单元为主要重复单元，熔点为180〜 223℃，还含有平均粒径为2.5μm以下的润滑剂; 该薄膜的平面取向系数为0.08〜0.16，150℃的热收缩率为10％以下，密度为1.385g / cm 3以下。

公开(公告)号：US5372867A

公开(公告)日：1994-12-13

申请号：US756304

申请日：1991-09-06

申请人： Kinji Hasegawa ,  Tadashi Ono ,  Takeo Asai ,  Yoji Murakami

发明人： Kinji Hasegawa ,  Tadashi Ono ,  Takeo Asai ,  Yoji Murakami

IPC分类号： B29C55/00 ,  B29D7/01 ,  B32B15/08 ,  C08J5/18 ,  B32B3/00

CPC分类号： C08J5/18 ,  B29C55/005 ,  B29D7/01 ,  B32B15/08 ,  B29K2067/00 ,  B29K2105/16 ,  B29K2995/0072 ,  C08J2367/00 ,  Y10T428/24355 ,  Y10T428/249953 ,  Y10T428/25 ,  Y10T428/259 ,  Y10T428/31681 ,  Y10T428/31786

摘要： A polyester film for metal sheet lamination processing which comprises a co-polyester containing a lubricant having an average particle diameter of 2.5 .mu.m or less and the co-polyester having a melting point of 210.degree. to 245.degree. C.; and wherein the refractive index in the direction of film thickness is 1.505 to 1.550, the refractive index in the direction of the film plane is 1.61 to 1.66 about all directions, subpeak by DSC is 150.degree. to 205.degree. C., and optionally, protrusions on the film surface satisfy the formula0.1.ltoreq.Nd/N.ltoreq.0.5wherein N is the number of all the protrusions on the film surface and Nd is the number of the protrusions each containing the lubricant as its nucleus and having a sunk hollow around it.

摘要翻译： 一种金属片层压处理用聚酯膜，其包含含有平均粒径为2.5μm以下的润滑剂的共聚酯和熔点为210〜245℃的共聚酯。 并且其中膜厚方向的折射率为1.505〜1.550，膜面方向的折射率在所有方向为1.61〜1.66，通过DSC表示的亚峰为150〜205℃，可选地，突起 在膜表面上满足公式0.1

公开(公告)号：US5780158A

公开(公告)日：1998-07-14

申请号：US684935

申请日：1996-07-19

申请人： Takeo Asai ,  Takafumi Kudo ,  Koji Kubo ,  Yukihiko Minamihira ,  Kinji Hasegawa

发明人： Takeo Asai ,  Takafumi Kudo ,  Koji Kubo ,  Yukihiko Minamihira ,  Kinji Hasegawa

IPC分类号： B32B15/08 ,  B32B27/36 ,  C08J5/18

CPC分类号： B32B15/08 ,  Y10T428/31507 ,  Y10T428/31681 ,  Y10T428/31786

摘要： A biaxially oriented film to be laminated on a metal, which is a laminate film comprising (A) a first layer of a polyester comprising ethylene terephthalate as a main recurring unit; and (B) a second layer formed from a composition of a polycarbonate and polyesters, the polycarbonate and the polyesters being each contained in amounts of 20 to 50% by weight and 50 to 80% by weight based on the total thereof; the polyesters consisting essentially of a first polyester comprising ethylene terephthalate as a main recurring unit and having a terminal carboxyl group concentration of more than 5 eq./10.sup.6 g and a second polyester comprising butylene terephthalate as a main recurring unit and having a terminal carboxyl group concentration of less than 20 eq./10.sup.6 g; and the first and second polyesters being each contained in an amount of 10 to 90% by weight based on the total thereof; and in which (C) the plane orientation coefficients of the first layer and second layer are both in the range of 0.05 to 0.10.

摘要翻译： 一种层压在金属上的双轴取向膜，它是层压膜，它包括（A）第一层包含对苯二甲酸乙二醇酯作为主要重复单元的聚酯; 和（B）由聚碳酸酯和聚酯的组合物形成的第二层，聚碳酸酯和聚酯的含量相对于其总量为20〜50重量％和50〜80重量％ 所述聚酯基本上由包含对苯二甲酸乙二醇酯作为主要重复单元并且具有大于5当量/ 10g的末端羧基浓度的第一聚酯和包含对苯二甲酸丁二醇酯作为主要重复单元并具有末端羧基的第二聚酯 浓度小于20当量/ 10 6 g; 所述第一和第二聚酯的含量相对于其总量为10〜90重量％ 并且其中（C）第一层和第二层的平面取向系数都在0.05至0.10的范围内。

公开(公告)号：US5473004A

公开(公告)日：1995-12-05

申请号：US277703

申请日：1994-07-20

申请人： Tadashi Ono ,  Kinji Hasegawa ,  Takeo Asai ,  Yoji Murakami

发明人： Tadashi Ono ,  Kinji Hasegawa ,  Takeo Asai ,  Yoji Murakami

IPC分类号： C08J5/18 ,  C08K3/00 ,  B29C55/00 ,  C08J3/00 ,  C08K3/26 ,  C08L67/02

CPC分类号： C08J5/18 ,  C08K3/0008 ,  C08J2367/02

摘要： A biaxially oriented polyester film comprising a copolyester which contains a lubricant having an average particle diameter of no greater than 2.5 .mu.m and has a melting point of from 210.degree. to 245.degree. C., the film having a plane orientation coefficient of from 0.10 to 0.16, a thermal shrinkage at 150.degree. C. of no higher than 10%, and a density of lower than 1.385 g/cm.sup.3, and optionally a refractive index in a direction of thickness of from 1.495 to 1.530 as well as a film plane refractive index of from 1.61 to 1.66 in all directions.

摘要翻译： 一种双轴取向聚酯膜，其包含含有平均粒径不大于2.5μm并且熔点为210-245℃的润滑剂的共聚酯，该膜的平面取向系数为0.10〜 0.16，在150℃下的热收缩率不高于10％，密度低于1.385g / cm 3，并且可选地在厚度方向上的折射率为1.495至1.530，以及膜平面折射率 指数从1.61到1.66的全方位。

公开(公告)号：US06180254B2

公开(公告)日：2001-01-30

申请号：US09179428

申请日：1998-10-27

申请人： Makoto Handa ,  Mitsumasa Ono ,  Takeo Asai ,  Hiroshi Tomita ,  Kenji Suzuki

发明人： Makoto Handa ,  Mitsumasa Ono ,  Takeo Asai ,  Hiroshi Tomita ,  Kenji Suzuki

IPC分类号： G11B566

CPC分类号： C08K3/22 ,  C08J5/18 ,  C08J2377/00 ,  C08K3/26 ,  G11B5/733 ,  Y10S428/90 ,  Y10T428/31725 ,  C08L77/00

摘要： A biaxially oriented film made from a wholly aromatic polyamide produced by an acid chloride process, which contains at least one member of inorganic particles having an average particle diameter of 5 to 2,000 nm and selected from the group consisting of hydroxides, carbonates and bicarbonates of metals of groups Ia and IIa of the periodic table. The inorganic particles is derived from inorganic particles which are added as a neutralizing agent to a reaction system to neutralize hydrogen chloride by-produced by the acid chloride reaction and its content corresponds to an excess portion added to the reaction system over the amount required for neutralizing the hydrogen chloride stoichiometrically. The film is useful as a base film for a magnetic recording medium, such as a coated, a multi-layer coated, or a thin metal film high-density magnetic recording medium.

摘要翻译： 由通过酰氯制造的全芳族聚酰胺制成的双轴取向膜，其含有至少一种平均粒径为5至2,000nm的无机颗粒，并且选自金属的氢氧化物，碳酸盐和碳酸氢盐 的周期表的Ia和IIa族。 无机颗粒源自作为中和剂加入到反应体系中的中和无机颗粒，以中和氯化反应产生的氯化氢，其含量相当于反应体系中过量的中和量所需的量 化学计量的氯化氢。 该膜可用作磁记录介质的基膜，例如涂覆的，多层涂覆的或薄的金属膜高密度磁记录介质。

公开(公告)号：US06344257B1

公开(公告)日：2002-02-05

申请号：US09445772

申请日：1999-12-13

申请人： Makoto Handa ,  Mitsumasa Ono ,  Takeo Asai

发明人： Makoto Handa ,  Mitsumasa Ono ,  Takeo Asai

IPC分类号： G11B566

CPC分类号： G11B5/733 ,  G11B5/73 ,  G11B5/738 ,  Y10S428/90 ,  Y10T428/24355 ,  Y10T428/24942 ,  Y10T428/25 ,  Y10T428/26

摘要： An aromatic polyamide film for a high-density magnetic recording medium which has excellent electromagnetic conversion characteristics and few drop outs even when it is used as a base film for a deposited metal thin film magnetic recording medium and enables the production of a large-capacity magnetic recording medium. An aromatic polyamide film for a high-density magnetic recording medium which has surface flatness and excellent transferability, is thereby useful as a base film especially for a high-density magnetic recording medium and can satisfy contradictory requirements, that is, the prevention of a trouble such as projection of protrusions in a calendering step and winding easiness at the same time.

摘要翻译： 一种用于高密度磁记录介质的芳族聚酰胺薄膜，即使在用作沉积的金属薄膜磁记录介质的基底膜时也具有优异的电磁转换特性和几滴，并且能够生产大容量磁 具有表面平坦性和转印性优异的高密度磁记录介质用芳香族聚酰胺薄膜可用作特别用于高密度磁记录介质的基膜，可以满足矛盾的要求，即防止 存在诸如在压延步骤中突起突出并且同时卷绕容易的麻烦。