摘要:
A nonaqueous secondary battery having a negative electrode containing a silicon active material and a nonaqueous solvent containing a fluorine-containing solvent. The active material layer has a fluorine content of 5 to 30 wt % based on the silicon content after at least 100 charge/discharge cycles at a rate of 50% or more of the battery's capacity. The battery is suitably produced by a method including applying a slurry containing silicon active material particles to a current collector, electroplating the resulting coating layer using a plating bath at a pH higher than 7 to coat at least part of the surface of the particles with copper, acid washing the coating layer to make a negative electrode, assembling the negative electrode together with a positive electrode, a separator, and a nonaqueous electrolyte containing a fluorine-containing solvent into a nonaqueous secondary battery, and subjecting the battery to a first charge operation at a low rate of 0.005 to 0.03 C.
摘要:
Disclosed is a negative electrode for a nonaqueous secondary battery comprised of a current collector and an active material structure containing an electro-conductive material having low capability of forming a lithium compound on at least one side of the current collector, the active material structure containing 5 to 80% by weight of active material particles containing a material having high capability of forming a lithium compound. The active material structure preferably has an active material layer containing the active material particles and a surface coating layer formed on the active material layer.
摘要:
Disclosed is a negative electrode for a nonaqueous secondary battery included of a current collector and an active material structure containing an electro-conductive material having low capability of forming a lithium compound on at least one side of the current collector, the active material structure containing 5 to 80% by weight of active material particles containing a material having high capability of forming a lithium compound. The active material structure preferably has an active material layer containing the active material particles and a surface coating layer formed on the active material layer.
摘要:
A negative electrode for nonaqueous secondary batteries is disclosed. The negative electrode has a pair of current collecting surface layers of which the surfaces are adapted to be brought into contact with an electrolyte and at least one active material layer interposed between the surface layers. The active material layer contains particles of an active material having high capability of forming a lithium compound. The material constituting the surfaces is preferably present over the whole thickness of the active material layer to electrically connect the surfaces so that the electrode exhibits a current collecting function as a whole. The surface layers each preferably have a thickness of 0.3 to 10 μm.
摘要:
An anode for nonaqueous secondary batteries is disclosed. The anode has a pair of current collecting surface layers of which the surfaces are adapted to be brought into contact with an electrolytic solution and at least one active material layer interposed between the surface layers. The active material layer contains particles of an active material having high capability of forming a lithium compound. The material constituting the surfaces is preferably present over the whole thickness of the active material layer to electrically connect the surfaces so that the electrode exhibits a current collecting function as a whole. The surface layers each preferably have a thickness of 0.3 to 10 μm.
摘要:
A negative electrode 10 for a nonaqueous secondary battery has an active material layer 12 containing active material particles 12a. The particles 12a are coated at least partially with a metallic material 13 having low capability of lithium compound formation. The active material layer 12 has voids located between the metallic material-coated particles 12a with a void fraction of 15% to 45%. The metallic material 13 on the surface of the particles is preferably present throughout the thickness of the active material layer. The active material particles 12a are preferably of a silicon-based material. The active material layer 12 preferably contains 1% to 3% by weight of an electroconductive carbon material based on the weight of the active material particles 12a.
摘要:
A negative electrode (10) for use in a non-aqueous electrolyte secondary battery comprises an active material layer (12) containing a particle (12a) of an active material. At least a part of the surface of the particle (12a) is coated with a metal material (13) having a poor ability of forming a lithium compound. A void is formed between the particles (12a) that are coated with the metal material (13). The active material layer has a void ratio of 15 to 45%. Preferably, the metal material (13) is present over the entire area of such a part of the surface of the particle that extends in the thickness-wise direction of the active material layer. Also preferably, the particle (12a) of the active material is composed of a silicone material, and the active material layer (12) contains a conductive carbon material in an amount of 1 to 3% by weight relative to the weight amount of the particle (12a) of the active material.
摘要:
[Object] A safe hydrogen storage tank in a highly reliable form where it is difficult for fatigue failure to occur is provided as a hydrogen storage tank where a cartridge is filled with a hydrogen occluding substance and contained within an integrally molded liner made of a metal.[Means for Achieving Object] A cartridge 10 is formed of a cartridge main body portion 11, a fixed side axial portion 13 and a free side axial portion 12, and an integrally molded liner 20 which is seamless is formed of a liner torso portion 21, a fixed side end portion 25 where a fixed side opening 25a is created via a portion in dome form 24 and a free side end portion 23 where a free side opening 23a for supporting a support plug 30 is created via a portion in dome form 22 in order to support a free side axial portion 12a, in such a manner that the fixed side opening 25a fixes and supports the fixed side axial portion 13 and is sealed by a sealing plug 40 while the free side opening 23a is sealed by the support plug 30, and the free side axial portion 12 is inserted into and supported by the recess 31 created in the support plug 30 so as to be moveable forward and backward in the direction of the axial line.
摘要:
A negative electrode 10 for a nonaqueous secondary battery, has an active material layer 2 containing active material particles 2a. The active material layer 2 has a metallic material 4 deposited among the particles by electroplating. The negative electrode 10 has a large number of holes 5 open on at least one side thereof and extending through the thickness of the active material layer. The negative electrode 10 further has a pair of current collecting layers 3a and 3b adapted to be brought into contact with an electrolyte. The active material layer 2 is between the current collecting layers 3a and 3b. The holes 5 open on the negative electrode 10 preferably have an opening area ratio of 0.3% to 30%. At least one of the pair of the current collecting layers 3a and 3b preferably has a thickness of 0.3 to 10 μm.
摘要:
A cylindrical reinforcing collar is fitted onto a cylindrical gas discharge section of a tank body and then engaged integrally on the exterior of the tank body between the cylindrical gas discharge section and the dome section by shrink fitting. This provides, easily and inexpensively, a high-pressure tank capable of withstanding high pressures of 35 to 75 MPa while keeping its lightness in weight.