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1.
公开(公告)号:US20130066091A1
公开(公告)日:2013-03-14
申请号:US13697038
申请日:2011-05-19
CPC分类号: C07B41/12 , C07C29/62 , C07C29/86 , C07C67/08 , C07C67/10 , C07C67/11 , C07C67/58 , C07C31/36 , C07C69/63 , C07C69/78
摘要: A process for producing a chlorohydrin, an ester of a chlorohydrin, or a mixture thereof including the steps of contacting, in a hydrochlorination reactor, a multihydroxylated aliphatic hydrocarbon, an ester of a multihydroxylated aliphatic hydrocarbon, or a mixture thereof with a source of a hydrogen chloride, in the presence of a hydrophobic or extractable carboxylic acid catalyst is provided.
摘要翻译: 一种生产氯代醇,氯代醇酯或其混合物的方法,包括以下步骤:在氢氯化反应器中将多羟基化脂族烃,多羟基化脂族烃或其混合物的酯与 提供了在疏水性或可提取的羧酸催化剂存在下的氯化氢。
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2.
公开(公告)号:US09067845B2
公开(公告)日:2015-06-30
申请号:US13697038
申请日:2011-05-19
IPC分类号: C07C51/363 , C07C69/76 , C07C69/02 , C07B41/12 , C07C29/62 , C07C29/86 , C07C67/11 , C07C67/58 , C07C67/08 , C07C67/10
CPC分类号: C07B41/12 , C07C29/62 , C07C29/86 , C07C67/08 , C07C67/10 , C07C67/11 , C07C67/58 , C07C31/36 , C07C69/63 , C07C69/78
摘要: A process for producing a chlorohydrin, an ester of a chlorohydrin, or a mixture thereof including the steps of contacting, in a hydrochlorination reactor, a multihydroxylated aliphatic hydrocarbon, an ester of a multihydroxylated aliphatic hydrocarbon, or a mixture thereof with a source of a hydrogen chloride, in the presence of a hydrophobic or extractable carboxylic acid catalyst is provided.
摘要翻译: 一种生产氯代醇,氯代醇酯或其混合物的方法,包括以下步骤:在氢氯化反应器中将多羟基化脂族烃,多羟基化脂族烃或其混合物的酯与 提供了在疏水性或可提取的羧酸催化剂存在下的氯化氢。
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3.
公开(公告)号:US20130109872A1
公开(公告)日:2013-05-02
申请号:US13808594
申请日:2011-06-28
申请人: Tina L. Arrowood , John F. Ford , Derrick W. Flick
发明人: Tina L. Arrowood , John F. Ford , Derrick W. Flick
IPC分类号: C07D301/32
CPC分类号: C07D301/32 , B01J19/245 , B01J2219/24 , C07D301/12 , C07D301/36
摘要: There is provided a process for manipulating the amount of alkyl alcohol in a product stream, e.g., such as an alkylene oxide product stream. More particularly, and in contrast to conventional processes wherein substantially all of the alkyl alcohol must be separated and desirably recycled, in the present process, a greater amount of alkyl alcohol may be allowed to remain in a partially refined alkylene oxide product stream. The residual alkyl alcohol is subsequently substantially entirely reacted to form a downstream product, e.g., a glycol ether, which is more easily separated from the alkylene oxide product stream. Indeed, the amount of alkyl alcohol in the partially refined alkylene oxide product stream can be selected based upon the output of glycol ethers, if desired.
摘要翻译: 提供了一种操纵产物流中烷基醇的量的方法,例如烯化氧产物流。 更具体地,与其中基本上所有烷基醇必须分离并期望再循环的常规方法相反,在本方法中,可以使更多量的烷基醇保留在部分精制的环氧烷产物流中。 残留的烷基醇随后基本上完全反应以形成下游产物,例如乙二醇醚,其更容易从环氧烷产物流中分离出来。 实际上,如果需要,可以基于二醇醚的输出来选择部分精制的环氧烷产物流中的烷基醇的量。
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4.
公开(公告)号:US09169226B2
公开(公告)日:2015-10-27
申请号:US13808594
申请日:2011-06-28
IPC分类号: C07D301/32 , C07D301/36
CPC分类号: C07D301/32 , B01J19/245 , B01J2219/24 , C07D301/12 , C07D301/36
摘要: There is provided a process for manipulating the amount of alkyl alcohol in a product stream, e.g., such as an alkylene oxide product stream. More particularly, and in contrast to conventional processes wherein substantially all of the alkyl alcohol must be separated and desirably recycled, in the present process, a greater amount of alkyl alcohol may be allowed to remain in a partially refined alkylene oxide product stream. The residual alkyl alcohol is subsequently substantially entirely reacted to form a downstream product, e.g., a glycol ether, which is more easily separated from the alkylene oxide product stream. Indeed, the amount of alkyl alcohol in the partially refined alkylene oxide product stream can be selected based upon the output of glycol ethers, if desired.
摘要翻译: 提供了一种操纵产物流中烷基醇的量的方法,例如烯化氧产物流。 更具体地,与其中基本上所有烷基醇必须分离并期望再循环的常规方法相反,在本方法中,可以使更多量的烷基醇保留在部分精制的环氧烷产物流中。 残留的烷基醇随后基本上完全反应以形成下游产物,例如乙二醇醚,其更容易从环氧烷产物流中分离出来。 实际上,如果需要,可以基于二醇醚的输出来选择部分精制的环氧烷产物流中的烷基醇的量。
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公开(公告)号:US08907137B2
公开(公告)日:2014-12-09
申请号:US13144958
申请日:2010-02-25
申请人: Philip J. Carlberg , Thomas C. Young , Tina L. Arrowood , Ernesto Occhiello , Paul R. Elowe , Jason C. MacDonald
发明人: Philip J. Carlberg , Thomas C. Young , Tina L. Arrowood , Ernesto Occhiello , Paul R. Elowe , Jason C. MacDonald
CPC分类号: C08G65/38 , C08G2650/56
摘要: A process comprising contacting a polyhydric phenol or a polyaliphatic alcohol with an epihalohydrin in the presence of a catalyst comprising a Schiff base metal complex is disclosed.
摘要翻译: 公开了一种方法,其包括在包含席夫贱金属络合物的催化剂的存在下使多元酚或多脂族醇与表卤代醇接触。
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公开(公告)号:US20110301366A1
公开(公告)日:2011-12-08
申请号:US13144958
申请日:2010-02-25
申请人: Philip J. Carlberg , Thomas C. Young , Tina L. Arrowood , Ernesto Occhiello , Paul R. Elowe , Jason C. MacDonald
发明人: Philip J. Carlberg , Thomas C. Young , Tina L. Arrowood , Ernesto Occhiello , Paul R. Elowe , Jason C. MacDonald
IPC分类号: C07D301/28 , C07C41/14
CPC分类号: C08G65/38 , C08G2650/56
摘要: A process comprising contacting a polyhydric phenol or a polyaliphatic alcohol with an epihalohydrin in the presence of a catalyst comprising a Schiff base metal complex is disclosed.
摘要翻译: 公开了一种方法,其包括在包含席夫贱金属络合物的催化剂的存在下使多元酚或多脂族醇与表卤代醇接触。
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公开(公告)号:US20110297877A1
公开(公告)日:2011-12-08
申请号:US13142060
申请日:2010-02-25
申请人: Tina L. Arrowood , Marty W. Degroot , Paul R. Elowe , Derrick W. Flick , Jason C. MacDonald , Peter N. Nickias , Daniel E. Verral
发明人: Tina L. Arrowood , Marty W. Degroot , Paul R. Elowe , Derrick W. Flick , Jason C. MacDonald , Peter N. Nickias , Daniel E. Verral
IPC分类号: C09K3/00
CPC分类号: B01J31/2243 , B01J21/08 , B01J31/1633 , B01J31/2252 , B01J2231/34 , B01J2231/349 , B01J2531/0216 , B01J2531/0252 , B01J2531/845 , C07C41/03 , C07C41/44 , C07C43/13
摘要: A process of contacting an alkylene oxide with 2-methoxy-1-propanol (PM1) in the presence of an oligomeric Schiff base metal complex catalyst is disclosed. Further, a process involving contacting an alkylene oxide with an alkyl alcohol using an oligomeric Schiff base metal complex as a catalyst is also disclosed. Additionally, novel compositions which can be used as catalysts in processes involving the contacting of an alkyl alcohol with an alkylene oxide are also disclosed.
摘要翻译: 公开了在低聚希夫碱金属配合物催化剂存在下使烯化氧与2-甲氧基-1-丙醇(PM1)接触的方法。 此外,还公开了使用低聚希夫碱金属络合物作为催化剂使烯化氧与烷基醇接触的方法。 此外,还公开了可用作烷烃与环氧烷接触的方法中的催化剂的新型组合物。
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公开(公告)号:US09630149B2
公开(公告)日:2017-04-25
申请号:US14407366
申请日:2013-07-03
申请人: Abhishek Roy , Tina L. Arrowood , Anand S. Badami , Robert C. Cieslinski , David D. Hawn , Steven D. Jons , Mou Paul , Steven Rosenberg , Huang Wu
发明人: Abhishek Roy , Tina L. Arrowood , Anand S. Badami , Robert C. Cieslinski , David D. Hawn , Steven D. Jons , Mou Paul , Steven Rosenberg , Huang Wu
IPC分类号: B01D71/56 , B01D39/14 , B01D29/00 , B05D5/00 , B01D67/00 , B01D69/12 , B01D61/02 , B01D69/10
CPC分类号: B01D67/0006 , B01D61/025 , B01D67/0002 , B01D69/10 , B01D69/12 , B01D69/125 , B01D71/56 , B01D2323/00 , B01D2323/38 , B01D2323/40 , B01D2325/20
摘要: A thin film composite polyamide membrane having a porous support and a thin film polyamide layer comprising a reaction product of m-phenylene diamine (mPD) and trimesoyl chloride (TMC), characterized by the thin film polyamide layer having a critical strain value of less than 10%. In another embodiment, the thin film polyamide layer has a modulus of greater than 0.75 (GPa). In yet another embodiment, the thin film polyamide layer has an equilibrium swelling value of at least 45%. In another embodiment, the thin film polyamide layer has a thickness of at least 230 nm.
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公开(公告)号:US20150165387A1
公开(公告)日:2015-06-18
申请号:US14407366
申请日:2013-07-03
申请人: Abhishek Roy , Tina L. Arrowood , Anand S. Badami , Robert C. Cieslinski , David D. Hawn , Steven D. Jons , Mou Paul , Steven Rosenberg , Huang Wu
发明人: Abhishek Roy , Tina L. Arrowood , Anand S. Badami , Robert C. Cieslinski , David D. Hawn , Steven D. Jons , Mou Paul , Steven Rosenberg , Huang Wu
CPC分类号: B01D67/0006 , B01D61/025 , B01D67/0002 , B01D69/10 , B01D69/12 , B01D69/125 , B01D71/56 , B01D2323/00 , B01D2323/38 , B01D2323/40 , B01D2325/20
摘要: A thin film composite polyamide membrane having a porous support and a thin film polyamide layer comprising a reaction product of m-phenylene diamine (mPD) and trimesoyl chloride (TMC), characterized by the thin film polyamide layer having a critical strain value of less than 10%. In another embodiment, the thin film polyamide layer has a modulus of greater than 0.75 (GPa). In yet another embodiment, the thin film polyamide layer has an equilibrium swelling value of at least 45%. In another embodiment, the thin film polyamide layer has a thickness of at least 230 nm.
摘要翻译: 一种具有多孔载体的薄膜复合聚酰胺膜和包含间苯二胺(mPD)和均苯三酰氯(TMC)的反应产物的薄膜聚酰胺层,其特征在于薄膜聚酰胺层的临界应变值小于 10%。 在另一个实施方案中,薄膜聚酰胺层的模量大于0.75(GPa)。 在另一个实施方案中,薄膜聚酰胺层具有至少45%的平衡溶胀值。 在另一个实施方案中,薄膜聚酰胺层具有至少230nm的厚度。
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公开(公告)号:US08835348B2
公开(公告)日:2014-09-16
申请号:US13142297
申请日:2010-02-25
IPC分类号: B01J23/32 , B01J27/24 , C07C41/03 , B01J31/22 , C07C41/44 , B01J23/00 , B01J27/00 , C08G59/68 , B01J21/08
CPC分类号: B01J31/2243 , B01J21/08 , B01J31/1633 , B01J31/2252 , B01J2231/34 , B01J2231/349 , B01J2531/0216 , B01J2531/0252 , B01J2531/845 , C07C41/03 , C07C41/44 , C07C43/13
摘要: A process of contacting an alkylene oxide with 2-methoxy-1-propanol (PM1) in the presence of an oligomeric Schiff base metal complex catalyst is disclosed. Further, a process involving contacting an alkylene oxide with an alkyl alcohol using an oligomeric Schiff base metal complex as a catalyst is also disclosed. Additionally, novel compositions which can be used as catalysts in processes involving the contacting of an alkyl alcohol with an alkylene oxide are also disclosed.
摘要翻译: 公开了在低聚希夫碱金属配合物催化剂存在下使烯化氧与2-甲氧基-1-丙醇(PM1)接触的方法。 此外,还公开了使用低聚希夫碱金属络合物作为催化剂使烯化氧与烷基醇接触的方法。 此外,还公开了可用作烷烃与环氧烷接触的方法中的催化剂的新型组合物。
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