Abstract:
A gas-barrier packaging material including: a support; an adhesive layer laminated on the support; a first barrier layer laminated on the adhesive layer; a second barrier layer laminated on the first barrier layer; and a protective layer formed of a coating liquid that contains a polyvalent metal compound, a polyester based resin, and a dispersant that is a sodium salt of a polycarboxylic acid based resin, the protective layer being laminated on the second barrier layer. In the gas-barrier packaging material, the protective layer contains the polyvalent metal compound by about 40 to 90 wt % relative to 100 wt % of the protective layer. When the second barrier layer is separated and an infrared absorption spectrum of the second barrier layer after separation is measured by a transmission method, a ratio between a maximum peak height α in a range of about 1,490 to about 1,659 cm−1 and a maximum peak height β in a range of about 1,660 to about 1,750 cm−1 as expressed by α/β is less than about one.
Abstract:
A gas barrier packaging material precursor, includes a support; an adhesion layer on one surface of the support; and a barrier layer and a protective layer formed adjacent each other on the adhesion layer. The adhesion layer contains a silicon compound composite. The protective layer is formed of a coating liquid containing a polyvalent metal compound, a polyester resin, and a dispersant, with the polyvalent metal compound being about 40 to about 90 mass % relative to 100 mass % . When the barrier layer is separated from the gas barrier packaging material precursor to measure an infrared absorption spectrum of the barrier layer by a transmission method, a ratio (α/β) of a maximum peak height (α) of absorbance in a range of about 1490 to about 1659 cm−1 to a maximum peak height (β) of absorbance in a range of about 1660 to about 1750 cm−1 is less than about 1.
Abstract:
A gas-barrier laminate film (5) which includes a film base material (1), a layer (2) that contains an inorganic compound (A) and is formed on one surface of the film base material, and two layers formed on the layer that contains the inorganic compound (A) so as to be adjacent to each other, wherein the two layers are made up of a layer (3) that contains a carboxylic acid polymer (B) and a layer (4) that contains at least one selected from a group consisting of a silicon compound (C) represented by the following general formula (I) and a hydrolysate thereof, and a vinyl alcohol polymer (D): Si(OR1)4 (I) (where R1 represents an alkyl group with 1-4 carbon atoms, and the four R1s may be identical or different).
Abstract:
This coating solution for a gas barrier contains an ammonium salt (A) of a polymer having a carboxyl group, a particulate multivalent metallic compound (B), and water, the content of the multivalent metallic compound (B) being about 0.5-2.0 times the chemical equivalent of the ammonium salt (A), and the mean particle diameter of the multivalent metallic compound (B) being about 4 μm or less.