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    Molded composite article and process for producing the same
    1.
    发明申请
    Molded composite article and process for producing the same 有权
    成型复合制品及其制造方法

    公开(公告)号：US20070172670A1

    公开(公告)日：2007-07-26

    申请号：US11579960

    申请日：2005-05-01

    申请人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

    发明人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

    IPC分类号： B32B27/00

    CPC分类号： C08L77/00 ,  B29C45/0001 ,  B29C45/1657 ,  B29C45/1676 ,  B29C47/0004 ,  B29C47/0021 ,  B29C49/0005 ,  B29C51/002 ,  B29C65/02 ,  B29C66/71 ,  B29C66/712 ,  B29C66/7212 ,  B29C66/73152 ,  B29C66/7392 ,  B29C66/91411 ,  B29K2075/00 ,  B29K2077/00 ,  B29K2101/12 ,  B29K2995/007 ,  C08G2410/00 ,  C08L75/04 ,  C08L2666/20 ,  B29C65/00 ,  B29K2309/08 ,  B29K2067/00

    摘要： In a molded composite article formed by directly bonding a resin member comprising a polyamide-series resin to a resin member comprising a thermoplastic polyurethane-series resin, the polyamide-series resin comprises a polyamide block copolymer containing (A) a polyether segment having at least one terminal imino group. The polyamide-series resin may comprise a polyamide-series resin having a free amino group in a concentration of not less than about 10 mmol/kg. The molded composite article is producible, for example, by heating at least one of the polyamide-series resin and the thermoplastic polyurethane-series resin to bond the former to the latter. Thus obtained molded composite article is suitable for a member of a shoe and an industrial roll. In such a process, the polyamide-series resin member and the thermoplastic polyurethane-series resin member both of which are different in nature from each other can be directly and firmly bonded together.

    摘要翻译： 在通过将包含聚酰胺系树脂的树脂构件直接结合到包含热塑性聚氨酯系树脂的树脂构件而形成的模制复合制品中，所述聚酰胺系树脂包含聚酰胺嵌段共聚物，所述聚酰胺嵌段共聚物含有（A）至少具有至少 一个终端亚氨基组。 聚酰胺系树脂可以含有游离氨基浓度不低于约10mmol / kg的聚酰胺系树脂。 成型复合制品例如可以通过加热聚酰胺系树脂和热塑性聚氨酯系树脂中的至少一种来将前者粘合到后者。 这样获得的模制复合制品适用于鞋和工业辊的构件。 在这种方法中，两者彼此之间的性质不同的聚酰胺系树脂部件和热塑性聚氨酯系树脂部件可以直接且牢固地结合在一起。

    Composite material and method for preparation thereof
    2.
    发明授权
    Composite material and method for preparation thereof 有权
    复合材料及其制备方法

    公开(公告)号：US07175916B2

    公开(公告)日：2007-02-13

    申请号：US10221680

    申请日：2002-01-09

    申请人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda

    发明人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda

    IPC分类号： B32B25/08

    CPC分类号： B32B27/20 ,  B32B5/08 ,  B32B25/08 ,  B32B27/285 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/40 ,  B32B2367/00 ,  B32B2375/00 ,  C08J5/121 ,  Y10T428/31511 ,  Y10T428/31554 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/31569 ,  Y10T428/31576 ,  Y10T428/3158 ,  Y10T428/31587 ,  Y10T428/31594 ,  Y10T428/31598 ,  Y10T428/31663 ,  Y10T428/31728 ,  Y10T428/31732 ,  Y10T428/31736 ,  Y10T428/31739 ,  Y10T428/31743 ,  Y10T428/31746 ,  Y10T428/3175 ,  Y10T428/31757 ,  Y10T428/31761 ,  Y10T428/31786 ,  Y10T428/31797 ,  Y10T428/31826 ,  Y10T428/31833 ,  Y10T428/31859 ,  Y10T428/31862 ,  Y10T428/3187 ,  Y10T428/31931 ,  Y10T428/31935 ,  Y10T428/31938

    摘要： A composite of a resin member bonded to a vulcanized rubber member is obtained with using a rubber member vulcanized with a radical-generating agent (e.g., an organic peroxide) and a thermoplastic resin having at least 2 atoms, on average, selected from H and S atom per molecule, each atom having not less than 0.006 of an orbital interaction energy coefficient S represented by the following formula (1): S=(CHOMO,n)2/|Ec−EHOMO,n|+(CLUMO,n)2/|Ec−ELUMO,n|   (1) wherein Ec: an orbital energy (eV) of a radical, CHOMO,n: a molecular-orbital coefficient of a highest occupied molecular orbital (HOMO) of an n-th H or S atom constituting a basic unit of the resin, EHOMO,n: an orbital energy (eV) of the HOMO, CLUMO,n: a molecular-orbital coefficient of a lowest unoccupied molecular orbital (LUMO) of the n-th H or S atom constituting the basic unit of the resin, ELUMO,n: an orbital energy (eV) of the LUMO, and above all represent a value calculated by a semiempirical molecular orbital method MOPACPM3. The thermoplastic resin includes a polyamide, a polyester, a PPE, a POM, a PPS, a polyolefinic resins, and the unvulcanized rubber may comprise a vulcanization-activating having plural polymerizable unsaturated bonds. The invention gives the composite of the resin bonded directly to the rubber firmly without adhesives in wide combinations of the resin and the rubber.

    摘要翻译： 使用与自由基发生剂（例如有机过氧化物）硫化的橡胶构件和平均具有至少2个原子的热塑性树脂，可以获得与硫化橡胶构件接合的树脂构件的复合物，所述热塑性树脂平均选自H和 S原子/分子，每个原子具有不小于0.006的由下式（1）表示的轨道相互作用能量系数S：<？in-line-formula description =“In-line Formulas”end =“lead”？> S =（C HOMO，n）2 HOMO，n + H（C（C） LUMO，N，N，N，C，C，C， （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中E c是基团的轨道能量（eV），C < HOMO，n H：构成树脂的基本单位的第n个H或S原子的最高占据分子轨道（HOMO）的分子轨道系数，HOMO，n < ：HOMO的轨道能量（eV），LUMO，n是构成基本单位的第n个H或S原子的最低未占分子轨道（LUMO）的分子轨道系数 的树脂，LUMO，n LUMO的轨道能量（eV），并且首先代表通过半经验分子轨道法MOPACPM3计算的值。 热塑性树脂包括聚酰胺，聚酯，PPE，POM，PPS，聚烯烃树脂，未硫化橡胶可以包含具有多个可聚合不饱和键的硫化活化。 本发明给出了树脂和橡胶的组合较多的粘合剂，直接粘合到橡胶上的树脂的复合材料。

    Composite dispersion and process for producing the same
    6.
    发明授权
    Composite dispersion and process for producing the same 有权
    复合分散体及其制造方法

    公开(公告)号：US07553912B2

    公开(公告)日：2009-06-30

    申请号：US10520205

    申请日：2003-07-04

    申请人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda

    发明人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda

    IPC分类号： C08C19/20 ,  C08L77/00

    CPC分类号： C08J3/02 ,  C08F291/00 ,  C08J3/005 ,  C08J2321/00 ,  C08J2371/00 ,  C08J2377/00 ,  C08K5/0025

    摘要： A resin comprises a resin containing a vulcanization-activating agent, or crosslinkable group-containing resin (e.g., a resin having an unsaturated bond). Moreover, a composite dispersion may be formed by a combination of a specific resin and rubber [e.g., (a) a combination of a resin, and an unvulcanized rubber containing a vulcanizing agent and a vulcanization-activating agent at a specific ratio; (b) a combination of a polyamide-series resin, and an unvulcanized rubber containing a vulcanizing agent and a polyalkenylene at a specific ratio; (c) a combination of a resin and a silicone-series unvulcanized rubber; and (d) a combination of a polyphenylene ether-series resin containing a polyalkenylene, and an unvulcanized rubber containing a sulfur or sulfur-containing organic compound as a vulcanizing agent].The present invention provides a composite dispersion which comprises a continuous phase comprising a resin, and a dispersed phase being firmly bonded to the continuous phase and comprising a vulcanized rubber in a wide range of a combination of the resin and the rubber.

    摘要翻译： 树脂包含含有硫化活化剂或含可交联基团的树脂（例如具有不饱和键的树脂）的树脂。 此外，复合分散体可以通过特定树脂和橡胶的组合形成（例如，（a）树脂和含硫化剂和硫化活化剂的未硫化橡胶的组合比例; （b）聚酰胺系树脂与含有硫化剂和聚亚烷基的未硫化橡胶的比例为特定比例的组合; （c）树脂和硅氧烷系列未硫化橡胶的组合; 和（d）含有聚亚烯基的聚苯醚系树脂和含硫或含硫有机化合物作为硫化剂的未硫化橡胶的组合]。 本发明提供了一种复合分散体，其包括连续相，其包含树脂，分散相牢固地结合到连续相上，并且包括在宽范围的树脂和橡胶的组合中的硫化橡胶。

    Molded composite article, process for producing the same, and a joinable resin
    8.
    发明申请
    Molded composite article, process for producing the same, and a joinable resin 有权
    成型复合制品，其制造方法和可接合树脂

    公开(公告)号：US20070122615A1

    公开(公告)日：2007-05-31

    申请号：US10574265

    申请日：2004-09-30

    申请人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

    发明人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

    IPC分类号： D02G3/00

    CPC分类号： B32B27/40 ,  B32B7/10 ,  B32B27/08 ,  B32B27/16 ,  B32B27/285 ,  B32B27/34 ,  B32B2274/00 ,  B32B2307/536 ,  B32B2307/538 ,  B32B2437/02 ,  C08G2410/00 ,  C08L27/12 ,  C08L29/10 ,  C08L75/04 ,  C09D175/04 ,  Y10T428/2933 ,  Y10T428/31551 ,  Y10T428/31562 ,  C08L2666/04

    摘要： In a molded composite article, a resin member comprising a non-urethane-series thermoplastic resin and a resin member comprising a thermoplastic polyurethane-series resin are directly joined with each other; and the non-urethane-series thermoplastic resin is a non-urethane-series thermoplastic resin (Ib) or (IIb), and the non-urethane-series thermoplastic resin and the thermoplastic polyurethane-series resin fulfill a following requirement (Ia) or (IIa), (Ia): the non-urethane-series thermoplastic resin (Ib) comprises at least one member selected from the group consisting of a polyamide component having an alicyclic ring, and an amino group-containing compound, or (IIa): each of the non-urethane-series thermoplastic resin (IIb) and the thermoplastic polyurethane-series resin has a polyether segment. The resin composition (Ib) may be a resin composition (Ib-2) containing a non-urethane-series thermoplastic resin and the amino group-containing compound. The molded composite article can be produced by heating at least one selected from the non-urethane-series thermoplastic resin and thermoplastic polyurethane-series resin to join the other. Even if the base resin is a non-urethane-series thermoplastic resin, the present invention achieves a direct and firm bonding between the non-urethane-series thermoplastic resin member and the thermoplastic polyurethane-series resin member which were different in properties from each other by a simple process.

    摘要翻译： 在成型复合制品中，包含非氨基甲酸酯类热塑性树脂的树脂构件和包含热塑性聚氨酯系树脂的树脂构件彼此直接接合; 非氨基甲酸酯系热塑性树脂为非氨基甲酸酯系热塑性树脂（Ib）或（IIb），非氨基甲酸酯系热塑性树脂和热塑性聚氨酯系树脂满足以下要求（Ia）或 （IIa），（Ia）：非氨基甲酸酯系热塑性树脂（Ib）包含选自具有脂环式的聚酰胺成分和含氨基化合物的组中的至少一种，或（IIa） ：非聚氨酯系热塑性树脂（IIb）和热塑性聚氨酯系树脂均具有聚醚链段。 树脂组合物（Ib）可以是含有非氨基甲酸酯系热塑性树脂和含氨基化合物的树脂组合物（Ib-2）。 可以通过加热选自非氨基甲酸酯系热塑性树脂和热塑性聚氨酯系树脂中的至少一种来加成成型复合体。 即使基础树脂是非氨基甲酸乙酯系热塑性树脂，本发明也可以实现非氨基甲酸乙酯系热塑性树脂部件与热塑性聚氨酯系树脂部件之间的直接且牢固的结合， 通过一个简单的过程。

    Composite and process for producing the same
    9.
    发明授权
    Composite and process for producing the same 有权
    复合材料及其制造方法

    公开(公告)号：US06800372B2

    公开(公告)日：2004-10-05

    申请号：US10221733

    申请日：2002-09-16

    申请人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda

    发明人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda

    IPC分类号： B32B2520

    CPC分类号： B32B25/08 ,  B29C45/1676 ,  B29K2083/005 ,  B29K2221/003 ,  B32B25/20 ,  B32B2038/0076 ,  B32B2319/00 ,  B32B2367/00 ,  B32B2369/00 ,  B32B2375/00 ,  B32B2377/00 ,  B32B2379/08 ,  B32B2398/20 ,  B32B2605/08 ,  C08J5/12 ,  C08J2383/04 ,  Y10T428/31663 ,  Y10T428/31667

    摘要： A composite of a resin member bonded to a rubber member is obtained by molding a resin molding element and a rubber molding element with contacting said elements each other, and vulcanizing or crosslinking the rubber molding element, wherein said resin molding element is either of a resin composition and a resin member, each comprising the thermoplastic resin; and said rubber molding element is either of a rubber composition and a rubber premolded article, each comprising at least an unvulcanized silicone rubber, and a radical-generating agent (e.g., organic peroxides) being activating on a surface to be contacted with said resin molding element. The thermoplastic resin includes a polyamide-series resin, a polyester-serires resin, a PPE-series resin, etc. The unvulcanized rubber composition may comprise a polyfunctional compound having plural polymerizable groups. Such a process can give a composite composed of a thermoplastic resin molded article bonded to a vulcanized silicone rubber molded article directly and firmly without an adhesive treatment.

    摘要翻译： 通过将树脂成型体和橡胶成型体成形为与所述橡胶成型体接触，通过使所述橡胶成型体接触而使橡胶成型体硫化或交联，从而获得与橡胶部件接合的树脂部件的复合体，其中，所述树脂成型体为树脂 组合物和树脂构件，每个包含热塑性树脂; 并且所述橡胶成型元件是橡胶组合物和橡胶预成型制品，每个橡胶组合物和橡胶预成型制品至少包含未硫化的硅橡胶和在与所述树脂模塑件接触的表面上活化的自由基产生剂（例如有机过氧化物） 元件。 热塑性树脂包括聚酰胺系树脂，聚酯系树脂，PPE系树脂等。未硫化橡胶组合物可以含有多个可聚合基团的多官能化合物。 这种方法可以直接且牢固地得到由粘合到硫化硅橡胶模塑制品上的热塑性树脂模塑制品组成的复合材料，而无需粘合处理。