摘要:
The invention provides a novel packing composition for separation and/or analysis which permits easy capillary replacement; a process for the production of the packing composition; a method for filling a capillary with the packing composition; and electrophoretic methods (such as capillary electrophoresis) with the same. The invention relates to a packing composition for electrophoretic separation and/or analysis which contains a long self-assembly produced by dissolving a low-molecular-weight amphiphilic compound having a hydrophobic moiety and a hydrophilic moiety in water under heating and then cooling the resulting solution; a process for the production of the packing composition; a method of separation and/or analysis with the composition; and so on.
摘要:
The present invention is a stable, nanometer scale micro-tubular aggregated material of an asymmetric double-headed lipid represented by the general formula R—NHCO—(CH2)n—COOH (I) (in the formula, R represents an aldopyranose radical from which the terminal reducing hydroxyl group is excluded and n is from six to twenty). The external diameter of the micro-tubular aggregated material is 10-300 nm, and the length is 0.3-10 μm. The micro-tubular aggregated material can be manufactured by dispersing the asymmetric double-headed lipid described above in water at pH of two to eight, next heating to 80-100° C. to dissolve it and then gradually cooling the aqueous solution obtained.
摘要:
A lipid represented by the following formula:MO--(CO--CH.sub.2 --NH).sub.p --CO--(CH.sub.2).sub.n --CO--(NH--CH.sub.2 --CO).sub.q --OMwherein M represents a hydrogen atom or an alkali metal, n is an integer of 6-18 and p and q each represent an integer of at least 1 with the proviso that a total of p and q is not greater than 6. When an aqueous solution of an alkali metal salt of the lipid is allowed to stand for 2-3 weeks, a fibrous microtube including a tubular body having a diameter of 1-3 .mu.m and a plurality of spherical vesicles contained within the tubular body and having a diameter of 0.1-3 .mu.m is formed.
摘要:
When a saturated aqueous solution of a bolaform glycolipid represented by the general formula G--NH--CO--(CH.sub.2).sub.n --CO--NH--G, in which G is a residue derived from a D- or L-glucopyranose by excepting the reduced-terminal hydroxyl group and the subscript n is 10, 12 or 14, at a high temperature, e.g., 90 .degree. C. or higher, is cooled at a controlled rate of 0.5 .degree. C./minute or lower, crystallite growth of the precipitates proceeds to form an ultrafine fibrous assembly of up to several hundreds .mu.m length having a twisted fibrous morphology of right- or left-hand screw. The twisted fibrous assembly thus obtained has usefulness as a functional material in the field of fine chemicals and in the fields of electronic and information technologies.
摘要:
The invention provides a novel hollow fibrous organic nanotube comprising an O-glycoside type glycolipid having an aldose residue as the glycosyl group and a group represented by the general formula: wherein R is an unsaturated straight-chain hydrocarbon group having 12 to 18 carbon atoms, as the aglycon. The nanotube structure can be obtained by gradually cooling a saturated aqueous solution of the starting material down to room temperature where the solution is kept standing for days or for weeks to cause spontaneous formation of hollow tubes as precipitates.
摘要:
A lipid represented by the following formula:MO--(CO--CH.sub.2 --NH).sub.p --CO--(CH.sub.2).sub.n --CO--(NH--CH.sub.2 --CO).sub.q --OMwherein M represents a hydrogen atom or an alkali metal, n is an integer of 6-18 and p and q each represent an integer of at least 1 with the proviso that a total of p and q is not greater than 6. When an aqueous solution of an alkali metal salt of the lipid is allowed to stand for 2-3 weeks, a fibrous microtube including a tubular body having a diameter of 1-3 .mu.m and a plurality of spherical vesicles contained within the tubular body and having a diameter of 0.1-3 .mu.m is formed.
摘要:
A method of solubilizing iodine in an aqueous medium is disclosed, which includes mixing the aqueous medium with iodine together with a polystyrene derivative having the recurring units of the formula ##STR1## wherein R represents an alkylene group having 1-4 carbon atoms and n is an integer of 2-20. An antiseptic composition includes an aqueous medium, the above polystryene derivative, and iodine dissolved in the aqueous medium.
摘要:
Provided is an organic nanotube having a hydrophobized inner surface, formed by molecules including an asymmetric bipolar lipid molecule represented by the following General Formula (1) and a derivative thereof represented by the following General Formula (2), wherein the organic nanotube has a hydrophilized outer surface and a hydrophobized inner surface of a hollow cylinder and is formed by binary self-assembly, the organic nanotube encapsulates a hydrophobic guest in the hollow cylinder, has a function of refolding a denatured protein, and has a function of sustainably-releasing a hydrophobic drug according to the change in hydrophobicity of the inner surface of the tube or external stimulus, In Formulas (1) and (2), wherein the same symbols have the same meanings, G is a 1-glucopyranosyl group or 2-glucopyranosyl group, and n is an integer of 12 to 22. Particularly, an asymmetric bipolar lipid molecule and an ester thereof respectively represented by general formulae (1) and (2) wherein n is an integer of 18 to 22, both of Z1 and Z2 are single bonds, Y is Gly, m(s) is the same or different integer of 3 to 6, X is OH, and R is a methoxy group, an ethoxy group, or a benzyloxy group are novel substances, and can form a carboxylic acid based asymmetric nanotube by single component self-assembly or binary self-assembly.
摘要:
A gelatinizer is provided having a component which promises to have biological compatibility, which can easily be mass-produced by a simple method, and which can solidify a large amount of water or aqueous solution when only a very small weight of it is used.This invention is a hydrogelatinizer represented by the general formula: R-An where A, which may be identical or different, are respectively nucleotides, n is 2 or 3, and R is a hydrocarbon chain (when n is 2, R is bivalent, and when n is 3, R is trivalent), said hydrocarbon being bonded to a phosphoric acid part of said nucleotides.
摘要:
A lipid represented by the following formula:MO--(CO--CH.sub.2 --NH).sub.p --CO--(CH.sub.2).sub.n --CO--(NH--CH.sub.2 --CO).sub.q --OMwherein M represents a hydrogen atom or an alkali metal, n is an integer of 6-18 and p and q each represent an integer of at least 1 with the proviso that a total of p and q is not greater than 6. When an aqueous solution of an alkali metal salt of the lipid is allowed to stand for 2-3 weeks, a fibrous microtube including a tubular body having a diameter of 1-3 .mu.m and a plurality of spherical vesicles contained within the tubular body and having a diameter of 0.1-3 .mu.m is formed.