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    Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbons
    2.
    发明授权
    Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbons 有权
    用于烃的部分氧化的催化剂和烃的部分氧化方法

    公开(公告)号：US6034028A

    公开(公告)日：2000-03-07

    申请号：US274116

    申请日：1999-03-23

    申请人： Toshio Hayashi ,  Masahiro Wada ,  Masatake Haruta ,  Susumu Tsubota

    发明人： Toshio Hayashi ,  Masahiro Wada ,  Masatake Haruta ,  Susumu Tsubota

    IPC分类号： B01J23/52 ,  B01J23/66 ,  C07C29/50 ,  C07C45/28 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07D301/04 ,  C07D301/10

    CPC分类号： C07D301/10 ,  B01J23/52 ,  B01J23/66 ,  C07C29/50 ,  C07C45/33 ,  C07D301/04

    摘要： A partially-oxidizing catalyst for hydrocarbon contains gold, titanium oxide and a carrier whose specific surface area is not less than 50 m.sup.2 /g. The carrier is preferably made from silicon oxide and/or aluminum oxide. The content of gold in the catalyst is preferably set in the range of 0.005 to 5% by weight. Further, another partially-oxidizing catalyst for a hydrocarbon contains gold, a titanium-containing metal oxide, and at least one element selected from the group consisting of an alkaline metal, an alkaline-earth metal and thallium. With these compositions, it becomes possible to provide a partially-oxidizing catalyst for a hydrocarbon having superior activity and selectivity in partially oxidizing the hydrocarbon in the presence of hydrogen and oxygen. Moreover, a partially-oxidizing method for a hydrocarbon is used for partially oxidizing the hydrocarbon by using any of the above-mentioned partially-oxidizing catalysts in the presence of hydrogen and oxygen. This method makes it possible to manufacture an epoxide from a hydrocarbon of the olefin family and also to manufacture an alcohol and/or a ketone from a saturated hydrocarbon, with high selectivity and high conversion.

    摘要翻译： 烃的部分氧化催化剂含有金，氧化钛和比表面积不小于50m 2 / g的载体。 载体优选由氧化硅和/或氧化铝制成。 催化剂中的金的含量优选设定在0.005〜5重量％的范围内。 此外，烃的另一种部分氧化催化剂含有金，含钛金属氧化物和选自碱金属，碱土金属和铊中的至少一种元素。 利用这些组合物，可以在氢气和氧气存在下部分氧化烃时提供具有优异活性和选择性的烃的部分氧化催化剂。 此外，通过在氢和氧的存在下使用任何上述部分氧化催化剂，使用烃的部分氧化方法来部分氧化烃。 该方法使得可以从烯烃族的烃制造环氧化物，并且以高选择性和高转化率从饱和烃制造醇和/或酮。

    Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbons
    3.
    发明授权
    Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbons 失效
    用于烃的部分氧化的催化剂和烃的部分氧化方法

    公开(公告)号：US5932750A

    公开(公告)日：1999-08-03

    申请号：US945989

    申请日：1997-11-10

    申请人： Toshio Hayashi ,  Masahiro Wada ,  Masatake Haruta ,  Susumu Tsubota

    发明人： Toshio Hayashi ,  Masahiro Wada ,  Masatake Haruta ,  Susumu Tsubota

    IPC分类号： B01J23/52 ,  B01J23/66 ,  C07C29/50 ,  C07C45/28 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07D301/04 ,  C07D301/10

    CPC分类号： C07D301/10 ,  B01J23/52 ,  B01J23/66 ,  C07C29/50 ,  C07C45/33 ,  C07D301/04

    摘要： A partially-oxidizing catalyst for hydrocarbon contains gold, titanium oxide and a carrier whose specific surface area is not less than 50 m.sup.2 /g. The carrier is preferably made from silicon oxide and/or aluminum oxide. The content of gold in the catalyst is preferably set in the range of 0.005 to 5 % by weight. Further, another partially-oxidizing catalyst for a hydrocarbon contains gold, a titanium-containing metal oxide, and at least one element selected from the group consisting of an alkaline metal, an alkaline-earth metal and thallium. With these compositions, it becomes possible to provide a partially-oxidizing catalyst for a hydrocarbon having superior activity and selectivity in partially oxidizing the hydrocarbon in the presence of hydrogen and oxygen. Moreover, a partially-oxidizing method for a hydrocarbon is used for partially oxidizing the hydrocarbon by using any of the above-mentioned partially-oxidizing catalysts in the presence of hydrogen and oxygen. This method makes it possible to manufacture an epoxide from a hydrocarbon of the olefin family and also to manufacture an alcohol and/or a ketone from a saturated hydrocarbon, with high selectivity and high conversion.

    摘要翻译： PCT No.PCT / JP97 / 00869 Sec。 371日期：1997年11月10日 102（e）日期1997年11月10日PCT 1997年3月18日PCT公布。 出版物WO97 / 34692 日期1997年9月25日烃的部分氧化催化剂含有金，氧化钛和比表面积不小于50m 2 / g的载体。 载体优选由氧化硅和/或氧化铝制成。 催化剂中的金的含量优选设定在0.005〜5重量％的范围内。 此外，烃的另一种部分氧化催化剂含有金，含钛金属氧化物和选自碱金属，碱土金属和铊中的至少一种元素。 利用这些组合物，可以在氢气和氧气存在下部分氧化烃时提供具有优异活性和选择性的烃的部分氧化催化剂。 此外，通过在氢和氧的存在下使用任何上述部分氧化催化剂，使用烃的部分氧化方法来部分氧化烃。 该方法使得可以从烯烃族的烃制造环氧化物，并且以高选择性和高转化率从饱和烃制造醇和/或酮。

    Method of manufacturing epoxide
    5.
    发明授权
    Method of manufacturing epoxide 失效
    环氧化物的制造方法

    公开(公告)号：US5929258A

    公开(公告)日：1999-07-27

    申请号：US996878

    申请日：1997-12-23

    申请人： Toshio Hayashi ,  Masahiro Wada ,  Masatake Haruta

    发明人： Toshio Hayashi ,  Masahiro Wada ,  Masatake Haruta

    IPC分类号： B01J23/52 ,  C07D301/04 ,  C07D301/10 ,  C07D301/03

    CPC分类号： B01J23/52 ,  C07D301/04 ,  C07D301/10 ,  Y02P20/582

    摘要： The method of manufacturing an epoxide according to the present invention includes: a dehydrogenation step 1, in which a gas A containing an alkane is dehydrogenated, producing a gas B which contains an alkene and hydrogen; an epoxidation step 2, in which the gas B is epoxidized by use of a gas C containing oxygen in the presence of a catalyst containing gold, producing a gas D which contains an epoxide and unreacted hydrogen and oxygen; a separation step 3, in which the epoxide is separated from the gas D, leaving a gas E; and an oxygen elimination step 4, in which oxygen and hydrogen contained in the gas E are allowed to react, eliminating the oxygen and leaving a gas F. At least part of the gas F (gas F.sub.1) is recycled by returning it to the dehydrogenation step 1. Hydrogen produced in the dehydrogenation step 1 is consumed in the epoxidation step 2 and the oxygen elimination step 4, and thus does not build up in the system of reaction. Accordingly, it is not necessary to separate or eliminate the hydrogen from the system of reaction. In other words, a method can be provided which is industrially advantageous for continuously producing an epoxide from an alkane.

    摘要翻译： 根据本发明的环氧化物的制造方法包括：脱氢步骤1，其中含有烷烃的气体A脱氢，产生含有烯烃和氢气的气体B; 环氧化步骤2，其中气体B在含有催化剂的存在下使用含氧的气体C进行环氧化，产生含有环氧化物和未反应的氢和氧的气体D; 分离步骤3，其中环氧化物与气体D分离，留下气体E; 和氧气消除步骤4，其中使气体E中所含的氧气和氢气发生反应，消除氧气并留下气体F.至少部分气体F（气体F1）通过将其返回脱氢而再循环 在脱氢步骤1中产生的氢在环氧化步骤2和氧消除步骤4中消耗，因此不会在反应体系中积聚。 因此，不需要从反应体系中分离或除去氢。 换句话说，可以提供一种工业上有利于从烷烃连续生产环氧化物的方法。

    Catalyst for use in production of epoxide, method for producing the catalyst, and method for producing epoxide
    6.
    发明授权
    Catalyst for use in production of epoxide, method for producing the catalyst, and method for producing epoxide 失效
    用于生产环氧化物的催化剂，生产催化剂的方法，以及环氧化物的制备方法

    公开(公告)号：US06500967B2

    公开(公告)日：2002-12-31

    申请号：US09788573

    申请日：2001-02-21

    申请人： Toshio Hayashi ,  Masahiro Wada ,  Takahiro Inagaki

    发明人： Toshio Hayashi ,  Masahiro Wada ,  Takahiro Inagaki

    IPC分类号： C07D30110

    CPC分类号： C07D301/10 ,  B01J23/52

    摘要： To provide an epoxide-production-use catalyst that is suitably used for producing an epoxide by partial oxidation of an unsaturated hydrocarbon, a catalyst in accordance with the present invention is obtained by fixing gold fine particles to a carrier containing an oxide containing at least one of titanium and zirconium, and has an acid quantity of not more than 0.1 mmol/g determined by the NH3-TPD method. Such a catalyst for epoxide producing use can be produced by, for instance, fixing gold fine particles to a carrier having an acid quantity of not more than 0.15 mmol/g. The catalyst for epoxide producing use arranged as above is preferably used as a catalyst in partial oxidation of an unsaturated hydrocarbon to produce a corresponding epoxide.

    摘要翻译： 为了提供适合用于通过不饱和烃的部分氧化制备环氧化物的环氧化物生产用催化剂，根据本发明的催化剂是通过将金微粒固定到含有至少一种 的钛和锆，并且通过NH 3 -TPD法测定的酸量不超过0.1mmol / g。 这种用于环氧化物的催化剂可以通过例如将金微粒固定到酸量不大于0.15mmol / g的载体来制备。 如上所述排出的环氧化物生产用催化剂优选用作不饱和烃的部分氧化中的催化剂，以产生相应的环氧化物。