公开(公告)号：US6111044A

公开(公告)日：2000-08-29

申请号：US952149

申请日：1998-11-04

申请人： Toshio Yamamoto ,  Kazuhi Koga ,  Yoshiaki Marutani ,  Hiroshi Kubota ,  Tadamitsu Nakahama ,  Mika Ohsawa

发明人： Toshio Yamamoto ,  Kazuhi Koga ,  Yoshiaki Marutani ,  Hiroshi Kubota ,  Tadamitsu Nakahama ,  Mika Ohsawa

IPC分类号： B05D7/24 ,  B05D7/14 ,  C08G59/20 ,  C08G63/20 ,  C08K5/00 ,  C08L63/00 ,  C08L67/00 ,  C09D133/06 ,  C09D163/00 ,  C08F124/00

CPC分类号： C09D133/068 ,  C08L67/00 ,  C08G63/20

摘要： A thermosetting composition which gives a cured product having excellent weatherability, chemical and physical properties, in particular acid resistance and abrasion resistance, at a relatively low temperature, which has superior storage stability, and which can be used as a one component coating material; a coating composition utilizing this thermosetting composition; a method of coating; and a coated article are provided. The thermosetting composition contains a resin having at least one functional group selected from the group consisting of a blocked hydroxyl group, blocked carboxylic acid, and an epoxy group. The thermosetting composition has a blocked hydroxyl group, blocked carboxylic acid, and an epoxy group.

摘要翻译： PCT No.PCT / JP97 / 00647 Sec。 371日期1997年11月4日 102（e）日1997年11月4日PCT 1997年3月4日PCT PCT热固性组合物在相对较低的温度下得到具有优异的耐候性，化学和物理特性，特别是耐酸性和耐磨性的固化产物， 储存稳定性，可用作单组分涂料; 使用该热固性组合物的涂料组合物; 一种涂层方法; 并提供涂层制品。 热固性组合物含有具有至少一个选自由封端羟基，封端羧酸和环氧基组成的组中的官能团的树脂。 热固性组合物具有封端的羟基，封端的羧酸和环氧基。

公开(公告)号：US6040009A

公开(公告)日：2000-03-21

申请号：US491736

申请日：1995-06-19

申请人： Yoshiaki Marutani ,  Takashi Tomita ,  Tadamitsu Nakahama ,  Hiroyuki Uemura ,  Kazuhi Koga ,  Mika Ohsawa

发明人： Yoshiaki Marutani ,  Takashi Tomita ,  Tadamitsu Nakahama ,  Hiroyuki Uemura ,  Kazuhi Koga ,  Mika Ohsawa

IPC分类号： B05D7/00 ,  C09D167/04 ,  C09B167/00 ,  C09B167/04

CPC分类号： B05D7/532 ,  C09D167/04

摘要： The present invention is to provide a low solvent content type-coating composition by which the resultant coatings with good scuff resistance or water resistance as well as good chipping resistance are produced, while the content of an organic solvent to be used can be much reduced. The low solvent content type-coating composition comprises a polyester oligomer having a hydroxyl group in an amount of 2.0 to 10.0 moles/Kg-resin, a number average molecular weight (Mn) of 300 to 1500, a weight average molecular weight (Mw) of 300 to 3000, and a ratio of a weight average molecular weight/a number average molecular weight (Mw/Mn) of 1 to 2.0, an amount of a modifying lactone being 31 to 85%, and an aliphatic hydrocarbon group of C4-22 which is not derived from lactones. The present invention is also to provide a process for coating a low solvent content type-coating composition on, for example, a base coating composition by a wet-on-wet coating. The base coating composition comprises a vinyl oligomer having a hydroxyl group and/or a blocked hydroxyl group, a melamine resin containing 50 to 100% of an imino type or methylol type mononucleus melamine and a weak acidic curing catalyst.

摘要翻译： 本发明提供一种低溶剂含量型涂料组合物，通过该组合物可以产生具有良好耐擦伤性或耐水性的所得涂层以及良好的抗碎裂性，同时可以大大降低所用有机溶剂的含量。 低溶剂含量型涂料组合物包含羟基数为2.0〜10.0摩尔/ Kg-树脂的聚酯低聚物，数均分子量（Mn）为300〜1500，重均分子量（Mw） 的比例为300〜3000，重均分子量/数均分子量（Mw / Mn）为1〜2.0，改性内酯的量为31〜85％，C4- 22，它不是从内酯衍生的。 本发明还提供了通过湿式湿式涂布在例如底涂层组合物上涂布低溶剂含量型涂料组合物的方法。 基础涂料组合物包含具有羟基和/或封端羟基的乙烯基低聚物，含有50-100％亚氨基型或羟甲基型单核三聚氰胺的三聚氰胺树脂和弱酸性固化催化剂。

公开(公告)号：US5962588A

公开(公告)日：1999-10-05

申请号：US968723

申请日：1997-11-12

申请人： Goro Iwamura ,  Shigeki Matsui ,  Ichiro Azuma ,  Yoshiaki Marutani ,  Hiroyuki Uemura ,  Tadamitsu Nakahama ,  Shinji Sasaki ,  Kazuhi Koga ,  Takashi Tomita ,  Mika Ohsawa

发明人： Goro Iwamura ,  Shigeki Matsui ,  Ichiro Azuma ,  Yoshiaki Marutani ,  Hiroyuki Uemura ,  Tadamitsu Nakahama ,  Shinji Sasaki ,  Kazuhi Koga ,  Takashi Tomita ,  Mika Ohsawa

IPC分类号： C09D201/06 ,  C08F8/00

CPC分类号： C09D201/06

摘要： The present invention provides a curable resin composition incorporating an oligomer containing blocked hydroxyl group, an epoxy-group containing compound, hydrolytic silyl-group containing compound, and a dissociation catalyst and/or curing catalyst, each possessing a specific molecular weight; a paint which uses this resin composition as a binder; and a coat-finishing method which coat-finishes any desired material using the aforementioned resin composition and paint. According to the present invention, it is possible to reduce viscosity, and consequently increase the coat non-volatile content and hence improve acid resistance, abrasion resistance, and the like. In addition, according to the present invention, it is possible to obtain a curable resin composition, paint using this curable resin composition, and coat-finishing method for this paint in which the aforementioned resin and paint have an extremely high utility and possess a high solid content wherein air bubbles and drip-runs are not generated.

摘要翻译： 本发明提供一种包含具有特定分子量的含有封端羟基的低聚物，含环氧基的化合物，含有水解甲硅烷基的化合物和解离催化剂和/或固化催化剂的固化性树脂组合物， 使用该树脂组合物作为粘合剂的涂料; 以及使用上述树脂组合物和涂料涂覆任何所需材料的涂层整理方法。 根据本发明，可以降低粘度，从而增加涂层不挥发成分，从而提高耐酸性，耐磨性等。 此外，根据本发明，可以得到固化性树脂组合物，使用该固化性树脂组合物的涂料，以及上述树脂和涂料具有极高效用且具有高的涂料的涂料精加工方法 不产生气泡和滴灌的固体成分。

公开(公告)号：US5786435A

公开(公告)日：1998-07-28

申请号：US926995

申请日：1997-09-10

申请人： Yoshiaki Marutani ,  Tadamitsu Nakahama ,  Shinji Sasaki ,  Hiroyuki Uemura ,  Kazuhi Koga ,  Takashi Tomita ,  Mika Ohsawa

发明人： Yoshiaki Marutani ,  Tadamitsu Nakahama ,  Shinji Sasaki ,  Hiroyuki Uemura ,  Kazuhi Koga ,  Takashi Tomita ,  Mika Ohsawa

IPC分类号： B05D1/00 ,  C09D133/06 ,  C08F120/32 ,  C08K5/01 ,  C08L33/14

CPC分类号： C09D133/068 ,  B05D1/002

摘要： The present invention relates to a low solvent content-type resin composition, a low solvent content-type coating composition containing such a resin composition as a binder, and a method for coating such a coating composition. The resin composition comprises an oligomer containing an alicyclic epoxy group in a molecule and having a number average molecular weight (Mn) of 300 to 2000, a weight average molecular weight (Mw) of 300 to 4000 and an Mw/Mn ratio of 1 to 2.5. The coating composition comprises such a resin composition and a cationic polymerization catalyst, wherein the content of an organic solvent content is 0 to 40 wt. %. Since the present composition contains a low molecular weight oligomer, the viscosity of the composition is low even though the solid content is high. Accordingly, the content of the organic solvent can be much reduced.

摘要翻译： 本发明涉及低溶剂含量型树脂组合物，含有这种树脂组合物作为粘合剂的低溶剂含量型涂料组合物，以及这种涂料组合物的涂布方法。 树脂组合物包含分子中含有脂环族环氧基的低聚物，数均分子量（Mn）为300〜2000，重均分子量（Mw）为300〜4000，Mw / Mn比为1〜 2.5。 涂料组合物包含这种树脂组合物和阳离子聚合催化剂，其中有机溶剂含量为0-40wt。 ％。 由于本发明的组合物含有低分子量低聚物，组合物的粘度即使固体含量高，也是低的。 因此，有机溶剂的含量可以大大降低。

公开(公告)号：US5650475A

公开(公告)日：1997-07-22

申请号：US508427

申请日：1995-07-31

申请人： Yoshiaki Marutani ,  Tadamitsu Nakahama ,  Takashi Tomita ,  Hiroyuki Uemura ,  Kazuhi Koga ,  Mika Ohsawa ,  Goro Iwamura

发明人： Yoshiaki Marutani ,  Tadamitsu Nakahama ,  Takashi Tomita ,  Hiroyuki Uemura ,  Kazuhi Koga ,  Mika Ohsawa ,  Goro Iwamura

IPC分类号： C08L101/02 ,  C08L101/00 ,  C09D133/06 ,  C09D143/04 ,  C09D201/02 ,  C08G77/04

CPC分类号： C09D133/062 ,  C09D143/04 ,  C08L2205/02

摘要： The present invention relates to a low solvent content type-coating composition which provides the resultant coating with improved surface appearance, acid resistance, alkali resistance, weathering resistance, scuff resistance and solvent resistance, while the content of an organic solvent of the coating composition can be much reduced to 0 to 30% at 25.degree. C. The low solvent content type-coating composition comprises a vinyl oligomer having a blocked carboxyl group and an additional group selected from an epoxy group, a silanol group, a hydrolyzable silyl group and an acid anhydride group. The vinyl oligomer has a number average molecular weight (Mn) of 600 to 2000, a weight average molecular weight (Mw) of 600 to 5000, and a ratio of a weight average molecular weight/a number average molecular weight (Mw/Mn) of 1.0 to 2.5. The blocked carboxyl group and an additional group may be present in the same or different vinyl oligomers.

摘要翻译： 本发明涉及一种低溶剂含量型涂料组合物，其中所述涂料组合物的有机溶剂的含量可以提供所得涂层具有改善的表面外观，耐酸性，耐碱性，耐候性，耐擦伤性和耐溶剂性， 在25℃下可以大大降低至0％至30％。低溶剂含量型涂料组合物包含具有封端羧基的乙烯基低聚物和选自环氧基，硅烷醇基，可水解甲硅烷基和 酸酐基。 乙烯基低聚物的数均分子量（Mn）为600〜2000，重均分子量（Mw）为600〜5000，重均分子量/数均分子量（Mw / Mn） 为1.0〜2.5。 封端的羧基和另外的基团可以存在于相同或不同的乙烯基低聚物中。

公开(公告)号：US06207235B1

公开(公告)日：2001-03-27

申请号：US08615941

申请日：1996-03-14

申请人： Mika Ohsawa ,  Yoshiaki Marutani ,  Hiroyuki Uemura ,  Kazuhi Koga ,  Hiroshi Kubota

发明人： Mika Ohsawa ,  Yoshiaki Marutani ,  Hiroyuki Uemura ,  Kazuhi Koga ,  Hiroshi Kubota

IPC分类号： B05D302

CPC分类号： C09D163/00 ,  C08K5/3435 ,  C09D7/48 ,  C09D133/068 ,  C08L2666/28

摘要： A one-pack coating composition is disclosed. The composition comprises (A) an oligomer or polymer containing an acid anhydride group, a blocked hydroxyl group and an epoxy group as indispensable functional groups in the same or different molecules, (B) a heat-potential curing catalyst which comprises a complex of an organometallic compound and an electron-donating compound or an onium salt and which exhibits its activity upon heating, (C) an ultraviolet absorber comprising a triazine or oxalic anilide, and (D) a hindered amine light stabilizer having a piperidine ring of the following structure: wherein R represents R1—CO—, a C2 to C20 alkyl group or R1—O— (R1 being a C2 to C20 alkyl group), and R2, R3, R4 and R5 independently from each other represent a C1 to C3 alkyl group, or a phenolic antioxidant. A method for coating using this coating composition is also disclosed.

摘要翻译： 公开了一种单组分涂料组合物。 该组合物包含（A）在相同或不同分子中含有酸酐基团，封端羟基和环氧基作为不可缺少的官能团的低聚物或聚合物，（B）一种热电位固化催化剂，其包含 有机金属化合物和给电子化合物或鎓盐，其加热时具有活性，（C）包含三嗪或草酰二苯胺的紫外线吸收剂，（D）具有以下结构的哌啶环的受阻胺光稳定剂 ：其中R表示R 1 -CO-，C 2至C 20烷基或R 1 -O-（R 1为C 2至C 20烷基），R 2，R 3，R 4和R 5彼此独立地表示C 1至C 3烷基 ，或酚类抗氧化剂。 还公开了使用该涂料组合物进行涂布的方法。

公开(公告)号：US5998035A

公开(公告)日：1999-12-07

申请号：US989021

申请日：1997-12-11

申请人： Goro Iwamura ,  Shigeki Matsui ,  Norio Kosaka ,  Yoshiaki Marutani ,  Kazuhi Koga ,  Mika Ohsawa ,  Hiroshi Kubota

发明人： Goro Iwamura ,  Shigeki Matsui ,  Norio Kosaka ,  Yoshiaki Marutani ,  Kazuhi Koga ,  Mika Ohsawa ,  Hiroshi Kubota

IPC分类号： B05D7/00 ,  B32B27/00 ,  B32B27/40

CPC分类号： B05D7/532 ,  Y10T428/31551 ,  Y10T428/31594 ,  Y10T428/31688

摘要： A coating method is disclosed, which comprises coating a base coating paint on a substrate, coating thereon a clear coating paint of a curing system different from that of the base coating paint in a wet-on-wet state, and then baking the resultant coatings, wherein a curing catalyst for curing the clear coating paint is incorporated into the base coating paint and wherein the curing catalyst has a boiling point of 150.degree. C. or higher under 760 mmHg. The base coating paint comprising such a curing catalyst is also disclosed.

摘要翻译： 公开了一种涂布方法，其包括在基底上涂覆基底涂料涂料，在湿润湿润状态下在其上涂覆与基底涂料不同的固化体系的固化体系的透明涂料，然后将所得涂料 其中，固化所述透明涂料涂料的固化催化剂被引入所述底漆涂料中，并且其中所述固化催化剂在760mmHg以下的沸点为150℃或更高。 还公开了包含这种固化催化剂的基底涂料。

公开(公告)号：US5721015A

公开(公告)日：1998-02-24

申请号：US623050

申请日：1996-03-28

申请人： Goro Iwamura ,  Shigeki Matsui ,  Norio Kosaka ,  Yoshiaki Marutani ,  Kazuhi Koga ,  Mika Ohsawa ,  Hiroshi Kubota

发明人： Goro Iwamura ,  Shigeki Matsui ,  Norio Kosaka ,  Yoshiaki Marutani ,  Kazuhi Koga ,  Mika Ohsawa ,  Hiroshi Kubota

IPC分类号： B05D1/36 ,  B05D5/06 ,  B05D7/00 ,  B05D7/14 ,  C09D161/20 ,  B05D3/10 ,  B05D3/02 ,  B05D7/16

CPC分类号： B05D7/532 ,  B05D1/36

摘要： A coating method is disclosed, which comprises coating a base coating paint on a substrate, coating thereon a clear coating paint of a curing system different from that of the base coating paint in a wet-on-wet state, and then baking the resultant coatings, wherein a curing catalyst for curing the clear coating paint is incorporated into the base coating paint and wherein the curing catalyst has a boiling point of 150.degree. C. or higher, under 760 mmHg. The base coating paint comprising such a curing catalyst is also disclosed.

摘要翻译： 公开了一种涂布方法，其包括在基底上涂覆基底涂料涂料，在湿润湿润状态下在其上涂覆与基底涂料不同的固化体系的固化体系的透明涂料，然后将所得涂料 其中，将固化所述透明涂料的固化催化剂掺入所述基底涂料涂料中，并且其中所述固化催化剂的沸点为150℃或更高，在760mmHg以下。 还公开了包含这种固化催化剂的基底涂料。

公开(公告)号：US5955545A

公开(公告)日：1999-09-21

申请号：US685648

申请日：1996-07-24

申请人： Yoshiaki Marutani ,  Mika Ohsawa ,  Yasuyuki Takeuchi ,  Hiroki Kagawa

发明人： Yoshiaki Marutani ,  Mika Ohsawa ,  Yasuyuki Takeuchi ,  Hiroki Kagawa

IPC分类号： B05D1/36 ,  B05D7/00 ,  B05D7/02 ,  C08F255/02 ,  C08J7/04 ,  C08L51/06 ,  C08L61/28 ,  C09D5/00 ,  C09D151/00 ,  C09D151/06 ,  C09D161/20 ,  C09D161/28 ,  C08L33/14

CPC分类号： B05D7/532 ,  B05D7/02 ,  C08F255/023 ,  C08J7/047 ,  C08L51/06 ,  C08L61/28 ,  C09D151/06 ,  C08J2323/02 ,  C08J2451/00 ,  C08J2461/00

摘要： A coating for polyolefin molding compositions comprises (1) (a) from 40-90% by weight of a chlorinated polyolefin grafted with a vinyl-polymerizable monomer having a hydroxyl group at a position 15 to 40 atoms distant from the main chain of vinyl polymer grafted onto the chlorinated polyolefin, or (b) from 50 to 90% by weight of a vinyl polymer obtained by polymerizing from 5 to 40% by weight of a hydroxyl group-containing (meth)acrylate monomer having a carbon chain derived from an alcohol residue with from 6 to 18 carbon atoms, and a vinyl-polymerizable monomer having a hydroxyl group at a position 15 to 40 atoms distant from the vinyl group, wherein the vinyl polymerizable monomer is derived from the reaction product of a vinyl-polymerizable monomer having a hydroxyl group at a position 2 to 12 atoms distant from the vinyl group and a lactone, and (2) from 10 to 60 or 50% by weight of a melamine resin containing methylol, alkoxy or imino groups.

摘要翻译： 用于聚烯烃模塑组合物的涂层包括（a）40-90重量％的接枝有乙烯基聚合物主链的15至40个原子具有羟基的乙烯基聚合单体的氯化聚烯烃 接枝到氯化聚烯烃上，或（b）50至90重量％的通过聚合5至40重量％的具有衍生自醇的碳链的含羟基的（甲基）丙烯酸酯单体获得的乙烯基聚合物 具有6至18个碳原子的残基和一个具有羟基的乙烯基聚合性单体，该乙烯基聚合性单体的距离为乙烯基的位置为15至40个原子，其中乙烯基聚合性单体是由具有 在距离乙烯基2至12个原子的位置的羟基和内酯，和（2）10至60或50重量％的含有羟甲基，烷氧基或亚氨基的三聚氰胺树脂。

公开(公告)号：US5773511A

公开(公告)日：1998-06-30

申请号：US560618

申请日：1995-11-20

申请人： Yoshiaki Marutani ,  Mika Ohsawa

发明人： Yoshiaki Marutani ,  Mika Ohsawa

IPC分类号： B05D7/02 ,  B05D7/24 ,  C08J7/04 ,  C08L51/06 ,  C09D151/00 ,  C09D151/06 ,  C09D161/20 ,  C09D161/28 ,  C08L23/26 ,  C08L23/36 ,  C08L61/28

CPC分类号： C08J7/047 ,  C09D151/06 ,  C09D161/28 ,  C08J2323/02 ,  C08J2451/00 ,  C08J2461/00 ,  C08L51/06 ,  Y10T428/31862

摘要： The present invention relates to a coating composition which is excellent in handling and safety, enables the curing of the resultant coating composition at low temperature, and provides an excellent adhesion to polyolefin resin moldings. The coating composition comprises (1) 40-90 wt. % of a grafted and chlorinated polyolefin oligomer obtained by graft polymerizing a vinyl polymerizable monomer to a chlorinated polyolefin, the grafted and chlorinated polyolefin oligomer having a primary or blocked primary hydroxyl group at a position of 15 to 40 atoms away from the vinyl graft polymer chain grafted to the chlorinated polyolefin, a number average molecular weight of 5,000 to 50,000, 0.4 to 2.5 mole/kg-resin of a primary or blocked primary hydroxyl group, 50 to 95 wt. % of said vinyl graft polymer chain, and 5 to 50 wt. % of the chlorinated polyolefin used as a starting material, and (2) 60 to 10 wt. % of an imino-type, methylol-type or complete alkoxy-type melamine resin. The present coating composition can be cured by baking the coating composition at 90.degree. to 120.degree. C.

摘要翻译： 本发明涉及处理性和安全性优异的涂料组合物，能够使所得涂料组合物在低温下固化，并且对聚烯烃树脂成型品提供优异的粘合性。 涂料组合物包含（1）40-90wt。 通过将乙烯基聚合性单体接枝聚合到氯化聚烯烃上而获得的接枝和氯化聚烯烃低聚物的接枝和氯化聚烯烃低聚物在乙烯基接枝聚合物链远离15至40个原子的位置具有伯或封闭的伯羟基 接枝到氯化聚烯烃上，数均分子量为5,000至50,000，0.4至2.5摩尔/千克 - 初级或封闭的伯羟基树脂，50至95重量％ ％的所述乙烯基接枝聚合物链，和5至50wt。 ％的氯化聚烯烃用作原料，和（2）60〜10wt。 ％的亚氨基型羟甲基型或完全烷氧基型三聚氰胺树脂。 本涂料组合物可通过在90℃至120℃下烘烤该涂料组合物而固化。