公开(公告)号：US5518779A

公开(公告)日：1996-05-21

申请号：US302570

申请日：1994-09-08

Applicant: Tsai-An Yu ,  Jing-Pin Pan

Inventor： Tsai-An Yu ,  Jing-Pin Pan

IPC: B05D3/02 ,  B05D7/16 ,  C08F2/48 ,  C09D179/08 ,  H05K3/02

CPC classification number: H05K3/022 ,  B05D3/0263 ,  B05D7/16 ,  C09D179/085 ,  B05D2505/50 ,  Y02P20/124 ,  Y10S430/145

Abstract: An improved method for preparing copper clad laminates from a copper substrate without a conventional or infrared oven. The method contains the steps of: (a) preparing a precursory coating composition which can be subsequently cured to become polyimide; (b) coating the precursory coating composition on a copper substrate; and (c) exposing the precursory coating composition to an infrared heater provided in an infrared curing apparatus. The infrared heater is selected such that it emits infrared rays of wavelengths correponding to the absorption spectrum of the precursory coating composition. A plurality of infrared heaters can be provided in the infrared curing apparatus, each can be designed to have a different effective heating length and/or operated at a uniquely predetermined surface temperature for optimum energy efficiency. Preferably, the precursory coating composition contains an upper layer consisting essentially of polyamic acid and a lower layer disposed between the upper layer and the copper substrate, the lower layer being a blended mixture of the polyamic acid and a modified bismaleimide.

Abstract translation: 一种用于从铜基底制备铜箔层压板而不使用常规或红外线烘箱的改进方法。 该方法包括以下步骤：（a）制备可随后固化成聚酰亚胺的前体涂料组合物; （b）将前体涂料组合物涂布在铜基材上; 和（c）将前体涂料组合物暴露于设置在红外固化装置中的红外加热器。 选择红外线加热器，使得其发射相应于前体涂料组合物的吸收光谱的波长的红外线。 红外线固化装置中可以设置多个红外加热器，每个红外线加热器可设计成具有不同的有效加热长度和/或在独特的预定表面温度下操作以获得最佳的能量效率。 优选地，前体涂料组合物包含基本上由聚酰胺酸组成的上层和设置在上层和铜基材之间的下层，下层是聚酰胺酸和改性双马来酰亚胺的共混混合物。

公开(公告)号：US5372891A

公开(公告)日：1994-12-13

申请号：US991287

申请日：1992-12-16

Applicant: Tsai-An Yu ,  Jing-Pin Pan ,  Han-Lung Chen ,  Jinn-Shing King ,  Tsung-Hsiung Wang

Inventor： Tsai-An Yu ,  Jing-Pin Pan ,  Han-Lung Chen ,  Jinn-Shing King ,  Tsung-Hsiung Wang

IPC: C08G73/10 ,  C09J179/08 ,  H05K1/03 ,  B32B15/08

CPC classification number: C08G73/101 ,  C09J179/08 ,  C09J179/085 ,  H05K1/0346 ,  Y10T428/31681 ,  Y10T428/31721

Abstract: An improved polyimide-based coating composition comprising a polyimide upper layer and a polyimide-modified bismaleimide lower layer for use as a coating on metal substrate, such as an electrolytic copper foil. The polyimide are prepared from reactions between diamines, such as p-phenylene diamine and 4-4'-diaminodiphenyl ether, and dianhydrides, such as 3,3',4,4'-benzophenone tetracarboxylic dianhydride and biphenyl-3,3',4,4'-tetracarboxylic dianhydride. The modified bismaleimide can be prepared from reacting an N,N',4,4'-diphenyl bismaleimide with a barbituric acid or its derivative. A double-layered extrusion coating technique having a double-layered extrusion die is utilized to apply the coating composition onto the metal substrate. The final laminated products show improved peel strength between the polyimide coating and the substrate, as well as improved dimensional stability and surface flatness thereof.

Abstract translation: 一种改进的聚酰亚胺基涂料组合物，其包含聚酰亚胺上层和用作金属基底如电解铜箔上的涂层的聚酰亚胺改性双马来酰亚胺下层。 聚酰亚胺由二胺如对苯二胺和4-4'-二氨基二苯基醚之间的反应制备，二酐如3,3'，4,4'-二苯甲酮四羧酸二酐和联苯-3,3' 4,4'-四羧酸二酐。 改性双马来酰亚胺可以通过使N，N'，4,4'-二苯基双马来酰亚胺与巴比妥酸或其衍生物反应来制备。 使用具有双层挤出模头的双层挤出涂布技术将涂料组合物施加到金属基材上。 最终的层压产品显示出聚酰亚胺涂层和基材之间的改善的剥离强度，以及改进的尺寸稳定性和表面平整度。

公开(公告)号：US09136559B2

公开(公告)日：2015-09-15

申请号：US13339384

申请日：2011-12-29

Applicant: Li-Duan Tsai ,  Yueh-Wei Lin ,  Chia-Chen Fang ,  Cheng-Liang Cheng ,  Jing-Pin Pan ,  Tsung-Hsiung Wang

Inventor： Li-Duan Tsai ,  Yueh-Wei Lin ,  Chia-Chen Fang ,  Cheng-Liang Cheng ,  Jing-Pin Pan ,  Tsung-Hsiung Wang

IPC: H01M10/0567 ,  H01M10/0525 ,  H01M4/58 ,  H01M10/42 ,  H01M4/40 ,  H01M4/587 ,  H01M4/62 ,  H01M10/0568 ,  H01M10/0569

CPC classification number: H01M10/0525 ,  H01M4/405 ,  H01M4/581 ,  H01M4/5815 ,  H01M4/587 ,  H01M4/621 ,  H01M4/625 ,  H01M4/626 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/4235 ,  H01M2300/0025 ,  Y02E60/122

Abstract: A non-aqueous electrolyte including a lithium salt, an organic solvent, and an electrolyte additive is provided. The electrolyte additive is a meta-stable state nitrogen-containing polymer formed by reacting Compound (A) and Compound (B). Compound (A) is a monomer having a reactive terminal functional group. Compound (B) is a heterocyclic amino aromatic derivative as an initiator. A molar ratio of Compound (A) to Compound (B) is from 10:1 to 1:10. A lithium secondary battery containing the non-aqueous electrolyte is further provided. The non-aqueous electrolyte of this disclosure has a higher decomposition voltage than a conventional non-aqueous electrolyte, such that the safety of the battery during overcharge or at high temperature caused by short-circuit current is improved.

Abstract translation: 提供了包含锂盐，有机溶剂和电解质添加剂的非水电解质。 电解质添加剂是通过使化合物（A）和化合物（B）反应而形成的间位稳定状态的含氮聚合物。 化合物（A）是具有反应性末端官能团的单体。 化合物（B）是作为引发剂的杂环氨基芳族衍生物。 化合物（A）与化合物（B）的摩尔比为10:1至1:10。 还提供含有非水电解质的锂二次电池。 本公开的非水电解质具有比常规的非水电解质更高的分解电压，从而提高了由于短路电流引起的过充电或高温下电池的安全性。

公开(公告)号：US09054376B2

公开(公告)日：2015-06-09

申请号：US13046781

申请日：2011-03-14

Applicant: Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Chung-Liang Chang ,  Yu-Ling Lin

Inventor： Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Chung-Liang Chang ,  Yu-Ling Lin

IPC: H01M4/88 ,  H01M4/36 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/62

CPC classification number: H01M4/366 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/622 ,  H01M4/624 ,  Y02E60/122

Abstract: A cathode material structure and a method for preparing the same are described. The cathode material structure includes a material body and a composite film coated thereon. The material body has a particle size of 0.1-50 μm. The composite film has a porous structure and electrical conductivity.

Abstract translation: 对阴极材料结构及其制备方法进行说明。 阴极材料结构包括材料体和涂覆在其上的复合膜。 材料体的粒径为0.1-50μm。 复合膜具有多孔结构和导电性。

公开(公告)号：US08389639B2

公开(公告)日：2013-03-05

申请号：US12623642

申请日：2009-11-23

Applicant: Chung-Liang Chang ,  Ya-Ting Hsu ,  Jing-Pin Pan

Inventor： Chung-Liang Chang ,  Ya-Ting Hsu ,  Jing-Pin Pan

IPC: C08F273/00 ,  C08F269/00 ,  C08F267/10

CPC classification number: B01D67/0006 ,  B01D71/32 ,  B01D71/64 ,  B01D71/76 ,  B01D71/82 ,  B01D2323/38 ,  B01D2325/26 ,  C08J5/2237 ,  C08J2327/18 ,  C08J2381/06 ,  C08J2400/202 ,  H01M8/1023 ,  H01M8/103 ,  H01M8/1039 ,  H01M8/1041 ,  H01M8/1081 ,  Y02P70/56

Abstract: A proton exchange membrane comprising modified hyper-branched polymer is disclosed. The proton exchange membrane includes 85-90 wt % of sulfonated tetrafluorethylene copolymer and 15-10 wt % of modified hyper-branched polymer. The modified hyper-branched polymer comprises the bismaleimide (BMI)-based hyper-branched polymer, and parts of the chain ends of the hyper-branched polymer are sulfonated by the sulfonic compound. Also, the modified hyper-branched polymer and sulfonated tetrafluorethylene copolymer are interpenetrated to form an interpenetrating polymer. Furthermore, the modification step could be performed before or after forming the interpenetrating polymer. For example, the sulfonation is proceeded after forming the interpenetrating polymer. Alternatively, the sulfonation of the hyper-branched polymer could be proceeded before the formation of the interpenetrating polymer.

Abstract translation: 公开了包含改性的超支化聚合物的质子交换膜。 质子交换膜包括85-90重量％的磺化四氟乙烯共聚物和15-10重量％的改性超支化聚合物。 改性的超支化聚合物包含基于双马来酰亚胺（BMI）的超支化聚合物，并且超支化聚合物的链端部分被磺酸化合物磺化。 此外，改性的超支化聚合物和磺化四氟乙烯共聚物被互穿以形成互穿聚合物。 此外，改性步骤可以在形成互穿聚合物之前或之后进行。 例如，在形成互穿聚合物之后进行磺化。 或者，超支化聚合物的磺化可以在形成互穿聚合物之前进行。

公开(公告)号：US20090311611A1

公开(公告)日：2009-12-17

申请号：US12344074

申请日：2008-12-24

Applicant: Hung-Chun WU ,  Fu-Ming Wang ,  Ching-Yi Su ,  Chang-Rung Yang ,  Jing-Pin Pan ,  Yu-Chan Yen ,  Nae-Lih Wu

Inventor： Hung-Chun WU ,  Fu-Ming Wang ,  Ching-Yi Su ,  Chang-Rung Yang ,  Jing-Pin Pan ,  Yu-Chan Yen ,  Nae-Lih Wu

IPC: H01M6/16

CPC classification number: H01M10/0567 ,  H01M2/16 ,  H01M4/131 ,  H01M4/134 ,  H01M4/622 ,  H01M4/623 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569

Abstract: Disclosed is a lithium battery including a silicon negative electrode, a lithium mixed metal oxide positive electrode, a separator disposed between the negative and positive electrodes to define a reservoir region, an electrolytic solution filled in the reservoir region, and a sealant structure wrapped around the silicon negative electrode, the lithium mixed metal oxide positive electrode, the separator, and the electrolytic solution. The electrolytic solution includes an organic solvent, a lithium salt, and an additive. The additive includes a maleimide compound and vinylene carbonate. The silicon negative electrode of the lithium battery employing the described electrolytic solution has higher cycle efficiency and longer operating lifespan.

Abstract translation: 公开了一种锂电池，其包括硅负极，锂复合金属氧化物正极，设置在负极和正极之间的隔板，以限定储存区，填充在储存区中的电解液和围绕 硅负极，锂复合金属氧化物正极，隔膜和电解液。 电解液包括有机溶剂，锂盐和添加剂。 添加剂包括马来酰亚胺化合物和碳酸亚乙烯酯。 使用所述电解液的锂电池的硅负极具有更高的循环效率和更长的使用寿命。

公开(公告)号：US20080160404A1

公开(公告)日：2008-07-03

申请号：US12003599

申请日：2007-12-28

Applicant: Yueh-Wei Lin ,  Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Chang-Rung Yang ,  Jung-Mu Hsu

Inventor： Yueh-Wei Lin ,  Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Chang-Rung Yang ,  Jung-Mu Hsu

IPC: H01M10/40

CPC classification number: H01M10/0565 ,  H01M10/052 ,  H01M2300/004

Abstract: A gel polymer electrolyte precursor and a rechargeable cell comprising the same are provided. The gel polymer electrolyte precursor comprises a bismaleimide monomer or bismaleimide oligomer, a compound having formula (I): , a non-aqueous metal salt electrolyte, a non-protonic solvent, and a free radical initiator, wherein the bismaleimide oligomer is prepared by reaction of barbituric acid and bismaleimide, X comprises oxygen, organic hydrocarbon compounds, organic hydrocarbon oxide compounds, oligomers or polymers, n is 2 or 3, and A independently comprises wherein m is 0˜6, X comprises hydrogen, cyano, nitro or halogen, and R1 independently comprises hydrogen or C1˜4 alkyl.

Abstract translation: 提供了一种凝胶聚合物电解质前体和包含该前体的可充电电池。 凝胶聚合物电解质前体包含双马来酰亚胺单体或双马来酰亚胺低聚物，具有式（I）的化合物：非水金属盐电解质，非质子溶剂和自由基引发剂，其中双马来酰亚胺低聚物通过反应 的巴比妥酸和双马来酰亚胺，X包括氧，有机烃化合物，有机烃氧化物，低聚物或聚合物，n为2或3，A独立地包含其中m为0〜6，X为氢，氰基，硝基或卤素， R 1和R 2独立地包括氢或C 1-4烷基。

公开(公告)号：US06780943B2

公开(公告)日：2004-08-24

申请号：US10162400

申请日：2002-06-05

Applicant: Shur-Fen Liu ,  Meng-Huei Chen ,  Jinn-Shing King ,  Jing-Pin Pan

Inventor： Shur-Fen Liu ,  Meng-Huei Chen ,  Jinn-Shing King ,  Jing-Pin Pan

IPC: C08K336

CPC classification number: H05K1/0313 ,  C08F283/08 ,  C08K5/3415 ,  C08K5/3462 ,  C08L63/00 ,  C08L71/126 ,  C08F222/40 ,  C08L71/12 ,  C08L2666/22

Abstract: A resin composition useful in the fabrication of circuit boards comprises (i) 1˜15 W % of bismaleimide modified by barbituric acid (BTA) and its derivatives; and (ii) 20˜50 wt % of polyphenylene ether (PPE) chain-broken in a phenol resin; wherein the phenol resin is terpene phenol resin or dicyclopentadiene phenol resin. Other additives, such as curing agent, catalyst or inorganic particle additive can be added as well, based on requirements. According to the invention, terpene novolac resin and initiator (peroxide) are added in polyphenylene ether so that molecules are rearranged to form a PPE resin having lower molecular weight and higher crosslinking density. Furthermore, BMI/epoxy resin/PPE are combined in different weight percentages. Semi-interpenetrating polymer network structures are thus formed. Consequently, Tg and resistances both to heat and solvent of the resin are increased.

Abstract translation: 用于制造电路板的树脂组合物包含（i）1〜15％的由巴比妥酸（BTA）及其衍生物改性的双马来酰亚胺; 和（ii）在酚醛树脂中链断裂的20〜50重量％的聚苯醚（PPE）; 其中所述酚醛树脂是萜烯酚树脂或二环戊二烯酚树脂。 也可以根据要求加入其他添加剂，如固化剂，催化剂或无机颗粒添加剂。 根据本发明，将萜烯酚醛清漆树脂和引发剂（过氧化物）加入到聚苯醚中，使分子重新排列形成具有较低分子量和较高交联密度的PPE树脂。 此外，BMI /环氧树脂/ PPE以不同的重量百分比组合。 因此形成半互穿聚合物网络结构。 因此，提高了Tg和对树脂的热和溶剂的电阻。

公开(公告)号：US5418066A

公开(公告)日：1995-05-23

申请号：US198352

申请日：1994-02-18

Applicant: Han L. Chen ,  Syh-Ming Ho ,  Tsung H. Wang ,  Jing-Pin Pan

Inventor： Han L. Chen ,  Syh-Ming Ho ,  Tsung H. Wang ,  Jing-Pin Pan

IPC: C08G73/18 ,  H05K1/03 ,  B32B15/08

CPC classification number: C08G73/18 ,  H05K1/0346 ,  Y10T428/31681 ,  Y10T428/31721

Abstract: A polyimide/copper foil laminate prepared using a polyimide composition that does not require an adhesive layer between the polyimide substrate and the copper foil. A polyimide precursor is first prepared from a monomer composition, which comprises a dianhydride and an imidazole-containing or benzimidazole-containing compound, or mixture thereof. The polyimide precursor is then coated onto a copper foil and subsequently subject to an imidization reaction to form a polyimide/copper foil laminate, which exhibits excellent peel strength and flatness while retaining all the advantageous properties that are characteristic of polyimide resins, such as excellent mechanical strength and heat and chemical resistance. Because the polyimide/copper foil laminates disclosed in the present invention are made without the need to apply an ahsesive layer, the process of manufacturing the same is greatly simplified and the cost of production therefor can be substantially reduced. Furthermore, many of the problems caused by the inferior chemical and/or physical properties of the adhesive layer are completely eliminated.

Abstract translation: 使用在聚酰亚胺基板和铜箔之间不需要粘合剂层的聚酰亚胺组合物制备的聚酰亚胺/铜箔层压体。 聚酰亚胺前体首先由包含二酐和含咪唑或苯并咪唑的化合物或其混合物的单体组合物制备。 然后将聚酰亚胺前体涂覆在铜箔上，随后进行酰亚胺化反应以形成聚酰亚胺/铜箔层压体，其表现出优异的剥离强度和平坦度，同时保持聚酰亚胺树脂特征的所有有利特性，例如优异的机械 强度和耐热性和耐化学性。 由于本发明中公开的聚酰亚胺/铜箔层叠体不需要施加有效层，因此大大简化了其制造工艺，并且可以显着降低其生产成本。 此外，完全消除了由粘合剂层的较差化学和/或物理性质引起的许多问题。

公开(公告)号：US5310850A

公开(公告)日：1994-05-10

申请号：US966738

申请日：1992-10-26

Applicant: Jyh-Chien Chen ,  Sheng-Yaw Hsu ,  Tzong-Ming Lee ,  Jing-Pin Pan

Inventor： Jyh-Chien Chen ,  Sheng-Yaw Hsu ,  Tzong-Ming Lee ,  Jing-Pin Pan

IPC: C08G18/34 ,  H01B3/30 ,  C08G18/66

CPC classification number: C08G18/345 ,  H01B3/302 ,  H01B3/303

Abstract: Disclosed is a novel linear urethane-amide-imide copolymer composition obtained from first reacting X mols of diol compound, which had been dissolved in an inert organic solvent, with Y mols of diisocyanate compound at room temperature to produce an intermediate reaction product, followed by reacting the intermediate reaction product with Z mols of trimellitic anhydride at elevated temperatures, wherein Y is greater than X (i.e., the amount of diisocyante groups is in excess) and approximately equals the sum of X plus Z. The polyurethane copolymer composition obtained from this process contains urethane, amide and imide groups on the polymer backbone, exhibits excellent mechanical and electric properties and heat resistance, and does not suffer from the phase separation problems observed from polyurethane-polyamideimide blends.

Abstract translation: 公开了一种新型的线性氨基甲酸酯 - 酰胺 - 酰亚胺共聚物组合物，其由室温下溶解在惰性有机溶剂中的二醇化合物的X摩尔与二异氰酸酯化合物的Y摩尔得到，产生中间反应产物， 在高温下使中间反应产物与偏苯三酸酐的Z摩尔反应，其中Y大于X（即，二异氰酸酯基团的量过量），并且大约等于X加Z的总和。由此获得的聚氨酯共聚物组合物 方法在聚合物主链上含有氨基甲酸酯，酰胺和酰亚胺基团，表现出优异的机械和电学性能和耐热性，并且不会遭受聚氨酯 - 聚酰胺酰亚胺共混物观察到的相分离问题。