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    SURFACE-MODIFIED ZEOLITES AND METHODS FOR PREPARING THE SAME
    2.
    发明申请
    SURFACE-MODIFIED ZEOLITES AND METHODS FOR PREPARING THE SAME 有权
    表面改性的沸石及其制备方法

    公开(公告)号：US20130296160A1

    公开(公告)日：2013-11-07

    申请号：US13938634

    申请日：2013-07-10

    Applicant: UOP LLC

    Inventor： Laszlo T. Nemeth ,  Feng Xu

    IPC: B01J29/85

    CPC classification number: B01J29/85 ,  B01J29/06 ,  B01J29/40 ,  B01J2229/123 ,  B01J2229/126 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/42 ,  C01B39/026

    Abstract: Surface-modified zeolites and methods for preparing surface-modified zeolites are provided. A hybrid polymer formed from a silicon alkoxide and a metal alkoxide, a co-monomer, or both, is contacted with a zeolite suspension. The zeolite suspension comprises a sodium-, an ammonium-, or a hydrogen-form zeolite and a solvent. The hybrid polymer and zeolite suspension are contacted under conditions sufficient to deposit hybrid polymer on external surfaces of the zeolite to form a treated zeolite. Solvent is removed therefrom. The treated zeolite is dried and calcinated to form a dried and calcinated treated zeolite. Forming of the zeolite suspension and the contacting, removing, drying, and calcinating steps are provided in one selectivation sequence to produce a surface-modified zeolite from the ammonium-form zeolite and the hydrogen-form zeolite. If the dried and calcinated treated zeolite is a sodium-form zeolite, the sodium is exchanged with ammonium and then additionally dried and calcinated.

    Abstract translation: 提供表面改性沸石和制备表面改性沸石的方法。 由硅醇盐和金属醇盐，共聚单体或两者形成的杂化聚合物与沸石悬浮液接触。 沸石悬浮液包含钠，铵或氢形式的沸石和溶剂。 混合聚合物和沸石悬浮液在足以在沸石的外表面上沉积杂化聚合物以形成经处理的沸石的条件下接触。 从中除去溶剂。 将经处理的沸石干燥并煅烧以形成经干燥和煅烧的处理的沸石。 沸石悬浮液的形成和接触，除去，干燥和煅烧步骤在一个选择序列中提供，以从铵型沸石和氢型沸石产生表面改性的沸石。 如果干燥和煅烧的经处理的沸石是钠型沸石，则钠与铵交换，然后另外干燥和煅烧。

    TRANSALKYLATION / DISPROPORTIONATION OR THERMAL HYDRODEALKYLATION HYDROCARBON PROCESSING METHODS AND SYSTEMS EMPLOYING AN INCREASED ETHYLBENZENE FEED CONTENT
    4.
    发明申请
    TRANSALKYLATION / DISPROPORTIONATION OR THERMAL HYDRODEALKYLATION HYDROCARBON PROCESSING METHODS AND SYSTEMS EMPLOYING AN INCREASED ETHYLBENZENE FEED CONTENT 有权
    渗透/分解或热水解氢化处理方法和系统使用增加的乙烯进料含量

    公开(公告)号：US20160060189A1

    公开(公告)日：2016-03-03

    申请号：US14472658

    申请日：2014-08-29

    Applicant: UOP LLC

    Inventor： Lawrence E. Sullivan ,  Emily Harrell ,  Feng Xu ,  Jason L. Noe

    IPC: C07C6/06

    CPC classification number: C07C6/126 ,  C07C4/16 ,  C07C15/04 ,  C07C15/08

    Abstract: Methods and apparatus for processing hydrocarbons are provided. In one example, a method for processing hydrocarbons includes the step of providing feed stream including toluene, ethylbenzene, mixed xylenes, and C9 hydrocarbons. Ethylbenzene is present in the feed stream in an amount of at least about 20% by weight of total C8 aromatic hydrocarbons present in the feed stream. The method further includes the step of subjecting the feed stream to ethylbenzene conversion to form a benzene-containing product stream that includes benzene.

    Abstract translation: 提供了处理碳氢化合物的方法和设备。 在一个实例中，用于处理烃的方法包括提供包括甲苯，乙苯，混合二甲苯和C 9烃的进料流的步骤。 乙基苯以进料流中存在的总C 8芳族烃的至少约20重量％的量存在于进料流中。 该方法还包括将进料流转化为乙苯以形成包含苯的含苯产物流的步骤。

    Catalyst regenerator process
    5.
    发明授权
    Catalyst regenerator process 有权
    催化剂再生器工艺

    公开(公告)号：US08993467B2

    公开(公告)日：2015-03-31

    申请号：US13970853

    申请日：2013-08-20

    Applicant: UOP LLC

    Inventor： Bryan J. Egolf ,  Feng Xu ,  Raelynn M. Miller

    IPC: B01J38/40

    CPC classification number: B01J23/96 ,  B01J8/085 ,  B01J8/087 ,  B01J8/12 ,  B01J38/12 ,  B01J38/14 ,  B01J38/44 ,  B01J2208/00504

    Abstract: A method of operating a continuous or semi-continuous system for a catalyst regeneration process. The system comprises a regenerator, the regenerator comprising a combustion zone and a halogenation zone. The catalyst is fed into the regenerator. A circulating regeneration gas is introduced into a regenerator circuit including oxygen, the circulating regeneration gas having a nitrogen concentration that is less than air. Oxygen from the circulating regeneration gas reacts with the coke to provide water and carbon dioxide. Water and the carbon dioxide formed in this first reaction then further react with the coke to form carbon monoxide and hydrogen.

    Abstract translation: 一种用于催化剂再生过程的连续或半连续系统的操作方法。 该系统包括再生器，再生器包括燃烧区和卤化区。 将催化剂进料到再生器中。 循环再生气体被引入到包含氧的再生器回路中，循环再生气体的氮浓度小于空气。 来自循环再生气体的氧气与焦炭反应以提供水和二氧化碳。 然后在该第一反应中形成的水​​和二氧化碳进一步与焦炭反应以形成一氧化碳和氢气。

    CATALYST REGENERATOR PROCESS
    6.
    发明申请
    CATALYST REGENERATOR PROCESS 有权
    催化再生器工艺

    公开(公告)号：US20150057146A1

    公开(公告)日：2015-02-26

    申请号：US13970853

    申请日：2013-08-20

    Applicant: UOP LLC

    Inventor： Bryan J. Egolf ,  Feng Xu ,  Raelynn M. Miller

    IPC: B01J38/40

    CPC classification number: B01J23/96 ,  B01J8/085 ,  B01J8/087 ,  B01J8/12 ,  B01J38/12 ,  B01J38/14 ,  B01J38/44 ,  B01J2208/00504

    Abstract: A method of operating a continuous or semi-continuous system for a catalyst regeneration process. The system comprises a regenerator, the regenerator comprising a combustion zone and a halogenation zone. The catalyst is fed into the regenerator. A circulating regeneration gas is introduced into a regenerator circuit including oxygen, the circulating regeneration gas having a nitrogen concentration that is less than air. Oxygen from the circulating regeneration gas reacts with the coke to provide water and carbon dioxide. Water and the carbon dioxide formed in this first reaction then further react with the coke to form carbon monoxide and hydrogen.

    Abstract translation: 一种用于催化剂再生过程的连续或半连续系统的操作方法。 该系统包括再生器，再生器包括燃烧区和卤化区。 将催化剂进料到再生器中。 循环再生气体被引入到包含氧的再生器回路中，循环再生气体的氮浓度小于空气。 来自循环再生气体的氧气与焦炭反应以提供水和二氧化碳。 然后在该第一反应中形成的水​​和二氧化碳进一步与焦炭反应以形成一氧化碳和氢气。

    AROMATIC ALKYLATION PROCESS
    8.
    发明申请
    AROMATIC ALKYLATION PROCESS 有权

    公开(公告)号：US20210171421A1

    公开(公告)日：2021-06-10

    申请号：US16705791

    申请日：2019-12-06

    Applicant: UOP LLC

    Inventor： Gregory B. Kuzmanich ,  Richard A. Johnson, II ,  Joseph A. Montalbano ,  Feng Xu ,  Robert E. Tsai

    IPC: C07C2/86

    Abstract: Processes and apparatuses for alkylating aromatic hydrocarbons with an alkylating reagent to produce an alkylated aromatic product are described. The processes and apparatuses use a riser reactor operated at a superficial velocity of 10 m/s to 25 m/s to produce the alkylated aromatic product. In some embodiments, a combination of steam and aromatic hydrocarbon is used to lift the catalyst.

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