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    Preparation of indolenines
    6.
    发明授权
    Preparation of indolenines 失效
    吲哚啉的制备

    公开(公告)号：US5210214A

    公开(公告)日：1993-05-11

    申请号：US866586

    申请日：1992-04-10

    申请人： Klaus Diehl ,  Martin Fischer ,  Manfred Dimmler

    发明人： Klaus Diehl ,  Martin Fischer ,  Manfred Dimmler

    IPC分类号： B01J27/10 ,  B01J27/125 ,  B01J27/128 ,  B01J27/135 ,  C07B61/00 ,  C07D209/08 ,  C07D317/38

    CPC分类号： C07D317/38 ,  C07D209/08

    摘要： A process for preparing indolenines of the formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are independently of one another hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.3 -C.sub.8 -cycloalkyl, aryl, C.sub.7 -C.sub.20 -alkylphenyl, C.sub.7 -C.sub.20 -phenalkyl, or R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3 together are an unsubstituted or C.sub.1 -C.sub.12 -alkyl-substituted C.sub.3 -C.sub.8 -alkylene chain,X and Y are independently of one another hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.2 -C.sub.8 -alkoxyalkyl, C.sub.2 -C.sub.8 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkylsulfonyl, halogen, nitro or cyano,by reacting a 4-methylene-1,3-dioxolan-2-one of the formula II ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each as defined above, with an aniline of the formula III ##STR3## where X and Y are each as defined above, in the presence of a Lewis acid and in the presence or absence of a halide of main group 1 or 2 of the Periodic Table at from 100.degree. to 350.degree. C. and at from 1 to 50 bar, comprises carrying out the reaction in a polar solvent.

    摘要翻译： 其中R1，R2和R3彼此独立地为氢，C1-C20-烷基，C2-C20-烯基，C3-C8-环烷基，芳基，C7-环烷基， C20烷基苯基，C7-C20-苯基烷基或R1和R2或R1和R3一起是未取代的或C 1 -C 12烷基取代的C 3 -C 8亚烷基链，X和Y彼此独立地为氢，C 1 -C 8 - 烷基，C 1 -C 8 - 烷氧基，C 2 -C 8 - 烷氧基烷基，C 2 -C 8 - 烷氧基羰基，C 1 -C 4 - 烷基磺酰基，卤素，硝基或氰基，通过将4-亚甲基-1,3-二氧戊环-2-酮 其中R 1，R 2和R 3各自如上所定义，其中X和Y各自如上定义，在路易斯酸存在下，式III的苯胺（III） 在100至350℃和1至50巴的条件下，在存在或不存在元素周期表的主要1或2族的卤化物的存在或不存在下，包括在极性溶剂中进行反应。

    Method for hydroformylating olefins having between 20 and 400 carbon atoms
    7.
    发明授权
    Method for hydroformylating olefins having between 20 and 400 carbon atoms 有权
    加氢甲酰化具有20至400个碳原子的烯烃的方法

    公开(公告)号：US06777503B2

    公开(公告)日：2004-08-17

    申请号：US10181454

    申请日：2002-07-18

    申请人： Harald Schwahn ,  Gerhard Borchert ,  Klaus Diehl ,  Armin Volker Grenacher ,  Friedrich Sauer

    发明人： Harald Schwahn ,  Gerhard Borchert ,  Klaus Diehl ,  Armin Volker Grenacher ,  Friedrich Sauer

    IPC分类号： C08F1000

    CPC分类号： C07C45/50 ,  C07C45/80 ,  C07C47/21

    摘要： A process for the hydroformylation of olefins having from 20 to 400 carbon atoms by reaction of the olefins with synthesis gas in the presence of a cobalt carbonyl catalyst and recovery of the cobalt catalyst by extraction of the reaction product with an aqueous acidic solution in the presence of oxygen and separation of the organic and aqueous phases, wherein (a) the aqueous phase is separated from the organic phase by means of gravitational forces to the extent that the proportion of aqueous phase dispersed in the organic phase is 2% by weight or less, based on the organic phase, and (b) the organic phase obtained in step (a) is exposed to an electric field to coalesce the remaining dispersed aqueous phase, is described. In this way, the residual cobalt content of the hydroformylation product can be reduced to less than 1 ppm.

    摘要翻译： 在羰基钴催化剂存在下，通过烯烃与合成气的反应，通过在酸存在下用酸性水溶液萃取反应产物来回收钴催化剂，从而使具有20至400个碳原子的烯烃加氢甲酰化的方法 的氧气和有机相和水相的分离，其中（a）通过重力将水相与有机相分离，使得分散在有机相中的水相的比例为2重量％以下 ，（b）将步骤（a）中获得的有机相暴露于电场以使剩余的分散的水相结合，这样，加氢甲酰化产物的残余钴含量可以 减少到1 ppm以下。