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    Carbamate-functionalized addition polymers and addition polymer-rubber copolymers derived therefrom
    1.
    发明授权
    Carbamate-functionalized addition polymers and addition polymer-rubber copolymers derived therefrom 失效
    氨基甲酸酯官能化加成聚合物和由其衍生的加成聚合物 - 橡胶共聚物

    公开(公告)号：US5310795A

    公开(公告)日：1994-05-10

    申请号：US77262

    申请日：1993-06-17

    申请人： William P. England ,  Gregory J. Stoddard ,  James J. Scobbo, Jr.

    发明人： William P. England ,  Gregory J. Stoddard ,  James J. Scobbo, Jr.

    IPC分类号： C08G81/02 ,  C08L55/00

    CPC分类号： C08G81/02

    摘要： Novel addition polymers and copolymers derived from carbamate-functionalized vinyl monomers, and optionally one or more conventional vinyl monomers such as acrylonitrile and/or styrene, are disclosed. When the addition polymers or copolymers are melt processed with an elastomer containing moieties reactive with amines, novel addition polymer-rubber copolymers are formed which are useful as compatibilizers and impact modifiers in plastic blends, such as AES.

    摘要翻译： 公开了衍生自氨基甲酸酯官能化的乙烯基单体和任选的一种或多种常规乙烯基单体如丙烯腈和/或苯乙烯的新型加成聚合物和共聚物。 当加成聚合物或共聚物用含有与胺反应的部分的弹性体熔融加工时，形成新的加成聚合物 - 橡胶共聚物，其可用作塑料共混物如AES中的增容剂和抗冲改性剂。

    Core-shell ABS copolymers and method for their preparation
    2.
    发明授权
    Core-shell ABS copolymers and method for their preparation 失效
    核壳ABS共聚物及其制备方法

    公开(公告)号：US5346953A

    公开(公告)日：1994-09-13

    申请号：US132951

    申请日：1993-10-07

    申请人： James J. Scobbo, Jr. ,  Gregory J. Stoddard

    发明人： James J. Scobbo, Jr. ,  Gregory J. Stoddard

    IPC分类号： C08F279/04 ,  C08F279/00 ,  C08G81/02 ,  C08L51/04 ,  C08F279/02 ,  C08L33/04 ,  C08L33/20

    CPC分类号： C08G81/022 ,  Y10S525/902

    摘要： Core-shell ABS copolymers having an SAN shell completely surrounding the diene core are provided by melt blending an aliphatic diene polymer with an SAN copolymer, said copolymer containing functional groups capable of reacting with the diene polymer. For example, the SAN copolymer may contain azide groups capable of reacting with the olefinic groups in the diene polymer, or both the SAN copolymer and the diene polymer may contain other functional groups capable of interreaction, such as acidic (e.g., maleic anhydride) groups in the diene and epoxy (e.g., glycidyl methacrylate) groups in the SAN copolymer.

    摘要翻译： 通过将脂族二烯聚合物与SAN共聚物熔融共混来提供具有完全包围二烯核的SAN壳的核 - 壳ABS共聚物，所述共聚物含有能够与二烯聚合物反应的官能团。 例如，SAN共聚物可以含有能够与二烯聚合物中的烯基反应的叠氮基，或者SAN共聚物和二烯聚合物都可以含有能够相互作用的其它官能团，例如酸性（例如马来酸酐）基团 在SAN共聚物中的二烯和环氧（例如，甲基丙烯酸缩水甘油酯）基团中。

    Elastomeric blends and method for their preparation
    3.
    发明授权
    Elastomeric blends and method for their preparation 失效
    弹性体共混物及其制备方法

    公开(公告)号：US5334659A

    公开(公告)日：1994-08-02

    申请号：US66289

    申请日：1993-05-24

    申请人： James J. Scobbo, Jr. ,  Gregory J. Stoddard

    发明人： James J. Scobbo, Jr. ,  Gregory J. Stoddard

    IPC分类号： C08G81/02 ,  C08L23/26 ,  C08L51/04 ,  C08L55/02 ,  C08L101/00

    CPC分类号： C08L23/26 ,  C08G81/02 ,  C08G81/021 ,  C08L51/04

    摘要： Copolymer compositions useful as impact modifiers are prepared by blending, under reactive conditions, at least one functionalized addition polymer with an excess of at least one functionalized elastomer reactive therewith to form a preblend, and subsequently blending said preblend, under reactive conditions, with a further amount of at least one functionalized addition polymer. The preferred addition polymers and elastomers are carbamate-functionalized styrene-acrylonitrile copolymers and maleic anhydride-grafted EPDM elastomers, respectively. The product of the two-step blending operation is a composition comprising a continuous addition polymer phase and elastomer particles dispersed therein, said elastomer particles containing occluded addition polymer. Said composition is stabilized by copolymer formation between the elastomer particles and the addition polymer.

    摘要翻译： 可用作抗冲击改性剂的共聚物组合物通过在反应条件下共混至少一种官能化的加成聚合物与过量的与其反应的至少一种官能化弹性体以形成预混合物，然后在反应条件下将所述预混合物与另外 至少一种官能化加成聚合物的量。 优选的加成聚合物和弹性体分别是氨基甲酸酯官能化的苯乙烯 - 丙烯腈共聚物和马来酸酐接枝的EPDM弹性体。 两步混合操作的产物是包含连续加成聚合物相和分散在其中的弹性体颗粒的组合物，所述弹性体颗粒含有封闭的加成聚合物。 所述组合物通过弹性体颗粒与加成聚合物之间的共聚物形成而稳定。

    Core-shell ABS copolymers and method for their preparation
    4.
    发明授权
    Core-shell ABS copolymers and method for their preparation 失效
    核壳ABS共聚物及其制备方法

    公开(公告)号：US5384361A

    公开(公告)日：1995-01-24

    申请号：US148547

    申请日：1993-11-08

    申请人： James J. Scobbo, Jr. ,  Gregory J. Stoddard

    发明人： James J. Scobbo, Jr. ,  Gregory J. Stoddard

    IPC分类号： C08F279/04 ,  C08F279/00 ,  C08G81/02 ,  C08L51/04 ,  C08L55/02

    CPC分类号： C08G81/022 ,  Y10S525/902

    摘要： Core-shell ABS copolymers having an SAN shell completely surrounding the diene core are provided by melt blending an aliphatic diene polymer with an SAN copolymer, said copolymer containing functional groups capable of reacting with the diene polymer. For example, the SAN copolymer may contain azide groups capable of reacting with the olefinic groups in the diene polymer, or both the SAN copolymer and the diene polymer may contain other functional groups capable of interreaction, such as acidic (e.g., maleic anhydride) groups in the diene and epoxy (e.g., glycidyl methacrylate) groups in the SAN copolymer.

    摘要翻译： 通过将脂族二烯聚合物与SAN共聚物熔融共混来提供具有完全包围二烯核的SAN壳的核 - 壳ABS共聚物，所述共聚物含有能够与二烯聚合物反应的官能团。 例如，SAN共聚物可以含有能够与二烯聚合物中的烯基反应的叠氮基，或者SAN共聚物和二烯聚合物都可以含有能够相互作用的其它官能团，例如酸性（例如马来酸酐）基团 在SAN共聚物中的二烯和环氧（例如，甲基丙烯酸缩水甘油酯）基团中。