Processes for the production of mono- and multifilaments and staple
fibers based on kolyarylene sulfides and high-strength polyarylene
sulfide fibers

    公开(公告)号:US5215819A

    公开(公告)日:1993-06-01

    申请号:US621403

    申请日:1990-12-03

    IPC分类号: D01D5/08 D01F6/76

    摘要: This invention relates to processes for the production of mono- and multifilaments and also staple fibers of multifilaments based on polyarylene sulfides, preferably substantially linear polyarylene sulfides and, more preferably, substantially linear poly-p-phenylene sulfide by melt spinning, multistage stretching and optionally crimping and setting.As a result of the treatment by blowing of air onto the stabilized spun filaments in the first stretching stages at temperatures .ltoreq.100.degree. C. (preferably in stretching baths, more particularly in boiling water), the chain molecules are oriented; the orientation and crystallinity required for high strengths is achieved by afterstretching (in hot air) at elevated temperature. The residence times in the first stage required for effective stretching in accordance with the invention can only be varied within relatively narrow limits in order subsequently to achieve the calculated orientations and effects, particularly high strengths, crystallinities and densities. Overly long residence times at temperatures above 100.degree. C. result in elongation of the material with no additional orientation and hence with an inadequate increase in strength.To increase crystallinity and strength in the production of mono- and multifilaments, multistage stretching may be followed by a thermal aftertreatment; in the staple fiber process, the material is additionally crimped, set (in the absence of tension) and cut. Where an aerodynamic crimping nozzle is used, as is preferably the case, stretching has to be carried out in accordance with the invention in such a way that the fibers are left with sufficiently high shrinkage which is important for crimping and subsequent processing. Crimping is improved by setting in the absence of tension. Relatively high-tensile fibers with sufficiently high residual crimping for subsequent processing are obtained.Textile-denier fibers (up to about 20 dtex) having hitherto unknown strengths of >6 cN/dtex, preferably >6.2 cN/dtex and, more preferably, >6.4 cN/dtex are claimed.

    Processes for the production of mono- and multifilaments and staple
fibers based on polyarylene sulfides
    2.
    发明授权
    Processes for the production of mono- and multifilaments and staple fibers based on polyarylene sulfides 失效
    用于生产基于聚亚芳基硫化物的单丝和复丝和短纤维的方法

    公开(公告)号:US5024797A

    公开(公告)日:1991-06-18

    申请号:US522296

    申请日:1990-05-11

    CPC分类号: D01D5/08 D01F6/765

    摘要: Processes for the production of mono- and multifilaments and also staple fibers of multifilaments based on polyarylene sulfides by melt spinning, multistage stretching and setting. As a result of the treatment by blowing of air onto the stabilized spun filaments in the first stretching stages at temperatures .ltoreq.100.degree. C., the chain molecules are oriented; the orientation and crystallinity required for high strengths is achieved by afterstretching at elevated temperature. The residence times in the first stage required for effective stretching can only be varied within relatively narrow limits in order subsequently to achieve the calculated orientations and effects. Overly long residence times at temperatures above 100.degree. C. result in elongation of the material with no additional orientation and hence with an inadequate increase in strength.

    摘要翻译: 用于通过熔融纺丝,多段拉伸和定型来生产单丝和多丝以及基于聚亚芳基硫化物的复丝的短纤维的方法。 作为通过在100℃的温度下在第一拉伸阶段中将空气吹到稳定纺丝上进行处理的结果,链分子被取向; 高强度所需的取向和结晶度通过在升高的温度下拉伸来实现。 在有效拉伸所需的第一阶段中的停留时间只能在相对窄的范围内变化,以便随后实现计算的取向和效果。 超过100℃的过长停留时间导致材料的伸长,没有额外的取向,因此强度不足。

    Elastane package
    4.
    发明授权
    Elastane package 失效
    弹性包装

    公开(公告)号:US06774064B1

    公开(公告)日:2004-08-10

    申请号:US09958422

    申请日:2002-01-11

    IPC分类号: B32B100

    摘要: An elastance spool is described which comprises a winding of elastane threads having a titre of greater than 160 dtex, particularly from 160 dtex to 1400 dtex, and a bobbin weight of elastane threads of at least 1.5 kg, in which the elastane threads have a ribbon-shaped fiber cross-section, wherein the ratio of the width of the elastane threads to the thickness of the elastane threads in cross-section is at least three to one. The elastane spool is used for the production of textile sheet products and for the production of disposable articles of hygiene.

    摘要翻译: 描述了一种弹性卷轴,其包括具有大于160dtex,特别是160dtex至1400dtex的滴定度的弹性纱线的卷绕和至少1.5kg的弹性纤维纱线的筒管重量,其中弹性纤维线具有带 形纤维横截面,其中弹性纤维丝的宽度与弹性纤维线的横截面的厚度之比至少为三比一。 弹性线轴用于生产纺织片材产品和生产一次性卫生用品。

    Process of making elastane yarn
    5.
    发明授权
    Process of making elastane yarn 失效
    制造弹性纱线的工艺

    公开(公告)号:US06602453B1

    公开(公告)日:2003-08-05

    申请号:US09720708

    申请日:2000-12-29

    IPC分类号: D01D506

    摘要: Described are a process for producing elastane yarn having a linear density of at least 2500 dtex by the wet spinning process and the thereby producible coarse linear density elastane yarn having a wide cross section and a low residual solvent content. The process comprises the steps of spinning an up to 35% strength by weight stable-viscosity elastane solution into a coagulation bath, washing and optionally drawing, drying by contact heating, setting, spin finishing and winding the yarn, the filaments leaving the coagulation bath passing around a diverting roller disposed just above the coagulation bath liquid, the as-spun filament linear density amounting to not more than 1% of the value of the final linear density, the jet stretch ratio being within the range from 0.5 to 50, the contact heating temperature being at least 220° C. and the contact time of the elastane yarn being at least 2 seconds.

    摘要翻译: 描述了通过湿法纺丝法制造线密度为2500dtex的弹性纤维的方法,从而生产出具有宽截面和低残留溶剂含量的粗制线性密度弹性纤维纱。 该方法包括以下步骤:将高达35%的重量比的稳定粘度的丙烯腈溶液旋转到凝固浴中,洗涤并任选地拉伸,通过接触加热,凝固,旋涂和卷绕纱线干燥,离开凝固浴的长丝 围绕设置在凝固浴液体正上方的转向辊,所述纺丝长丝线密度为不超过最终线密度值的1%,喷射拉伸比在0.5至50的范围内, 接触加热温度至少为220℃,弹性纤维的接触时间为至少2秒。

    Apparatus and a process for the production of elastane filaments
    8.
    发明授权
    Apparatus and a process for the production of elastane filaments 失效
    用于生产弹性纤维丝的装置和方法

    公开(公告)号:US5961908A

    公开(公告)日:1999-10-05

    申请号:US40789

    申请日:1998-03-18

    摘要: A spinning noxxle apparatus for the production of elastane filaments from spinning solutions by the wet spinning method comprising a feed line (7) for the spinning solution, a filter unit (1) having a mixer element (2) and a filter element element (3), a spinning nozzle (5) for immersion in a precipation bath (11), and a connection piece (8) for the direct connection of the filter unit (1) and spinning nozzle (5), wherein the spinning nozzle (5) is joined to the connection piece (8) by a quick-release coupling connection (4), particularly a bayonet coupling (4).

    摘要翻译: 一种用于通过湿式纺丝方法由纺丝溶液生产弹性纤维丝的旋转式纱线装置,包括用于纺丝溶液的进料管线(7),具有混合元件(2)和过滤元件元件(3)的过滤器单元 ),用于浸渍在沉淀池(11)中的纺丝喷嘴(5)和用于直接连接过滤器单元(1)和纺丝喷嘴(5)的连接件(8),其中纺丝喷嘴(5) 通过快速释放联接连接件(4),特别是卡口式联接器(4)连接到连接件(8)。

    Elastane yarn having a linear density of at least 2500 dtex and a cross-sectional width to height ratio of at least 4:1
    9.
    发明授权
    Elastane yarn having a linear density of at least 2500 dtex and a cross-sectional width to height ratio of at least 4:1 失效
    线密度为2500dtex,截面宽高比至少为4:1的弹性纤维纱

    公开(公告)号:US06844060B2

    公开(公告)日:2005-01-18

    申请号:US10425457

    申请日:2003-04-29

    IPC分类号: D01F6/70 D01G6/00 D01G3/00

    摘要: Described are a process for producing elastane yarn having a linear density of at least 2500 dtex by the wet spinning process and the thereby producible coarse linear density elastane yarn having a wide cross section and a low residual solvent content. The process comprises the steps of spinning an up to 35% strength by weight stable-viscosity elastane solution into a coagulation bath, washing and optionally drawing, drying by contact heating, setting, spin finishing and winding the yarn, the filaments leaving the coagulation bath passing around a diverting roller disposed just above the coagulation bath liquid, the as-spun filament linear density amounting to not more than 1% of the value of the final linear density, the jet stretch ratio being within the range from 0.5 to 50, the contact heating temperature being at least 220° C. and the contact time of the elastane yarn being at least 2 seconds.

    摘要翻译: 弹性纤维横截面宽,残留溶剂含量低,线密度至少为2500dtex。