摘要:
A conductive carbon nanotube film having high tensile strength and initial tensile modulus comprises primarily oxidized small-diameter carbon nanotubes wherein the diameter of the small-diameter carbon nanotubes are at most about 3 nm. A method for making the film comprises refluxing an aqueous mixture comprising carbon nanotubes and an oxidizing agent to form a refluxed nanotube dispersion; forming a carbon nanotube film from the refluxed carbon nanotube dispersion; optionally removing nitric acid or other oxidizing agent from the carbon nanotube film; drying the carbon nanotube film; and heat-treating the carbon nanotube film to form a heat-treated carbon nanotube film. The method can also comprise sonicating the nanotubes prior to or after refluxing. A heat-treated small-diameter carbon nanotube film can have a tensile strength of over 70 MPa and an initial tensile modulus of about 5 GPa.
摘要:
The present invention relates to a high modulus macroscopic fiber comprising single-wall carbon nanotubes (SWNT) and an acrylonitrile-containing polymer. In one embodiment, the macroscopic fiber is a drawn fiber having a cross-sectional dimension of at least 1 micron. In another embodiment, the acrylonitrile polymer-SWNT composite fiber is made by dispersing SWNT in a solvent, such as dimethyl formamide or dimethyl acetamide, admixing an acrylonitrile-based polymer to form a generally optically homogeneous polyacrylonitrile polymer-SWNT dope, spinning the dope into a fiber, drawing and drying the fiber. Polyacrylonitrile/SWNT composite macroscopic fibers have substantially higher modulus and reduced shrinkage versus a polymer fiber without SWNT. A polyacrylonitrile/SWNT fiber containing 10 wt % SWNT showed over 100% increase in tensile modulus and significantly reduced thermal shrinkage compared to a control fiber without SWNT. With 10 wt % SWNT, the glass transition temperature of the polymer increased by more than 40° C.
摘要:
The invention relates to a film comprising greater than 80 wt % single-wall carbon nanotubes wherein the tensile modulus is at least about 6 GPa at 0.2% strain and the conductivity of the film is at least about 70,000 S/m. The tensile modulus is typically about 8 GPa at 0.2% strain. The method for making the film comprises preparing a solution of single-wall carbon nanotubes in a superacid, such as oleum containing approximately 20 to 30% sulfur trioxide, under a dry, oxygen-free atmosphere. The solution is placed on a surface in a moisture-containing atmosphere, wherein the solution absorbs moisture and acid leaches out. The film is washed to further remove acid, dried, and, optionally, subjected to a heat treatment. Besides free-standing films, coatings of single-wall carbon nanotubes can be made on a variety of surfaces including polymers, glass, metals, and ceramics. The surfaces can be flat planes, fibers or contour shapes.
摘要翻译:本发明涉及包含大于80重量%的单壁碳纳米管的膜,其中在0.2%应变下的拉伸模量为至少约6GPa,并且膜的导电率为至少约70,000S / m 2。 在0.2%应变下,拉伸模量通常约为8GPa。 制造该膜的方法包括在干燥,无氧气氛下,在含有约20-30%三氧化硫的发烟硫酸的超酸中制备单壁碳纳米管的溶液。 将溶液放置在含水气氛中的表面上,其中溶液吸收水分并酸浸出。 洗涤该膜以进一步除去酸,干燥,并且任选地进行热处理。 除了独立的膜,单壁碳纳米管的涂层可以在各种表面上制成,包括聚合物,玻璃,金属和陶瓷。 表面可以是平面,纤维或轮廓形状。
摘要:
The present invention relates to a supercapacitor, also known as an electrical double-layer capacitor or ultracapacitor, having electrode material comprising single-wall carbon nanotubes. The carbon nanotubes can be derivatized with functional groups. The electrode material is made by preparing a polymer-nanotube suspension comprising polymer and nanotubes, forming the polymer-nanotube suspension into a polymer-nanotube composite of the desired form, carbonizing the polymer-nanotube composite to form a carbonaceous polymer-nanotube material, and activating the material. The supercapacitor includes electrode material comprising activated carbonaceous polymer-nanotube material in contact with current collectors and permeated with an electrolyte, which may be either fluid or solid. In the case of a fluid or compressible electrolyte, an electrolyte-permeable separator or spacer is interposed between the electrodes to keep the electrodes from shorting. The supercapacitor made with electrodes comprising underivatized single-wall carbon nanotubes and polymer that has been carbonized and activated appears to operate as a non-Faradaic supercapacitor.
摘要:
The present invention relates to a supercapacitor, also known as an electrical double-layer capacitor or ultracapacitor, having electrode material comprising single-wall carbon nanotubes. The carbon nanotubes can be derivatized with functional groups. The electrode material is made by preparing a polymer-nanotube suspension comprising polymer and nanotubes, forming the polymer-nanotube suspension into a polymer-nanotube composite of the desired form, carbonizing the polymer-nanotube composite to form a carbonaceous polymer-nanotube material, and activating the material. The supercapacitor includes electrode material comprising activated carbonaceous polymer-nanotube material in contact with current collectors and permeated with an electrolyte, which may be either fluid or solid. In the case of a fluid or compressible electrolyte, an electrolyte-permeable separator or spacer is interposed between the electrodes to keep the electrodes from shorting. The supercapacitor made with electrodes comprising underivatized single-wall carbon nanotubes and polymer that has been carbonized and activated appears to operate as a non-Faradaic supercapacitor.
摘要:
A method and apparatus for cleaning a fluid comprising a fluid supply port for receiving a contaminated fluid; a fluid return port for providing a cleaned fluid; an evaporator for evaporating liquid contaminants from the fluid; a fluid line connecting the evaporator between the fluid supply port and the fluid return port; a sensor connected to at least one of the fluid filter, the evaporator, and the fluid line; a controller connected to an output of the sensor, wherein the controller includes: a processor; and a memory device including computer readable instructions which, when executed by the processor cause the processor to perform the steps of: receiving data from the sensor; comparing the data from the sensor to reference data; sending a control signal to at least one of the fluid filter and the evaporator based on comparing the data from the sensor to the reference data.
摘要:
In a method of making a carbon fiber, polyacrylonitrile is dissolved into a first solvent, thereby generating a first solution. A plurality of cellulose nano-structures is dispersed in a second solvent, thereby generating a first suspension. The first suspension is mixed with the first solution, thereby generating a first mixture. The first mixture is spun so as to draw fibers from the first mixture. The fibers are stabilized and then the fibers are carbonized. A fiber includes an elongated carbonized polyacrylonitrile matrix. A plurality of carbonized cellulose nano-structures is in the carbonized polyacrylonitrile matrix.
摘要:
WD-repeat proteins are very diverse, yet these are structurally related proteins that participate in a wide range of cellular functions. WDR13, a member of this family, is conserved from fishes to humans and localizes into the nucleus. To understand the in vivo function(s) of Wdr13 gene, we have created and characterized a mutant mouse strain lacking this gene. The mutant mice had higher serum insulin levels and increased pancreatic islet mass as a result of the enhanced beta cell proliferation. While a known cell cycle inhibitor, p21, was down regulated in the mutant islets overexpression of WDR13 in the pancreatic MIN6 cell line resulted in upregulation of p21, accompanied by retardation of cell proliferation. We suggest that WDR13 is a novel negative regulator of the pancreatic beta cell proliferation. Co-immunoprecipitation experiments showed that this protein interacts with estrogen receptors and various HDACs. We provide evidence to show that WDR13 can regulate estrogen receptors-mediated transcription both in HDAC-dependent and HDAC-independent manner. Given the higher insulin levels, better glucose clearance and the lack of insulin resistance in WDR13 deficient mice, we propose that this protein may be a potential candidate drug target for ameliorating impaired glucose metabolism in diabetes.
摘要:
Methods, software suites, and systems of generating a recovery snapshot and creating a virtual view of the recovery snapshot are disclosed. In an embodiment, a method includes generating a recovery snapshot at a predetermined interval to retain an ability to position forward and backward when a delayed roll back algorithm is applied and creating a virtual view of the recovery snapshot using an algorithm tied to an original data, a change log data, and a consistency data related to an event. The method may include redirecting an access request to the original data based on a meta-data information provided in the virtual view. The method may further include substantially retaining a timestamp data, a location of a change, and a time offset of the change as compared with the original data.
摘要:
A method for encoding a picture in a video sequence is provided that includes determining the current encoded size of the picture after coding a plurality of macroblocks in the picture, determining that encoding remaining macroblocks in the picture may cause the encoded size of the picture to exceed a maximum encoded picture size, computing a quantization scale responsive to the determining, wherein the quantization scale is computed such that the estimated encoded size of the remaining macroblocks if the remaining macroblocks are quantized with the quantization scale does not exceed the difference between the maximum encoded picture size and the current encoded picture size, and quantizing at least one of the remaining macroblocks with the new quantization scale.