摘要:
An efficient method for producing a hydrogen-containing gas for a fuel cell by using a gas produced by reforming reaction of an organic compound is disclosed. The method comprises the following steps: adding an oxygen-containing gas to a hydrogen-containing gas containing carbon monoxide to form a mixed gas, and bringing the mixed gas into contact with a catalyst comprising a ruthenium metal as a main component and having a carbon monoxide adsorption of not less than 1 mmol/g-ruthenium and a carbon monoxide adsorption index of not less than 0.5, to thereby oxidize and remove carbon monoxide.
摘要:
The present invention provides a catalyst for a fuel cell with excellent resistance for poisoning gas such as CO and the electrode using the same, and a high performance catalyst for a direct methanol-type fuel cell using methanol as fuel and the electrode using the same. For this purpose, the present invention uses a solid heteropolyacid catalyst for a fuel cell which is a partial salt of a heteropolyacid including a noble metal and/or a transition metal and having a molecular weight of 800 to 10000.
摘要:
By the vapor phase reaction of benzene or a monoalkylbenzene with an alkylating agent in the presence of a specific catalyst obtained by subjecting a zeolite to a treatment with a gas containing a silicic acid ester and then a calcination in an oxygen-containing gas, said zeolite being 10 or more with respect to its molar ratio of SiO.sub.2 /X.sub.2 O.sub.3 in which X is at best one member selected from the group consisting of Al, B and Cr and having a constraint index within the range of 1 to 15, various useful 1,4-dialkylbenzenes can be produced not only in high yield but also in high selectivity.
摘要翻译:通过使苯或单烷基苯与烷基化剂在存在特定催化剂的情况下进行气相反应,所述催化剂通过使沸石进行含硅酸酯的气体处理,然后在含氧气体中进行煅烧而获得,所述沸石 相对于SiO 2 / X 2 O 3的摩尔比为10以上,其中,X为选自Al,B和Cr中的一种以上且约束指数为1〜15的范围,各种有用的1, 4-二烷基苯不仅可以高产率而且以高选择性产生。
摘要:
The present invention provides a catalyst for a polymer electrolyte fuel cell including catalyst particles made of platinum supported on a carbon powder carrier, wherein the carbon powder carrier includes 0.7 to 3.0 mmol/g (based on the weight of the carrier) of a hydrophilic group bonded thereto; and the platinum particles have an average particle size of 3.5 to 8.0 nm and the platinum specific surface area based on CO adsorption (COMSA) of 40 to 100 m2/g. The catalyst for a polymer electrolyte fuel cell according to the present invention is a catalyst excellent in initial activity and satisfactory in durability.
摘要:
An object of the present invention is to provide a method for producing a liquefied fuel oil using biomass as a feedstock, in which a relatively inexpensive liquefaction apparatus is used; a good balance is maintained between the liquefaction of water-insoluble lignin and the liquefaction of water-soluble cellulose to achieve a high yield of the liquefied fuel oil based on the biomass solids content; and the amount of ash derived from an alkali catalyst and the like is low. The method for producing a liquefied fuel oil using biomass as a feedstock is characterized by adding, to biomass comprising lignocellulose, a solvent comprising an organic solvent and having a moisture content adjusted to 10 to 25 wt %, including moisture contained in the biomass, and liquefying the biomass at a temperature of 250 to 350° C.
摘要:
Conductive metal powders having high conductivity with minimized silver migration are characterized in that an average composition is represented by Ag.sub.x M.sub.1-x (wherein M is at least one metal selected from Ni, Co, Cu and Fe; 0.01.ltoreq.x.ltoreq.0.4) and has a region wherein a silver concentration progressively increases on moving from the inner part toward the surface. The conductive metal powders, which are useful as leads, electrodes and shielding from electromagnetic interference are prepared by solidifying rapidly a molten metal having the specific composition.
摘要:
Vapor phase methylation of phenols with methanol in contact with a vanadium oxide catalyst which may additionally contain iron oxide and at least one other oxide of magnesium, titanium, manganese, beryllium or boron.
摘要:
A high thermal expansion member consisting of such as an Fe--Ni--Cr based alloy, a low thermal expansion member consisting of such as an Fe--Ni based alloy, and an intermediary member, which comprises one kind of metal selected from Fe, Al and Cu or an alloy comprising these metals, possesses a thermal expansion coefficient .alpha..sub.3 which is located between those of the high thermal expansion member (thermal expansion coefficient .alpha..sub.1) and the low thermal expansion member (thermal expansion coefficient .alpha..sub.2) (.alpha..sub.1 >.alpha..sub.3 >.alpha..sub.2), and is interposed therebetween, are laminated to form a thermal deformation member for an electron tube or a thermal deformation member for electric control. The intermediary member, without adversely affecting strength or long term reliability of the thermal deformation member, contributes to manufacturing cost reduction and improvement of workability. In a color picture tube, the above described thermal deformation member for an electron tube is employed in a thermal deformation portion of a frame holder which one edge is solidly stuck to a panel and the other edge thereof is solidly stuck to a mask frame of a shadow mask. In an overcurrent protection, the above described thermal deformation member for electric current control is employed in a thermal deformation portion which opens a contact point.
摘要:
Disclosed is a Lewis acid catalyst composition comprising a specific mixed medium and a Lewis acid catalyst (II), wherein the specific mixed medium is mixed medium (I) comprising a perfluorinated aliphatic hydrocarbon (A) and at least one non-fluorinated hydrocarbon or a mixed medium (I′) comprising a perfluorinated aliphatic hydrocarbon (A), a perfluorinated aromatic hydrocarbon (C) and water (D), and wherein the Lewis acid catalyst (II) is at least one compound selected from the group consisting of compounds respectively represented by the following formulae (1), (2) and (3): (RfSO3)nM (1), [(RfSO2)2N]nM (2), and [(RfSO2)3C]nM (3). Also disclosed is a Lewis acid catalyst represented by the above-mentioned formula (3).
摘要:
The present invention provides a method of producing vinyl chloride polymers, including the steps of subjecting vinyl chloride monomer or a mixture of monomers containing vinyl chloride monomer to suspension polymerization reaction in an aqueous medium within a polymerization vessel equipped with a reflux condenser, and subsequently, after the completion of the polymerization reaction, recovering any unreacted monomer, wherein foam generated on the surface of the liquid phase inside the polymerization vessel is eliminated by discharging a high pressure water having a pressure of 20 kg/cm.sup.2 or more substantially linearly to the surface of the liquid phase. The high pressure water discharging is carried out at the polymerization step, particularly from the time when operation of the reflux condenser begins, and/or at the recovery step. A vinyl chloride polymer is thus obtained without the splashing of foam over the gaseous phase section of the polymerization vessel, regardless of whether the heat removal rate of the reflux condenser, or the recovery rate per unit time for the unreacted monomer are increased.