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公开(公告)号：US20060148910A1
公开(公告)日：2006-07-06
申请号：US11364595
申请日：2006-02-27
申请人： Yong Wang , David Vanderwiel , Anna Tonkovich , Yufei Gao , Eddie Baker
发明人： Yong Wang , David Vanderwiel , Anna Tonkovich , Yufei Gao , Eddie Baker
IPC分类号： C07C27/06
CPC分类号： C10G2/332 , B01J8/0285 , B01J12/007 , B01J19/0093 , B01J19/248 , B01J19/249 , B01J19/2495 , B01J23/8913 , B01J35/0006 , B01J35/04 , B01J35/10 , B01J35/1076 , B01J37/0217 , B01J37/0225 , B01J37/0238 , B01J37/0244 , B01J37/0248 , B01J2219/00783 , B01J2219/00822 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00984 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/32244 , B01J2219/32293 , B01J2219/32296 , B01J2219/32408 , B01J2219/32466 , B01J2219/32475 , C07C1/041 , C07C1/0425 , C07C1/0455 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C10G2/32 , C10G2/33 , C10G2/34 , C10G2/341
摘要： The present invention includes a catalyst structure and method of making the catalyst structure for Fischer-Tropsch synthesis that both rely upon the catalyst structure having a first porous structure with a first pore surface area and a first pore size of at least about 0.1 μm, preferably from about 10 μm to about 300 μm. A porous interfacial layer with a second pore surface area and a second pore size less than the first pore size is placed upon the first pore surface area. Finally, a Fischer-Tropsch catalyst selected from the group consisting of cobalt, ruthenium, iron and combinations thereof is placed upon the second pore surface area. Further improvement is achieved by using a microchannel reactor wherein the reaction chamber walls define a microchannel with the catalyst structure placed therein through which pass reactants. The walls may separate the reaction chamber from at least one cooling chamber. The present invention also includes a method of Fischer-Tropsch synthesis.
摘要翻译： 本发明包括一种制备费 - 托合成催化剂结构的催化剂结构和方法，它们均依赖于具有第一孔表面积和至少约0.1μm的第一孔径的第一多孔结构的催化剂结构，优选 从约10毫米到约300毫米。 具有第二孔表面积和小于第一孔径的第二孔径的多孔界面层被放置在第一孔表面积上。 最后，将选自钴，钌，铁及其组合的费 - 托催化剂置于第二孔表面积上。 通过使用微通道反应器来实现进一步的改进，其中反应室壁限定了具有催化剂结构置于其中的微通道，通过反应物。 壁可以将反应室与至少一个冷却室分开。 本发明还包括费 - 托合成方法。
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公开(公告)号：US20060073967A1
公开(公告)日：2006-04-06
申请号：US11231708
申请日：2005-09-20
申请人： Yong Wang , David Vanderwiel , Anna Lee Tonkovich , Yufei Gao , Eddie Baker
发明人： Yong Wang , David Vanderwiel , Anna Lee Tonkovich , Yufei Gao , Eddie Baker
CPC分类号： B01J23/8913 , B01J8/0285 , B01J12/007 , B01J19/248 , B01J23/462 , B01J23/75 , B01J35/0006 , B01J35/002 , B01J35/04 , B01J35/10 , B01J35/1009 , B01J37/0221 , B01J37/0238 , B01J37/0244 , B01J2219/32293 , B01J2219/32296 , B01J2219/32408 , B01J2219/32466 , B01J2219/32475 , C07C1/041 , C07C1/0425 , C07C1/0455 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C10G2/33 , C10G2/332
摘要： The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.
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公开(公告)号：US20060067861A1
公开(公告)日：2006-03-30
申请号：US11282423
申请日：2005-11-18
申请人： Anna Tonkovich , Yong Wang , Sean Fitzgerald , Jennifer Marco , Gary Roberts , David Vanderwiel , Robert Wegeng
发明人： Anna Tonkovich , Yong Wang , Sean Fitzgerald , Jennifer Marco , Gary Roberts , David Vanderwiel , Robert Wegeng
CPC分类号： C01B3/384 , B01J12/007 , B01J19/0093 , B01J23/58 , B01J23/60 , B01J35/04 , B01J37/0215 , B01J37/031 , B01J2219/00159 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00844 , B01J2219/00873 , B01J2219/00907 , B01J2219/00984 , B01J2219/2453 , B01J2219/2465 , B01J2219/2474 , B01J2219/2475 , B01J2219/2479 , B01J2219/2482 , B01J2219/2497 , C01B3/38 , C01B3/501 , C01B13/0251 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/041 , C01B2203/044 , C01B2203/047 , C01B2203/065 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0833 , C01B2203/0838 , C01B2203/1005 , C01B2203/1011 , C01B2203/1029 , C01B2203/1035 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1217 , C01B2203/1223 , C01B2203/1241 , C01B2203/1258 , C01B2203/1276 , C01B2203/1288 , C01B2203/148 , C01B2203/1604 , C01B2203/1619 , C01B2203/1652 , C01B2203/1676 , C01B2210/0046 , H01M8/0612 , Y02P20/128 , Y02P20/52
摘要： The present invention is a chemical reactor and method for catalytic chemical reactions having gas phase reactants. The chemical reactor has reactor microchannels for flow of at least one reactant and at least one product, and a catalyst material wherein the at least one reactant contacts the catalyst material and reacts to form the at least one product. The improvement, according to the present invention is: the catalyst material is on a porous material having a porosity that resists bulk flow therethrough and permits molecular diffusion therein. The porous material further has a length, a width and a thickness, the porous material defining at least a portion of one wall of a bulk flow path through which the at least one reactant passes.
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4.发明申请INTEGRATED REACTORS, METHODS OF MAKING SAME, AND METHODS OF CONDUCTING SIMULTANEOUS EXOTHERMIC AND ENDOTHERMIC REACTIONS 有权一体化反应器，其制备方法以及导致同时发生和内毒素反应的方法公开(公告)号：US20110236279A1
公开(公告)日：2011-09-29
申请号：US12891800
申请日：2010-09-27
申请人： Robert S. Wegeng , Yong Wang , David Vanderwiel , Jennifer L. Marco , Anna Lee Tonkovich , Gary Roberts , Steven T. Perry , Sean P. Fitzgerald
发明人： Robert S. Wegeng , Yong Wang , David Vanderwiel , Jennifer L. Marco , Anna Lee Tonkovich , Gary Roberts , Steven T. Perry , Sean P. Fitzgerald
CPC分类号： B01J8/0285 , B01J12/007 , B01J19/0093 , B01J19/249 , B01J2208/00309 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00833 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00891 , B01J2219/2453 , B01J2219/2458 , B01J2219/2459 , B01J2219/2465 , B01J2219/247 , B01J2219/2471 , B01J2219/2474 , B01J2219/2475 , B01J2219/2479 , B01J2219/2482 , B01J2219/2497 , B01J2219/2498 , C01B3/38 , C01B3/384 , C01B3/501 , C01B13/0251 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/041 , C01B2203/0495 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0833 , C01B2203/0844 , C01B2203/0883 , C01B2203/1005 , C01B2203/1029 , C01B2203/1035 , C01B2203/1041 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1205 , C01B2203/1241 , C01B2203/1276 , C01B2203/1288 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/1604 , C01B2203/1619 , C01B2203/1633 , C01B2203/1652 , C01B2203/1676 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , F23C13/00 , F23N1/007 , H01M8/0631 , Y02E60/324 , Y02P20/128 , Y02P20/52 , Y02P70/56 , Y10T29/49826
摘要： Integrated Combustion Reactors (ICRs) and methods of making ICRs are described in which combustion chambers (or channels) are in direct thermal contact to reaction chambers for an endothermic reaction. Superior results were achieved for combustion chambers which contained a gap for free flow through the chamber. Particular reactor designs are also described. Processes of conducting reactions in integrated combustion reactors are described and results presented. Some of these processes are characterized by unexpected and superior results.
摘要翻译： 描述了集成燃烧反应器（ICR）和制造ICR的方法，其中燃烧室（或通道）与用于吸热反应的反应室直接热接触。 对于具有通过室的自由流动的间隙的燃烧室实现了优异的结果。 还描述了特定的反应器设计。 介绍了综合燃烧反应器中进行反应的过程，并提出了结果。 其中一些过程的特征是意想不到的和优异的结果。
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5.发明授权Integrated reactors, methods of making same, and methods of conducting simultaneous exothermic and endothermic reactions 有权集成反应器，制备方法以及进行同时放热和吸热反应的方法公开(公告)号：US07803325B2
公开(公告)日：2010-09-28
申请号：US11232485
申请日：2005-09-21
申请人： Anna Lee Tonkovich , Gary Roberts , Steven T. Perry , Sean P. Fitzgerald , Robert S. Wegeng , Yong Wang , David Vanderwiel , Jennifer L. Marco
发明人： Anna Lee Tonkovich , Gary Roberts , Steven T. Perry , Sean P. Fitzgerald , Robert S. Wegeng , Yong Wang , David Vanderwiel , Jennifer L. Marco
CPC分类号： B01J8/0285 , B01J12/007 , B01J19/0093 , B01J19/249 , B01J2208/00309 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00833 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00891 , B01J2219/2453 , B01J2219/2458 , B01J2219/2459 , B01J2219/2465 , B01J2219/247 , B01J2219/2471 , B01J2219/2474 , B01J2219/2475 , B01J2219/2479 , B01J2219/2482 , B01J2219/2497 , B01J2219/2498 , C01B3/38 , C01B3/384 , C01B3/501 , C01B13/0251 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/041 , C01B2203/0495 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0833 , C01B2203/0844 , C01B2203/0883 , C01B2203/1005 , C01B2203/1029 , C01B2203/1035 , C01B2203/1041 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1205 , C01B2203/1241 , C01B2203/1276 , C01B2203/1288 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/1604 , C01B2203/1619 , C01B2203/1633 , C01B2203/1652 , C01B2203/1676 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , F23C13/00 , F23N1/007 , H01M8/0631 , Y02E60/324 , Y02P20/128 , Y02P20/52 , Y02P70/56 , Y10T29/49826
摘要： Integrated Combustion Reactors (ICRs) and methods of making ICRs are described in which combustion chambers (or channels) are in direct thermal contact to reaction chambers for an endothermic reaction. Superior results were achieved for combustion chambers which contained a gap for flee flow through the chamber. Particular reactor designs are also described. Processes of conducting reactions in integrated combustion reactors are described and results presented. Some of these processes are characterized by unexpected and superior results.
摘要翻译： 描述了集成燃烧反应器（ICR）和制造ICR的方法，其中燃烧室（或通道）与用于吸热反应的反应室直接热接触。 燃烧室获得了优异的效果，燃烧室含有通过室的流动空隙。 还描述了特定的反应器设计。 介绍了综合燃烧反应器中进行反应的过程，并提出了结果。 其中一些过程的特征是意想不到的和优异的结果。
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公开(公告)号：US08557186B2
公开(公告)日：2013-10-15
申请号：US12891800
申请日：2010-09-27
申请人： Anna Lee Tonkovich , Gary Roberts , Steven T. Perry , Sean P. Fitzgerald , Robert S. Wegeng , Yong Wang , David Vanderwiel , Jennifer L. Marco
发明人： Anna Lee Tonkovich , Gary Roberts , Steven T. Perry , Sean P. Fitzgerald , Robert S. Wegeng , Yong Wang , David Vanderwiel , Jennifer L. Marco
CPC分类号： B01J8/0285 , B01J12/007 , B01J19/0093 , B01J19/249 , B01J2208/00309 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00833 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00891 , B01J2219/2453 , B01J2219/2458 , B01J2219/2459 , B01J2219/2465 , B01J2219/247 , B01J2219/2471 , B01J2219/2474 , B01J2219/2475 , B01J2219/2479 , B01J2219/2482 , B01J2219/2497 , B01J2219/2498 , C01B3/38 , C01B3/384 , C01B3/501 , C01B13/0251 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/041 , C01B2203/0495 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0833 , C01B2203/0844 , C01B2203/0883 , C01B2203/1005 , C01B2203/1029 , C01B2203/1035 , C01B2203/1041 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1205 , C01B2203/1241 , C01B2203/1276 , C01B2203/1288 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/1604 , C01B2203/1619 , C01B2203/1633 , C01B2203/1652 , C01B2203/1676 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , F23C13/00 , F23N1/007 , H01M8/0631 , Y02E60/324 , Y02P20/128 , Y02P20/52 , Y02P70/56 , Y10T29/49826
摘要： Integrated Combustion Reactors (ICRs) and methods of making ICRs are described in which combustion chambers (or channels) are in direct thermal contact to reaction chambers for an endothermic reaction. Superior results were achieved for combustion chambers which contained a gap for free flow through the chamber. Particular reactor designs are also described. Processes of conducting reactions in integrated combustion reactors are described and results presented. Some of these processes are characterized by unexpected and superior results.
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