摘要:
The present invention provides a ferrite magnetic material capable of attaining such magnetic properties that Br+(⅓)HcJ is 6200 or more even by sintering at a temperature of 1150° C. or lower. The ferrite magnetic material includes as a main phase thereof a ferrite phase having a hexagonal structure, the main phase being represented by the following composition formula (1): LaxCamα1−x−m(Fe12−yCoy)z with α representing one or two of Ba and Sr; wherein the constituent ratios of the metal elements constituting the main phase satisfy the following conditions: x and m are the values in a region bounded by the points, A: (0.53, 0.27), B: (0.64, 0.27), C: (0.64, 0.35), D: (0.53, 0.45), E: (0.47, 0.45) and F: (0.47, 0.32) in the (x, m) coordinates shown in FIG. 2; 1.3≦x/yz≦1.8; and 9.5≦12z≦11.0.
摘要:
The present invention provides a ferrite magnetic material capable of attaining such magnetic properties that Br+(⅓)HcJ is 6200 or more even by sintering at a temperature of 1150° C. or lower. The ferrite magnetic material includes as a main phase thereof a ferrite phase having a hexagonal structure, the main phase being represented by the following composition formula (1): LaxCamα1−x−m(Fe12−yCoy)z with α representing one or two of Ba and Sr; wherein the constituent ratios of the metal elements constituting the main phase satisfy the following conditions: x and m are the values in a region bounded by the points, A: (0.53, 0.27), B: (0.64, 0.27), C: (0.64, 0.35), D: (0.53, 0.45), E: (0.47, 0.45) and F: (0.47, 0.32) in the (x, m) coordinates shown in FIG. 2; 1.3≦x/yz≦1.8; and 9.5≦12z≦11.0.
摘要翻译:本发明提供一种铁氧体磁性材料,即使在1150℃以下的温度下烧结也能够获得Br +(1/3)HcJ为6200以上的磁特性。 铁氧体磁性材料主要包括具有六方结构的铁素体相,其主相由以下组成式(1)表示:La x Si x Ca α1-x M(Fe 12-y Co y z)Z a,其中α代表一个或两个Ba和 锶 其中构成主相的金属元素的组成比满足以下条件:x和m是由点限定的区域中的值,A:(0.53,0.27),B:(0.64,0 .27),C:( 0.64,0.35),D:(0.53,0.45),E:(0.47,0.45)和F:(0.47,0.32)。 2; 1.3 <= x / yz <= 1.8; 和9.5 <= 12z <= 11.0。
摘要:
A core/shell structured powder different in composition between the inside the particle and the surface thereof before sintering, so that it is possible to sinter the powder at lower temperature and give a core/shell structured powder having a shell portion uniform in thickness after sintering; a multilayered ceramic capacitor having a longer lifetime, by preparing the multilayered ceramic capacitor by using a powder having a core/shell structure different in composition between the inside the particle and the surface thereof before sintering; and a method of producing a powder by synthesizing particles in the liquid containing a raw material, wherein particles different in composition at least between the inside the particle and the surface thereof are obtained by adding a composition to be incorporated as a component of the particles to the liquid during the synthetic process so that the composition of the liquid changes continuously or intermittently.
摘要:
A multilayer ceramic capacitor 1 having dielectric layers 2 having barium titanate or barium calcium titanate as a main ingredient. When the dielectric layers are barium titanate, the ratio of the grains having a thickness of the crystal grain boundaries 22 present between adjoining dielectric grains 20 is 30% to 95% of the plurality of dielectric grains 20 forming the dielectric layers 2. When the dielectric layers 2 are barium calcium titanate, the ratio of the grains having a thickness of the crystal grain boundaries 22 present between adjoining dielectric grains 20 is 20% to 70% of the plurality of dielectric grains 20 forming the dielectric layers 2.
摘要:
An object of the present invention is to make a core/shell structured powder different in composition between the inside the particle and the surface thereof before sintering, so that it is possible to sinter the powder at lower temperature and give a core/shell structured powder having a shell portion uniform in thickness after sintering. Another object of the present invention is to provide a multilayered ceramic capacitor having a longer lifetime, by preparing the multilayered ceramic capacitor by using a powder having a core/shell structure different in composition between the inside the particle and the surface thereof before sintering. The method of producing a powder according to the invention is a method of producing a powder by synthesizing particles in the liquid containing a raw material, wherein particles different in composition at least between the inside the particle and the surface thereof are obtained by adding a composition to be incorporated as a component of the particles to the liquid during the synthetic process so that the composition of the liquid changes continuously or intermittently.
摘要:
A multilayer ceramic capacitor 1 having dielectric layers 2 having barium titanate or barium calcium titanate as a main ingredient. When the dielectric layers are barium titanate, the ratio of the grains having a thickness of the crystal grain boundaries 22 present between adjoining dielectric grains 20 is 30% to 95% of the plurality of dielectric grains 20 forming the dielectric layers 2. When the dielectric layers 2 are barium calcium titanate, the ratio of the grains having a thickness of the crystal grain boundaries 22 present between adjoining dielectric grains 20 is 20% to 70% of the plurality of dielectric grains 20 forming the dielectric layers 2.
摘要:
A sintered body comprising a main phase consisting of an R2T14B phase (wherein R represents one or more rare earth elements (providing that the rare earth elements include Y), and T represents one or more transition metal elements essentially containing Fe, or Fe and Co), and a grain boundary phase containing a higher amount of R than the main phase, wherein a platy or acicular product exists. This sintered body enables to inhibit the grain growth, while keeping a decrease in magnetic properties to a minimum, and to improve a suitable sintering temperature range.
摘要翻译:一种烧结体,其包含由R 2 2 T 14 B相构成的主相(其中R表示一种或多种稀土元素(使得稀土元素包括Y) ,T表示一种或多种基本上含有Fe或Fe和Co的过渡金属元素,以及含有比主相高的R的晶界相,其中存在片状或针状产物。 该烧结体能够抑制晶粒生长,同时将磁特性降低至最小,并提高合适的烧结温度范围。
摘要:
A magnetic body which can reversibly change its magnetic force with a small external magnetic field while having a high residual magnetic flux density is provided. The magnetic body of the present invention has a residual magnetic flux density Br of at least 11 kG and a coercive force HcJ of 5 kOe or less, while an external magnetic field required for the residual magnetic flux density Br to become 0 is 1.10 HcJ or less.
摘要:
A method of producing fine and uniform barium titanate particles having high crystallinity by performing a heat treatment on titanium dioxide and barium carbonate having a specific surface area of at least 20 m2/g and low rutile ratio; comprising the steps of preparing mixed powder by mixing titanium dioxide particles having a rutile ratio of 30% or lower and a specific surface area of 20 m2/g or more and barium carbonate particles, a first heat treatment step for performing a heat treatment on the mixed powder to generate a barium titanate phase having an average thickness of at least 3 nm continuously on surfaces of titanium dioxide particles by an amount of 15 wt % or more, and a second heat treatment step for performing a heat treatment at 800° C. to 1000° C.
摘要:
An active material with a sufficient cycle characteristic and a process for its production are provided. According to the process for production of an active material of this invention, an aqueous solution containing a metal fluorocomplex is contacted with a metal oxide to form a surface-modified layer on the surface of the metal oxide. The active material of the invention comprises a core section made of a metal oxide and a surface-modified layer covering the core section, wherein the surface-modified layer is an oxide containing a metal present in the core section and a metal not present in the core section.