摘要:
There is provided a novel method for producing an optically active succinimide compound which is a useful compound utilized as an intermediate raw material for pharmaceutical products or the like. The method for producing an optically active succinimide compound of formula (2) comprises processing a racemic compound of a succinimide compound of formula (1) in the presence of a hydrolase to selectively hydrolyze one of the enantiomers, and subjecting to a post-treatment.
摘要:
There is provided a novel method for producing an optically active succinimide compound which is a useful compound utilized as an intermediate raw material for pharmaceutical products or the like. The method for producing an optically active succinimide compound of formula (2) comprises processing a racemic compound of a succinimide compound of formula (1) in the presence of a hydrolase to selectively hydrolyze one of the enantiomers, and subjecting to a post-treatment.
摘要:
In one example embodiment, a core-shell type platinum-containing catalyst is allowed to reduce the amount of used platinum and has high catalytic activity and stability. In one example embodiment, the core-shell type platinum-containing catalyst includes a core particle (with an average particle diameter R1) made of a non-platinum element and a platinum shell layer (with an average thickness ts) satisfying 1.4 nm≦R1≦3.5 nm and 0.25 nm≦ts≦0.9 nm. The core particle includes an element satisfying Eout≧3.0 eV, where average binding energy relative to the Fermi level of 5d orbital electrons of platinum present on an outermost surface of the shell layer is Eout. In a fuel cell including a platinum-containing catalyst which contains a Ru particle as a core particle, the output density at a current density of 300 mA/cm2 is 70 mW/cm2 or over, and an output retention ratio is approximately 90% or over.
摘要:
A core-shell type platinum-containing catalyst being allowed to reduce the amount of used platinum and having high catalytic activity and stability and a method of producing the same, an electrode and an electrochemical device are provided. The platinum-containing catalyst includes: metal particles each including a core particle including a metal atom except for platinum or an alloy of a metal atom except for platinum and a shell layer, including platinum on a surface of the core particle, the metal particles being supported by a conductive carrier and satisfying 0.25 nm≦ts≦0.9 nm and 1.4 nm≦R1≦3.5 nm, where an average thickness of the shell layer is ts and an average particle diameter of the core particle is R1.
摘要:
A positive electrode active material includes: a secondary particle obtained upon aggregation of a primary particle that is a lithium complex oxide particle in which at least nickel (Ni) and cobalt (Co) are solid-solved as transition metals, wherein an average composition of the whole of the secondary particle is represented by the following formula (1): LixCoyNizM1-y-zOb-aXa Formula (1) wherein an existent amount of cobalt (Co) becomes large from a center of the primary particle toward the surface thereof; and an existent amount of cobalt (Co) in the primary particle existing in the vicinity of the surface of the secondary particle is larger than an existent amount of cobalt (Co) in the primary particle existing in the vicinity of the center of the secondary particle.
摘要:
A positive electrode active material includes: a secondary particle obtained upon aggregation of a primary particle that is a lithium complex oxide particle in which at least nickel (Ni) and cobalt (Co) are solid-solved as transition metals, wherein an average composition of the whole of the secondary particle is represented by the following formula (1): LixCoyNizM1-y-zOb-aXa Formula (1) wherein an existent amount of cobalt (Co) becomes large from a center of the primary particle toward the surface thereof; and an existent amount of cobalt (Co) in the primary particle existing in the vicinity of the surface of the secondary particle is larger than an existent amount of cobalt (Co) in the primary particle existing in the vicinity of the center of the secondary particle.
摘要:
Provided is a magnetic reproducing method that enables a thin-film magnetic head including a head element for reading data signals which has a noise in its output due to a low temperature to bring out an excellent read characteristic in which the noise is suppressed even under the use environment with the low temperature. The magnetic reproducing method comprises the steps of: heating a head element for reading data signals which has a noise in its output due to a low temperature; and performing a read operation by using the head element for reading data signals under condition that the head element is increased in temperature.
摘要:
A battery with a high capacity and superior cycle characteristics and an anode active material used for it are provided. An anode contains an anode active material capable of reacting with lithium. The anode active material contains tin, cobalt, and carbon, and further contains at least one from the group consisting of indium, niobium, germanium, titanium, molybdenum, aluminum, phosphorus, and bismuth. Further, in the anode active material, the carbon content is from 9.9 wt % to 29.7 wt %, and the ratio of cobalt to the total of tin and cobalt is from 30 wt % to 70 wt %. Further, coordination number of cobalt as a first neighboring atom around tin obtained by the radial structure function calculated based on one scattering theory of X-ray absorption spectroscopy is 4 or less.
摘要:
A platinum-containing catalyst that is able to optimize state density of platinum 5d vacant orbital and is able to improve catalyst activity and a fuel cell using the same are provided. In the platinum-containing catalyst, when ratio of a peak intensity of a PtLIII absorption edge of a normalized X-ray absorption spectrum of the platinum-containing catalyst with respect to a peak intensity of a PtLIII absorption edge of a normalized X-ray absorption spectrum of a platinum simple substance metal foil having a thickness of 10 μm is Y, the number of holes of a platinum 5d vacant orbital in the platinum simple substance metal foil is 0.3, the number of holes of a platinum 5d vacant orbital in the platinum-containing catalyst is N, and molar ratio of total of metal elements other than platinum to the platinum in the platinum-containing catalyst is X, Y=0.144X+1.060 is established in the range of 0.1≦X≦1, and N=0.030X+0.333 is established in the range of 0.1≦X≦1.
摘要:
A head support mechanism includes a suspension for supporting a magnetic head slider with a thin-film magnetic head, having a slider mounting section on which the magnetic head slider is fixed, and a heating unit formed on the slider mounting section of the suspension. The heating unit is capable of producing heat.