摘要:
In an internal combustion engine, inside of an engine exhaust passage, an NOx adsorption part and an NOx purification part are arranged. The NOx purification part has the property of reducing NOx which is contained in exhaust gas if the concentration of hydrocarbons is made to vibrate by within a predetermined range of amplitude and within a predetermined range of period. When NOx is to be desorbed from the NOx adsorption part, the current NOx which is contained in the exhaust gas and the NOx which is desorbed from the NOx adsorption part are reduced by making the concentration of hydrocarbons of the NOx purification part vibrate by the amplitude and period which are set for the current engine operating state, at least of which (ΔT·k) has been corrected so that the amount of hydrocarbons becomes greater.
摘要:
In an internal combustion engine, inside of an engine exhaust passage, a hydrocarbon feed valve (15) and an exhaust treatment catalyst (13) are arranged. On a substrate (45) of the exhaust treatment catalyst (13), a coat layer comprised of at least two layers of a top coat layer (46) and a bottom coat layer (47) is formed. The top coat layer (46) is comprised of an exhaust purification catalyst for reacting NOx contained in exhaust gas and reformed hydrocarbons, while the bottom coat layer (47) is comprised of an NOx absorption catalyst. The concentration of hydrocarbons which flows into the exhaust treatment catalyst (13) is made to vibrate within a predetermined range of amplitude and within a predetermined range of period. Due to this, NOx contained in exhaust gas and NOx desorbed from the NOx absorption catalyst (47) are reduced in the exhaust purification catalyst (46).
摘要:
In an internal combustion engine, inside of an engine exhaust passage, a hydrocarbon feed valve (15) and an exhaust treatment catalyst (13) are arranged. On a substrate (45) of the exhaust treatment catalyst (13), a coat layer comprised of at least two layers of a top coat layer (46) and a bottom coat layer (47) is formed. The top coat layer (46) is comprised of an exhaust purification catalyst for reacting NOx contained in exhaust gas and reformed hydrocarbons, while the bottom coat layer (47) is comprised of an NOx absorption catalyst. The concentration of hydrocarbons which flows into the exhaust treatment catalyst (13) is made to vibrate within a predetermined range of amplitude and within a predetermined range of period. Due to this, NOx contained in exhaust gas and NOx desorbed from the NOx absorption catalyst (47) are reduced in the exhaust purification catalyst (46).
摘要:
In an internal combustion engine, inside of an engine exhaust passage, an NOx adsorption part and an NOx purification part are arranged. The NOx purification part has the property of reducing NOx which is contained in exhaust gas if the concentration of hydrocarbons is made to vibrate by within a predetermined range of amplitude and within a predetermined range of period. When NOx is to be desorbed from the NOx adsorption part, the current NOx which is contained in the exhaust gas and the NOx which is desorbed from the NOx adsorption part are reduced by making the concentration of hydrocarbons of the NOx purification part vibrate by the amplitude and period which are set for the current engine operating state, at least of which (ΔT·k) has been corrected so that the amount of hydrocarbons becomes greater.
摘要:
A temperature sensor includes temperature detecting means and at least one of a catalyst and an adsorbent applied to the surface of the temperature detecting means. At least one of the catalyst and the adsorbent catalyzes an exothermic reaction of a reactant in gas on the temperature detecting means. A temperature that is increased by the exothermic reaction is detected by the temperature detecting means. The catalytic efficiency for the exothermic reaction of at least one of the catalyst and the adsorbent is reduced by sulfur poisoning. The temperature sensor is disposed upstream of an exhaust purification system. Accordingly, it is determined that the temperature sensor is subjected to sulfur poisoning if the temperature detected by the temperature sensor is below a prescribed temperature.
摘要:
An internal combustion engine in which an SOx trap catalyst (13) for trapping SOx contained in the exhaust gas contains an oxygen adsorbing and releasing material (54) which can adsorb SO2 contained in the exhaust gas and an SOx storage material (55) which can store SOx in the form of sulfates. The SO2 which is contained in the exhaust gas is chemically adsorbed at the oxygen adsorbing and releasing material (54) without being oxidized. If the temperature of the SOx trap catalyst (13) becomes higher than the start temperature of adsorbed SO2 movement, the SO2 which is chemically adsorbed at the oxygen adsorbing and releasing material (54) is oxidized and stored in the form of sulfates in the SOx storage material (55).
摘要:
The present detector for detecting sulfur components includes a storage portion for storing SOx and NOx in the exhaust gas passing through an exhaust passage, in which the more an amount of stored SOx increases, the more an amount of stored NOx decreases, and which does not release SOx but release NOx at a set temperature, and a temperature sensor, estimates the amount of stored SOx on the basis of a relationship between, after the storage portion becomes the set temperature by heating, a heating pattern of the storage portion and temperature change of the storage portion measured by the temperature sensor, and detects an integrated amount of SOx passing through the exhaust passage during a given period or an value on the basis of the integrated amount.
摘要:
An internal combustion engine in which an SOx trap catalyst for trapping SOx contained in the exhaust gas is comprised of an upstream side catalyst and a downstream side catalyst into which the exhaust gas flowing out from the upstream side catalyst flows. The SOx storing material of the upstream side catalyst is mainly comprised of an alkali earth metal, while the SOx storing material of the downstream side catalyst is mainly comprised of an alkali metal.
摘要:
An exhaust purification system of an internal combustion engine has a selective reduction type NOX catalyst device which can hold ammonia and a storage reduction type NOX catalyst device which is arranged at an upstream side of the selective reduction type NOX catalyst device, which makes an air-fuel ratio of exhaust gas which flows into the storage reduction type NOX catalyst device change from a lean air-fuel ratio to a rich air-fuel ratio for starting an ammonia generation period, and which makes an air-fuel ratio of exhaust gas which flows into the storage reduction type NOX catalyst device change from a rich air-fuel ratio to a lean air-fuel ratio for ending the ammonia generation period.
摘要:
A temperature sensor includes temperature detecting means and at least one of a catalyst and an adsorbent applied to the surface of the temperature detecting means. At least one of the catalyst and the adsorbent catalyzes an exothermic reaction of a reactant in gas on the temperature detecting means. A temperature that is increased by the exothermic reaction is detected by the temperature detecting means. The catalytic efficiency for the exothermic reaction of at least one of the catalyst and the adsorbent is reduced by sulfur poisoning. The temperature sensor is disposed upstream of an exhaust purification system. Accordingly, it is determined that the temperature sensor is subjected to sulfur poisoning if the temperature detected by the temperature sensor is below a prescribed temperature.