公开(公告)号：US20070237691A1

公开(公告)日：2007-10-11

申请号：US11631536

申请日：2005-07-07

申请人： Yoshinori Takata ,  Masanori Miyake ,  Toshihiko Sumida

发明人： Yoshinori Takata ,  Masanori Miyake ,  Toshihiko Sumida

IPC分类号： C01B3/38 ,  B01D53/04 ,  C01B3/56

CPC分类号： C01B3/56 ,  B01D53/0446 ,  B01D53/047 ,  B01D2253/102 ,  B01D2253/104 ,  B01D2253/108 ,  B01D2256/16 ,  B01D2257/102 ,  B01D2257/502 ,  B01D2257/504 ,  B01D2257/704 ,  B01D2259/40001 ,  B01D2259/65 ,  B01J8/0285 ,  B01J8/0411 ,  B01J8/0484 ,  B01J8/0492 ,  B01J8/0496 ,  B01J8/067 ,  B01J2208/00203 ,  B01J2208/00504 ,  B01J2208/00522 ,  B01J2208/0053 ,  C01B3/323 ,  C01B2203/0244 ,  C01B2203/043 ,  C01B2203/0465 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/048 ,  C01B2203/1223 ,  C01B2203/1288 ,  Y02C10/08 ,  Y02P20/152

摘要： A hydrogen production system (X1) according to the present invention includes a reforming apparatus (Y1) having a vaporizer (1) and a reforming reactor (2), and a PSA apparatus (5). In the vaporizer (1) a mixed material (hydrocarbon-based material, water, and oxygen) is heated and vaporized. In the reforming reactor (2), steam reforming reaction and partial oxidation reaction of the hydrocarbon-based material take place at a time, so that reformed gas (containing hydrogen) is led out from the vaporized mixed material. In the PSA apparatus (5), the reformed gas is introduced into an adsorption tower loaded with an adsorbing agent, so that an unnecessary component in the gas is adsorbed by the adsorbing agent and hence hydrogen-rich gas is led out of the tower, while the unnecessary component is desorbed from the adsorbing agent, so that hydrogen-containing desorbed gas that contains the unnecessary component and hydrogen remaining in the tower is discharged out of the tower. The desorbed gas is burnt in the vaporizer (1), and combustion gas generated by burning the desorbed gas is utilized as a heat source to heat the mixed material.

摘要翻译： 根据本发明的氢生产系统（X 1）包括具有蒸发器（1）和重整反应器（2）的重整装置（Y 1）和PSA装置（5）。 在蒸发器（1）中，混合材料（烃基材料，水和氧）被加热和蒸发。 在重整反应器（2）中，烃类材料一次进行蒸汽重整反应和部分氧化反应，从汽化的混合材料引出重整气体（含氢气）。 在PSA装置（5）中，将重整气体引入装载有吸附剂的吸附塔，使吸附剂吸附气体中的不必要成分，将富氢气体从塔内引出， 同时不必要的成分从吸附剂中解吸，使得含有残留在塔中的不必要成分和氢的含氢脱附气体排出塔内。 解吸气体在蒸发器（1）中燃烧，并且通过燃烧解吸气体产生的燃烧气体用作加热混合材料的热源。

公开(公告)号：US08048177B2

公开(公告)日：2011-11-01

申请号：US12300366

申请日：2007-05-07

申请人： Toshihiko Sumida ,  Yoshinori Takata ,  Masanori Miyake ,  Yoshiaki Imoto

发明人： Toshihiko Sumida ,  Yoshinori Takata ,  Masanori Miyake ,  Yoshiaki Imoto

IPC分类号： B01J7/00 ,  C01B3/36 ,  C01B6/24 ,  C01B3/02 ,  C10J3/46 ,  C02F1/72 ,  C02F1/68

CPC分类号： C01B3/323 ,  B01J8/025 ,  B01J2208/00203 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2208/00716 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/043 ,  C01B2203/0495 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0883 ,  C01B2203/1076 ,  C01B2203/1223 ,  C01B2203/1288 ,  C01B2203/1604 ,  H01M8/0631 ,  H01M8/0662 ,  Y02P20/128 ,  Y02P20/52

摘要： A method for treating drain in hydrogen production includes steps of gasifying in a gasifier (1), reforming in a reformer (2), gas-liquid separation in a gas-liquid separator (4), PSA gas separation in a PSA separator (5) and evaporation in a drain treatment unit (6). In the gasifying, a mixed material containing methanol is heated and gasified. In the reforming, reformed gas containing hydrogen is produced from the mixed material by reforming reaction of methanol. In the gas-liquid separation, a liquid component is separated from the reformed gas and discharged as drain. In the PSA gas separation, hydrogen-rich gas and offgas are extracted from the reformed gas by PSA separation using an adsorption tower. In the gasifying, the offgas is burned, and the mixed material is heated by using the combustion gas as heat source. In the evaporation, drain is evaporated using the combustion gas after heating the mixed material as heat source.

摘要翻译： 用于处理氢气生产中的排水的方法包括在气化器（1）中气化，重整器（2）中的重整，气 - 液分离器（4）中的气液分离，PSA分离器（5）中的PSA气体分离 ）并在排水处理单元（6）中蒸发。 在气化中，将含有甲醇的混合物质加热并气化。 在重整中，通过甲醇的重整反应，由混合材料产生含氢气的重整气体。 在气液分离中，将液体成分从重整气体中分离出来，排出。 在PSA气体分离中，使用吸附塔通过PSA分离从重整气体中提取富氢气体和废气。 在气化中，废气被燃烧，并且通过使用燃烧气体作为热源来加热混合物。 在蒸发中，加热混合材料作为热源后，使用燃烧气体蒸发排出物。

公开(公告)号：US20090148381A1

公开(公告)日：2009-06-11

申请号：US12300366

申请日：2007-05-07

申请人： Toshihiko Sumida ,  Yoshinori Takata ,  Masanori Miyake ,  Yoshiaki Imoto

发明人： Toshihiko Sumida ,  Yoshinori Takata ,  Masanori Miyake ,  Yoshiaki Imoto

IPC分类号： C01B3/24 ,  C10J1/20

CPC分类号： C01B3/323 ,  B01J8/025 ,  B01J2208/00203 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2208/00716 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/043 ,  C01B2203/0495 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0883 ,  C01B2203/1076 ,  C01B2203/1223 ,  C01B2203/1288 ,  C01B2203/1604 ,  H01M8/0631 ,  H01M8/0662 ,  Y02P20/128 ,  Y02P20/52

摘要： A method for treating drain in hydrogen production includes steps of gasifying in a gasifier (1), reforming in a reformer (2), gas-liquid separation in a gas-liquid separator (4), PSA gas separation in a PSA separator (5) and evaporation in a drain treatment unit (6). In the gasifying, a mixed material containing methanol is heated and gasified. In the reforming, reformed gas containing hydrogen is produced from the mixed material by reforming reaction of methanol. In the gas-liquid separation, a liquid component is separated from the reformed gas and discharged as drain. In the PSA gas separation, hydrogen-rich gas and offgas are extracted from the reformed gas by PSA separation using an adsorption tower. In the gasifying, the offgas is burned, and the mixed material is heated by using the combustion gas as heat source. In the evaporation, drain is evaporated using the combustion gas after heating the mixed material as heat source.

摘要翻译： 用于处理氢气生产中的排水的方法包括在气化器（1）中气化，重整器（2）中的重整，气 - 液分离器（4）中的气液分离，PSA分离器（5）中的PSA气体分离 ）并在排水处理单元（6）中蒸发。 在气化中，将含有甲醇的混合物质加热并气化。 在重整中，通过甲醇的重整反应，由混合材料产生含氢气的重整气体。 在气液分离中，将液体成分从重整气体中分离出来，排出。 在PSA气体分离中，使用吸附塔通过PSA分离从重整气体中提取富氢气体和废气。 在气化中，废气被燃烧，并且通过使用燃烧气体作为热源来加热混合物。 在蒸发中，加热混合材料作为热源后，使用燃烧气体蒸发排出物。

公开(公告)号：US08690972B2

公开(公告)日：2014-04-08

申请号：US11631536

申请日：2005-07-07

申请人： Yoshinori Takata ,  Masanori Miyake ,  Toshihiko Sumida

发明人： Yoshinori Takata ,  Masanori Miyake ,  Toshihiko Sumida

IPC分类号： B01J7/00

CPC分类号： C01B3/56 ,  B01D53/0446 ,  B01D53/047 ,  B01D2253/102 ,  B01D2253/104 ,  B01D2253/108 ,  B01D2256/16 ,  B01D2257/102 ,  B01D2257/502 ,  B01D2257/504 ,  B01D2257/704 ,  B01D2259/40001 ,  B01D2259/65 ,  B01J8/0285 ,  B01J8/0411 ,  B01J8/0484 ,  B01J8/0492 ,  B01J8/0496 ,  B01J8/067 ,  B01J2208/00203 ,  B01J2208/00504 ,  B01J2208/00522 ,  B01J2208/0053 ,  C01B3/323 ,  C01B2203/0244 ,  C01B2203/043 ,  C01B2203/0465 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/048 ,  C01B2203/1223 ,  C01B2203/1288 ,  Y02C10/08 ,  Y02P20/152

摘要： A hydrogen production system (X1) according to the present invention includes a reforming apparatus (Y1) having a vaporizer (1) and a reforming reactor (2), and a PSA apparatus (5). In the vaporizer (1) a mixed material (hydrocarbon-based material, water, and oxygen) is heated and vaporized. In the reforming reactor (2), steam reforming reaction and partial oxidation reaction of the hydrocarbon-based material take place at a time, so that reformed gas (containing hydrogen) is led out from the vaporized mixed material. In the PSA apparatus (5), the reformed gas is introduced into an adsorption tower loaded with an adsorbing agent, so that an unnecessary component in the gas is adsorbed by the adsorbing agent and hence hydrogen-rich gas is led out of the tower, while the unnecessary component is desorbed from the adsorbing agent, so that hydrogen-containing desorbed gas that contains the unnecessary component and hydrogen remaining in the tower is discharged out of the tower. The desorbed gas is burnt in the vaporizer (1), and combustion gas generated by burning the desorbed gas is utilized as a heat source to heat the mixed material.

摘要翻译： 根据本发明的氢生产系统（X1）包括具有蒸发器（1）和重整反应器（2）的重整装置（Y1）和PSA装置（5）。 在蒸发器（1）中，混合材料（烃基材料，水和氧）被加热和蒸发。 在重整反应器（2）中，烃类材料一次进行蒸汽重整反应和部分氧化反应，从汽化的混合材料引出重整气体（含氢气）。 在PSA装置（5）中，将重整气体引入装载有吸附剂的吸附塔，使吸附剂吸附气体中的不必要成分，将富氢气体从塔内引出， 同时不必要的成分从吸附剂中解吸，使得含有残留在塔中的不必要成分和氢的含氢脱附气体排出塔内。 解吸气体在蒸发器（1）中燃烧，并且通过燃烧解吸气体产生的燃烧气体用作加热混合材料的热源。

公开(公告)号：US5254512A

公开(公告)日：1993-10-19

申请号：US796354

申请日：1991-11-22

申请人： Kanji Ueda ,  Yoshinori Takata ,  Tadaichi Shibahara ,  Yoshinori Yoshida

发明人： Kanji Ueda ,  Yoshinori Takata ,  Tadaichi Shibahara ,  Yoshinori Yoshida

IPC分类号： B01D53/86 ,  B01J38/04 ,  B01J38/12 ,  B01J38/14 ,  B01D53/36 ,  B01J20/34

CPC分类号： B01D53/864 ,  B01D53/8668

摘要： A method for continuously treating a gas using an apparatus with a catalyst bed housed therein comprises the steps of passing a subject gas through the catalyst bed to adsorb the adsorbable substances in the subject gas thereto; and passing a regenerating gas through the catalyst bed adsorbed by the adsorbable substances in the subject gas to react and decompose them and simultaneously regenerate the catalyst bed. A particular apparatus is used with this method.By carrying out this method of the present invention using the gas treating apparatus, it is possible to continuously, efficiently and economically advantageously treat a gas containing a malodorous component, harmful component, organic solvent, hydrocarbon vapor or the like.

公开(公告)号：US5100557A

公开(公告)日：1992-03-31

申请号：US443149

申请日：1989-11-30

申请人： Taro Nogami ,  Hironori Kaji ,  Kaoru Hagiya ,  Katsuo Tsukada ,  Yoshinori Takata

发明人： Taro Nogami ,  Hironori Kaji ,  Kaoru Hagiya ,  Katsuo Tsukada ,  Yoshinori Takata

IPC分类号： B01D15/08 ,  G01N30/24 ,  G01N30/44 ,  G01N30/82

CPC分类号： G01N30/44 ,  G01N30/82 ,  G01N30/24

摘要： A liquid chromatography system and a method of utilizing the same, comprising a plurality of separated-component vessels for collecting components eluted in a separation column, a flowing system conduit for component extraction through which the components separated in the separation column are individually delivered to the separated-component vessels. The system further comprises a flowing system conduit for sample introduction through which any of the separated components collected in the plurality of separated-component vessels is selectively drawn from its vessel and introduced to the upstream side of the separation column. The present invention allows a plurality of components in a sample of a mixture to be individual collected, and also allows any of the collected components to be re-separated selectively and automatically.

摘要翻译： 一种液相色谱系统及其应用方法，包括用于收集在分离塔中洗脱的组分的多个分离组分容器，用于组分萃取的流动系统管道，分离塔中分离的组分通过其分别输送到 分离容器。 该系统还包括用于样品引入的流动系统管道，通过该流动系统管道，收集在多个分离组分容器中的任何分离的组分从其容器中选择性地拉出并被引入分离塔的上游侧。 本发明允许混合物样品中的多个组分被单独收集，并且还允许任何收集的组分被选择性地和自动地重新分离。

公开(公告)号：US4576706A

公开(公告)日：1986-03-18

申请号：US647483

申请日：1984-09-05

申请人： Yoshinori Takata ,  Mamoru Taki

发明人： Yoshinori Takata ,  Mamoru Taki

IPC分类号： G01N27/28 ,  G01N27/42 ,  G01N30/64

CPC分类号： G01N27/42 ,  G01N27/28

摘要： A sample leaving a separation column of liquid chromatograph is led to an electrolytic cell to obtain an electrolytic current corresponding to the amount of an assayed sample component. The electrolytic cell is divided into two compartments by an ion exchange pipe penetrating therethrough at the center. One compartment is a cylindrical working electrode chamber in the pipe, and the other compartment is a cylindrical chamber for a counterelectrode outside the pipe. A working electrode comprising a bundle of electroconductive carbon fibers is provided in the working electrode chamber, and preferably a swellable rod is inserted as a core into the working electrode. In the chamber for the counterelectrode, a cylindrical counterelectrode made of carbon fibers is provided to surround the outside surface of the ion exchange pipe. The inner diameter of the ion exchange pipe is substantially equal to the inner diameter of a tube for introducing the sample. The sample undergoes electrolysis reaction while the sample passes through the carbon fibers of the working electrode.

摘要翻译： 将离开液相色谱仪的分离柱的样品导入电解槽，以获得与测定的样品组分的量相对应的电解电流。 电解槽被中心穿过的离子交换管分成两个隔室。 一个隔室是管道中的圆柱形工作电极室，另一个隔室是用于管外的反电极的圆柱形室。 在工作电极室中设置包括导电性碳纤维束的工作电极，优选将可膨胀的棒作为芯插入到工作电极中。 在反电极的室中，设置由碳纤维制成的圆柱形对电极以包围离子交换管的外表面。 离子交换管的内径基本上等于用于引入样品的管的内径。 样品经过电解反应，同时样品通过工作电极的碳纤维。

公开(公告)号：US5294336A

公开(公告)日：1994-03-15

申请号：US896784

申请日：1992-06-09

申请人： Masako Mizuno ,  Kenji Tochigi ,  Yutaka Misawa ,  Hiroyuki Miyagi ,  Yoshio Watanabe ,  Taro Nogami ,  Junkichi Miura ,  Yoshinori Takata

发明人： Masako Mizuno ,  Kenji Tochigi ,  Yutaka Misawa ,  Hiroyuki Miyagi ,  Yoshio Watanabe ,  Taro Nogami ,  Junkichi Miura ,  Yoshinori Takata

IPC分类号： G01N30/32 ,  B01D15/08 ,  B01J20/281 ,  G01N30/02 ,  G01N30/86 ,  G01N30/88 ,  G01N33/487 ,  G01N33/72

CPC分类号： G01N33/723 ,  B01D15/08 ,  G01N2030/027

摘要： Stable hemoglobin A.sub.lc (s-A.sub.lc) can be separated from other hemoglobin components and quantitated in a short time by means of a liquid-chromatographic apparatus comprising a separation column packed with a packing material consisting essentially of a porous substance having a carboxyalkyl group combined thereinto, as ion exchanger, a means for injecting a sample into the separation column, a means for passing one or more eluents through the separation column, and a means for detecting hemoglobin, hemoglobin derivatives or glycosylated hemoglobin, the average particle size of the packing material in dry state being 4 .mu.m or less.

摘要翻译： 稳定的血红蛋白Alc（s-Alc）可以与其他血红蛋白成分分离，并通过液相色谱装置在短时间内定量，该​​液相色谱装置包括一个分离柱，该分离柱填充有基本上由其中组合有羧基烷基的多孔物质组成的包装材料 作为离子交换剂，将样品注入分离塔的方法，使一个或多个洗脱液通过分离塔的装置和用于检测血红蛋白，血红蛋白衍生物或糖基化血红蛋白的装置，包装材料的平均粒径 在干燥状态下为4（my）m或更小。

公开(公告)号：US4452682A

公开(公告)日：1984-06-05

申请号：US200264

申请日：1980-10-24

申请人： Yoshinori Takata ,  Hiroyuki Miyagi ,  Kunio Hirota ,  Yasuhisa Shibata ,  Kazuo Nidaira ,  Fusao Shirato

发明人： Yoshinori Takata ,  Hiroyuki Miyagi ,  Kunio Hirota ,  Yasuhisa Shibata ,  Kazuo Nidaira ,  Fusao Shirato

IPC分类号： G01N27/403 ,  G01N27/416 ,  G01N27/46

CPC分类号： G01N33/4915 ,  G01N33/492

摘要： An apparatus for electrochemically measuring clinical emergency check items of blood for a short time by flowthrough system, using a small amount of whole blood as a blood sample, which comprises a blood pH/gas component sensor unit, an electrolyte component sensor unit, and/or a biochemical component sensor unit, arranged in series in this order, a sampler and these sensor units being communicated with one another through a blood sample flow passage or channel, each of the sensor units being provided with sensor electrodes and at least one reference electrode as electrochemical sensor means.Detected values from each of the sensor units are transmitted to a computer or calculator through a current amplifier and/or a differential amplifier for a differential voltage from the voltage of the reference electrode to compute pH, pressure, or concentrations from the detected values, and numerically displayed on a display device connected to the computer.

摘要翻译： 一种用于使用少量全血作为血液样品的流过系统电化学测量血液临时紧急检查项目的装置，其包括血液pH /气体成分传感器单元，电解质成分传感器单元和/ 或生物化学成分传感器单元，其依次排列成一个采样器，并且这些传感器单元通过血液样本流动通道或通道彼此连通，每个传感器单元设置有传感器电极和至少一个参考电极 作为电化学传感器装置。 来自每个传感器单元的检测值通过电流放大器和/或差分放大器传输到计算机或计算器，用于与参考电极的电压的差分电压，以从检测值计算pH，压力或浓度，以及 数字显示在连接到计算机的显示设备上。

公开(公告)号：US4266196A

公开(公告)日：1981-05-05

申请号：US25571

申请日：1979-03-30

申请人： Kazuyoshi Kawazoe ,  Yoshinori Takata ,  Mon Suzuki ,  Shizuo Uehara

发明人： Kazuyoshi Kawazoe ,  Yoshinori Takata ,  Mon Suzuki ,  Shizuo Uehara

IPC分类号： G01N27/64 ,  G01N27/66 ,  G01N30/64 ,  G01N27/62

CPC分类号： G01N30/64 ,  G01N27/66 ,  G01N2030/642

摘要： A gas detecting means of this invention is provided with a discharge section which radiates light by electric discharge, a detecting section which collects an ion current of a sample gas ionized by the light, and an optical path which connects the discharge and the detecting sections. The discharge is formed by a pointed cathode and an anode having a penetration hole. The tip of the pointed cathode is directed to the optical path. The diameter of the penetration hole of the anode is smaller than that of the optical path. The anode is disposed in such a manner that any peripheral part of an inlet of the penetration hole is at an equal distance from the tip of the cathode. Both the discharge section and the detecting section are shielded electrically by an outer shell of metal.

摘要翻译： 本发明的气体检测装置设置有通过放电辐射光的放电部分，收集由光离子化的样品气体的离子电流的检测部分和连接放电和检测部分的光路。 放电由具有穿透孔的尖锐阴极和阳极形成。 尖锐阴极的尖端被引导到光路。 阳极的穿透孔的直径小于光路的直径。 阳极以这样的方式设置，使得穿透孔的入口的任何外围部分处于与阴极的尖端相等的距离处。 放电部和检测部均由金属外壳电隔离。