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公开(公告)号：US06294291B1
公开(公告)日：2001-09-25
申请号：US07863043
申请日：1992-04-03
申请人： Yoshiyuki Ozaki , Nobuo Eda , Akiyoshi Morita
发明人： Yoshiyuki Ozaki , Nobuo Eda , Akiyoshi Morita
IPC分类号： H01M458
CPC分类号： H01M10/0525 , H01M4/131 , H01M4/133 , H01M4/505 , H01M4/525 , H01M4/587 , H01M10/0587
摘要： A secondary battery with non-aqueous electrolyte having a high voltage and energy density and a superior cycle property, characterized in that a cathode comprises composite oxides containing lithium and an anode comprises composite carbon materials containing graphite spherical particles and carbon fibers. The carbon fiber improves the stiffness of the anode depolarizing mix to prevent the body made thereof from swelling and decomposing.
摘要翻译： 具有高电压和能量密度以及优良循环性能的非水电解质的二次电池，其特征在于阴极包含含锂的复合氧化物和阳极，其包含含有石墨球形颗粒和碳纤维的复合碳材料。 碳纤维改善了阳极去极化混合物的刚度，以防止由其制成的身体膨胀和分解。
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公开(公告)号：US6106976A
公开(公告)日：2000-08-22
申请号：US863042
申请日：1992-04-03
申请人： Yoshiyuki Ozaki , Nobuo Eda , Akiyoshi Morita
发明人： Yoshiyuki Ozaki , Nobuo Eda , Akiyoshi Morita
IPC分类号： C01B31/02 , C01B31/04 , H01M4/131 , H01M4/133 , H01M4/36 , H01M4/485 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M4/58 , H01M4/587 , H01M10/05 , H01M10/0525 , H01M10/0566 , H01M10/0587 , H01M10/36 , H01M4/02
CPC分类号： H01M10/0525 , H01M4/587 , H01M10/0587 , H01M4/131 , H01M4/133 , H01M4/505 , H01M4/525
摘要： A secondary battery with non-aqueous electrolyte having a high voltage and capacity and an improved cycle property, characterized in that the battery has an anode which is comprised of graphite spherical particles provided with a lamellar structure and an optically anisotropic and single phase such as meso-carbon microbeads; and a cathode which is comprised of composite oxides containing lithium.
摘要翻译： 具有高电压和容量以及循环性能改善的非水电解质的二次电池，其特征在于，所述电池具有阳极，所述阳极由具有层状结构和光学各向异性和单相如石墨的石墨球形颗粒组成 碳微珠; 以及由含有锂的复合氧化物构成的阴极。
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3.发明授权Measuring method of the specific surface area available for reaction of noble metal catalyst in the electrode of polymer electrolyte membrane fuel cell 失效贵金属催化剂在聚合物电解质膜燃料电池电极中可用于反应的比表面积的测量方法
公开(公告)号：US5866423A
公开(公告)日：1999-02-02
申请号：US783577
申请日：1997-01-15
申请人： Yasushi Sugawara , Makoto Uchida , Yuko Fukuoka , Nobuo Eda
发明人： Yasushi Sugawara , Makoto Uchida , Yuko Fukuoka , Nobuo Eda
CPC分类号： H01M4/926 , H01M4/92 , H01M8/1004 , H01M2300/0082
摘要： A measuring method for determining the specific surface area available for reaction of a noble metal catalyst of an electrode for use in a polymer electrolyte membrane fuel cell. The method includes measuring the total specific surface area of the noble metal catalyst and the specific surface area of the noble metal catalyst mixed with a polymer electrolyte by detecting the adsorption amounts of carbon monoxide upon exposure to carbon monoxide after reduction in hydrogen, and subtracting the latter from the former. Also provided is an electrode material for use in a polymer electrolyte membrane fuel cell having excellent polarization characteristics by controlling the utilization of a noble metal catalyst determined from the total specific surface area and specific surface area available for reaction of the noble metal catalyst. The electrode material includes a noble metal catalyst powder and a polymer electrolyte, wherein the utilization ratio of the noble metal catalyst is at least 40% of the saturation value of the utilization of the noble metal catalyst powder.
摘要翻译： 一种用于确定用于聚合物电解质膜燃料电池的电极的贵金属催化剂可用于反应的比表面积的测量方法。 该方法包括通过检测在氢还原后暴露于一氧化碳时一氧化碳的吸附量，测量贵金属催化剂的总比表面积和与聚合物电解质混合的贵金属催化剂的比表面积，并减去 后者来自前者。 还提供了一种用于聚合物电解质膜燃料电池的电极材料，其通过控制由可用于贵金属催化剂的反应的总比表面积和比表面积确定的贵金属催化剂的利用而具有优异的极化特性。 电极材料包括贵金属催化剂粉末和聚合物电解质，其中贵金属催化剂的利用率为贵金属催化剂粉末的利用饱和值的至少40％。
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公开(公告)号：US5518834A
公开(公告)日：1996-05-21
申请号：US355600
申请日：1994-12-14
申请人： Hiroshi Yoshizawa , Isao Kubo , Shigeto Noya , Takafumi Fujiwara , Akira Miura , Nobuo Eda
发明人： Hiroshi Yoshizawa , Isao Kubo , Shigeto Noya , Takafumi Fujiwara , Akira Miura , Nobuo Eda
摘要： The sealing of the top and/or bottom of the cylindrical positive electrode of an air-cell is improved and leakage of the electrolyte from the jellied zinc negative electrode disposed within the positive electrode which is constituted of a collector layer, catalyst layer, and a porous layer is prevented. By utilizing a positive electrode constituted of a metallic collector layer made of a metal mesh or such, a catalyst layer disposed around said collector, and a fluororesin porous layer as an air diffusion layer, an outer cup and an inner cup are pressed on the top of the positive electrode in order to prevent the leakage of the electrolyte. The possible leakage of electrolyte from the bottom of the positive electrode can be prevented by providing a resin sealing body with a ring shaped indentation fitted to the bottom of a positive electrode, and by inserting this resin sealing body into the positive electrode cannister, and by pressing the side wall of the positive electrode cannister against the side of the resin sealing body, in order to fit the bottom of the positive electrode to the indentation of the resin sealing body.
摘要翻译： 空气电池的圆筒形正极的顶部和/或底部的密封被改善，并且电解质从布置在正极内的凝胶状锌负电极泄漏，该正极由集电极层，催化剂层和 防止多孔层。 通过利用由金属网等构成的金属集电体构成的正极，设置在集电体周围的催化剂层和作为空气扩散层的氟树脂多孔层，将外杯和内杯按压在顶部 的正极，以防止电解液的泄漏。 可以通过设置安装在正极底部的环形压痕的树脂密封体，并将该树脂密封体插入正极罐中，并通过 将正极罐的侧壁压在树脂密封体的侧面，以便将正极的底部装配到树脂密封体的凹部。
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公开(公告)号：US5723173A
公开(公告)日：1998-03-03
申请号：US590118
申请日：1996-01-23
申请人： Yuko Fukuoka , Makoto Uchida , Nobuo Eda
发明人： Yuko Fukuoka , Makoto Uchida , Nobuo Eda
CPC分类号： H01M4/926 , H01M8/1004 , H01M2300/0082 , Y02P70/56 , Y10T29/49115
摘要： The invention provides a method for manufacturing a solid polymer electrolyte electrolyte fuel cell which exhibits higher performances by sufficiently and uniformly contacting the solid polymer electrolyte with a catalyst to increase the reaction area inside the electrode. The method comprises the steps of dispersing a carbon powder supporting a noble metal catalyst in an organic solvent to obtain a dispersion, mixing the resulting dispersion with an alcoholic solution of a solid polymer electrolyte to produce a colloid of the solid polymer electrolyte and simultaneously to obtain a mixed solution in which said colloid is adsorbed to the carbon powder, applying the mixed solution on one side of a gas-diffusion layer to produce an electrode, and pressing the resulting electrode on at least one side of a solid polymer electrolyte membrane to integrate them. Furthermore, a fluorocarbon polymer can be added, to thereby form a gas channel without excessive covering of the catalyst and increase gas permeability of the electrode. Thus, a solid polymer electrolyte fuel cell which exhibits high performances in a high current density area can be further provided.
摘要翻译： 本发明提供一种固体高分子电解质型燃料电池的制造方法，其特征在于，通过使固体高分子电解质与催化剂充分均匀地接触，能够提高电极内部的反应面积，显示出更高的性能。 该方法包括将负载贵金属催化剂的碳粉分散在有机溶剂中以获得分散体的步骤，将所得分散体与固体高分子电解质的醇溶液混合，制成固体聚合物电解质的胶体，同时获得 将所述胶体吸附到碳粉末上的混合溶液，将混合溶液施加在气体扩散层的一侧以产生电极，并将所得电极压在固体聚合物电解质膜的至少一侧上以使其整合 他们。 此外，可以加入氟碳聚合物，从而形成气体通道，而不会过度地覆盖催化剂并增加电极的气体渗透性。 因此，可以进一步提供在高电流密度区域表现出高性能的固体聚合物电解质燃料电池。
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公开(公告)号：US5474857A
公开(公告)日：1995-12-12
申请号：US265730
申请日：1994-06-27
申请人： Makoto Uchida , Yuko Aoyama , Nobuo Eda , Masahiko Ogawa
发明人： Makoto Uchida , Yuko Aoyama , Nobuo Eda , Masahiko Ogawa
CPC分类号： H01M8/1004 , Y02P70/56 , Y10T29/49115
摘要： The invention provides a solid polymer electrolyte having high performances in which the reaction area of electrode is increased by uniformly dispersing and bonding a solid polymer electrolyte and a catalyst and the ability of gas feeding to the reaction site is improved by adding a fluoropolymer so that the catalyst is not excessively coated. A method for making the fuel cell is also provided. The electrode provided on at least one side of a solid polymer electrolyte membrane is formed by coating on one side of a gas-diffusible layer a mixed dispersion of a noble metal catalyst, a carbon fine powder and a colloidal dispersion of a solid polymer electrolyte, the colloidal dispersion being prepared using an organic solvent having a polar group other than hydroxyl group in the molecule and having a carbon chain of 1-8 carbon atoms which bonds to the polar group or having a dielectric constant of 3-10.
摘要翻译： 本发明提供了一种具有高性能的固体聚合物电解质，其中通过均匀分散和粘合固体聚合物电解质和催化剂来增加电极的反应面积，并且通过加入含氟聚合物来提高进料到反应部位的能力，使得 催化剂没有过度涂层。 还提供了制造燃料电池的方法。 设置在固体聚合物电解质膜的至少一侧的电极通过在气体扩散层的一侧上涂覆贵金属催化剂，碳细粉末和固体聚合物电解质的胶体分散体的混合分散体而形成， 该胶体分散体使用在分子中具有除羟基以外的极性基团并具有与极性基团键合或介电常数为3-10的碳原子数为1-8个碳原子的有机溶剂制备。
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公开(公告)号：US4670811A
公开(公告)日：1987-06-02
申请号：US683493
申请日：1984-12-19
申请人： Nobuo Eda
发明人： Nobuo Eda
摘要： In a differential-type protective relay actuated to generate a signal necessary for the protection of a bus of an electric power system when a troubled current has flown through the bus, a gapped first transformer is used to receive an output from a current transformer which is adapted to detect each current in the bus. Each output of a first detection element, which is actuated when the output of the first transformer is higher than a preset level, is fed out to the exterior only when a value obtained by subtracting the sum of the maximum of the output of the first transformer and the value of a signal obtained by shifting the phase of the output through a predetermined angle from the value of a signal obtained by subjecting the output of the first transformer to full-wave transformation is equal to or lower than a preset value.
摘要翻译： 在一个差动式保护继电器中，当有困难的电流已经通过总线时，被致动以产生保护电力系统总线所必需的信号的差分式保护继电器中，使用有间隙的第一变压器来接收来自电流互感器 适用于检测总线中的每个电流。 当第一变压器的输出高于预设电平时被激励的第一检测元件的每个输出仅在通过减去第一变压器的输出的最大值的和获得的值时被馈送到外部 并且通过使从第一变压器的输出经过全波变换得到的信号的值将输出相位偏移预定角度而获得的信号的值等于或低于预设值。
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公开(公告)号：US06905796B2
公开(公告)日：2005-06-14
申请号：US09042681
申请日：1998-03-12
申请人： Akiko Ishida , Ken Nishimura , Masahiko Ogawa , Nobuo Eda , Masaki Kitagawa , Tetsuhisa Sakai
发明人： Akiko Ishida , Ken Nishimura , Masahiko Ogawa , Nobuo Eda , Masaki Kitagawa , Tetsuhisa Sakai
IPC分类号： H01M4/02 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/137 , H01M4/62 , H01M6/16 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/36 , H01M10/40
CPC分类号： H01M4/62 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/137 , H01M4/621 , H01M6/168 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M2004/027
摘要： A lithium secondary battery has high capacity and excellent current characteristics. The lithium battery comprises of a positive electrode, a negative electrode and an electrolyte; the negative electrode comprising Al2O3 particles not relating to the charge-and discharge reactions of the battery. The presence of the ceramics particles in the electrode leads to a decrease in the internal resistance of the battery because of the enhancement of ion conductivity in the electrode, resulting in higher capacity at high rate discharge of the lithium secondary battery.
摘要翻译： 锂二次电池具有高容量和优异的电流特性。 锂电池包括正极，负极和电解质; 所述负极包含与电池的充放电反应无关的Al 2 O 3 3颗粒。 由于电极中的离子传导性的提高，电极中的陶瓷粒子的存在导致电池的内部电阻降低，导致锂二次电池的高倍率放电时的容量增加。
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公开(公告)号：US06215272B1
公开(公告)日：2001-04-10
申请号：US09457401
申请日：1999-12-09
申请人： Hideo Ohara , Makoto Uchida , Yuko Fukuoka , Yasushi Sugawara , Nobuo Eda , Keiichi Iiyama
发明人： Hideo Ohara , Makoto Uchida , Yuko Fukuoka , Yasushi Sugawara , Nobuo Eda , Keiichi Iiyama
IPC分类号： H02J700
CPC分类号： H01M8/04626 , H01M8/04298 , H01M8/04947 , H01M10/44 , H01M16/006 , H02J7/34
摘要： A fuel cell device, wherein, after an output voltage from a main body of a fuel cell is converted using a converter, the relation between the resultant predetermined output voltage V 1 and an output voltage V 2 from a secondary battery is so set as to satisfy V 1>V 2. When, at the time of a sudden change of an external load, the output voltage V from the main body of the fuel cell becomes lower than a predetermined voltage V 3, an output to a charge controlling unit is stopped. When the output voltage V from the main body of the fuel cell is lowered even further and becomes lower than a predetermined voltage V 4, an output to an auxiliary device, which is necessary for driving the fuel cell device, is switched from the output from the converter to the output from the secondary battery.
摘要翻译： 一种燃料电池装置，其中，在使用转换器对来自燃料电池的主体的输出电压进行了转换之后，从二次电池得到的预定的输出电压V 1与输出电压V 2的关系设定为 满足V 1> V 2.当外部负载突然变化时，来自燃料电池主体的输出电压V变得低于预定电压V 3时，向充电控制单元输出的输出为 停了 当来自燃料电池主体的输出电压V进一步降低并且变得低于预定电压V 4时，从驱动燃料电池装置所需的辅助装置的输出切换为 转换器到二次电池的输出。
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公开(公告)号：US4172927A
公开(公告)日：1979-10-30
申请号：US949380
申请日：1978-10-06
申请人： Yoshinori Toyoguchi , Nobuo Eda , Takashi Iijima
发明人： Yoshinori Toyoguchi , Nobuo Eda , Takashi Iijima
摘要： This invention relates to improvement in an organic electrolyte battery employing a light metal as an anodic material; organic electrolyte; and CuO as a cathodic material.By using, as the cathodic material, the solid solution of alkali metal oxide and CuO as a mother substance, the delivered volumetric energy density of the battery is fairly increased.
摘要翻译： 本发明涉及使用轻金属作为阳极材料的有机电解质电池的改进; 有机电解液 和CuO作为阴极材料。
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