公开(公告)号：US08597500B2

公开(公告)日：2013-12-03

申请号：US12921436

申请日：2009-03-13

申请人： Youhao Xu ,  Lishun Dai ,  Zhigang Zhang ,  Shouye Cui ,  Jianhong Gong ,  Chaogang Xie ,  Jun Long ,  Hong Nie ,  Zhijian Da ,  Jiushun Zhang ,  Tao Liu ,  Anguo Mao

发明人： Youhao Xu ,  Lishun Dai ,  Zhigang Zhang ,  Shouye Cui ,  Jianhong Gong ,  Chaogang Xie ,  Jun Long ,  Hong Nie ,  Zhijian Da ,  Jiushun Zhang ,  Tao Liu ,  Anguo Mao

IPC分类号： C10G11/00

CPC分类号： C10G55/06 ,  C10G11/18 ,  C10G67/0409 ,  C10G69/04 ,  C10G2300/1033 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/1055 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/203 ,  C10G2300/205 ,  C10G2300/308 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/4093 ,  C10G2300/44 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/28

摘要： A catalytic conversion process to convert inferior feedstock to high quality fuel oil and propylene is disclosed. Inferior feedstock is introduced into first and second reactor zone, wherein first step and second step reactions occur by contacting with catalytic conversion catalyst. Product vapors include fluid catalytic cracking gas oil (FGO) which is introduced into a hydrotreating unit and/or extraction unit to obtain hydrotreated FGO and/or extracted FGO. Hydrotreated FGO and/or extracted FGO returns to the first reactor zone and/or another catalytic cracking unit to obtain propylene and gasoline. The extracted oil of said FGO is rich in double ring aromatics and the raffinate of said FGO is rich in chain alkane and cycloalkane. More particularly, the invention utilizes petroleum oil resources efficiently for decreasing the yield of dry gas and coke significantly.

摘要翻译： 公开了将劣质原料转化为高质量燃料油和丙烯的催化转化方法。 将不良原料引入第一和第二反应器区，其中通过与催化转化催化剂接触进行第一步和第二步反应。 产物蒸气包括流化催化裂化瓦斯油（FGO），其被引入加氢处理单元和/或提取单元以获得加氢处理的FGO和/或提取的FGO。 加氢处理的FGO和/或提取的FGO返回到第一反应器区和/或另一个催化裂化单元以获得丙烯和汽油。 所述FGO的提取油富含双环芳族化合物，所述FGO的残油富含链烷烃和环烷烃。 更具体地说，本发明有效地利用石油资源，显着降低干气和焦炭的产率。

公开(公告)号：US20110000818A1

公开(公告)日：2011-01-06

申请号：US12921436

申请日：2009-03-13

申请人： Youhao Xu ,  Lishun Dai ,  Zhigang Zhang ,  Shouye Cui ,  Jianhong Gong ,  Chaogang Xie ,  Jun Long ,  Hong Nie ,  Zhijian Da ,  Jiushun Zhang ,  Tao Liu ,  Anguo Mao

发明人： Youhao Xu ,  Lishun Dai ,  Zhigang Zhang ,  Shouye Cui ,  Jianhong Gong ,  Chaogang Xie ,  Jun Long ,  Hong Nie ,  Zhijian Da ,  Jiushun Zhang ,  Tao Liu ,  Anguo Mao

IPC分类号： C10G57/00

CPC分类号： C10G55/06 ,  C10G11/18 ,  C10G67/0409 ,  C10G69/04 ,  C10G2300/1033 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/1055 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/203 ,  C10G2300/205 ,  C10G2300/308 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/4093 ,  C10G2300/44 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/28

摘要： A catalytic conversion process can convert inferior feedstock to high quality fuel oil and propylene. A inferior feedstock is introduced into first and second reactor zone, wherein the feedstock carry out first step and second step reactions by contacting with catalytic conversion catalyst. Product vapors separate from spent catalyst by gas-solid separation. The spent catalyst is stripped, regenerated by burning off coke and then returns to reactor. The product vapors are introduced into separation system to obtain propylene, gasoline, diesel, fluid catalytic cracking gas oil (FGO) and other products. The FGO is introduced into hydrotreating unit and/or extraction unit to obtain hydrotreated FGO and/or extracted FGO. Said hyrotreated FGO and/or extracted FGO return to the first reactor zone and/or another catalytic cracking unit to obtain propylene and gasoline. The extracted oil of said FGO is rich in double ring aromatics which are good chemical materials. The raffinate of said FGO is rich in chain alkane and cycloalkane which are suitable for catalytic cracking. More particularly, the invention relates to a process to utilize petroleum oil resources efficiently for decreasing the yield of dry gas and coke significantly.

摘要翻译： 催化转化过程可以将劣质原料转化为高质量的燃料油和丙烯。 将劣质原料引入第一和第二反应器区，其中原料通过与催化转化催化剂接触进行第一步和第二步反应。 产物蒸气通过气 - 固分离与废催化剂分离。 废弃的催化剂被汽提，通过燃烧焦炭再生，然后返回反应器。 将产品蒸气引入分离系统中，得到丙烯，汽油，柴油，流化催化裂化瓦斯油（FGO）等产品。 将FGO引入加氢处理单元和/或提取单元以获得加氢处理的FGO和/或提取的FGO。 所述经处理的FGO和/或提取的FGO返回到第一反应器区和/或另一个催化裂化装置以获得丙烯和汽油。 所述FGO的提取油富含双环芳族化合物，其为良好的化学物质。 所述FGO的萃余液富含链烷烃和环烷烃，适用于催化裂化。 更具体地说，本发明涉及一种利用石油资源有效降低干燥气体和焦炭产率的方法。

公开(公告)号：US08696887B2

公开(公告)日：2014-04-15

申请号：US12672666

申请日：2008-08-07

申请人： Youhao Xu ,  Lishun Dai ,  Longsheng Tian ,  Shouye Cui ,  Jianhong Gong ,  Chaogang Xie ,  Jiushun Zhang ,  Jun Long ,  Zhijian Da ,  Hong Nie ,  Jinbiao Guo ,  Zhigang Zhang

发明人： Youhao Xu ,  Lishun Dai ,  Longsheng Tian ,  Shouye Cui ,  Jianhong Gong ,  Chaogang Xie ,  Jiushun Zhang ,  Jun Long ,  Zhijian Da ,  Hong Nie ,  Jinbiao Guo ,  Zhigang Zhang

IPC分类号： C10G11/00

CPC分类号： B01J29/084 ,  B01J29/46 ,  B01J29/80 ,  B01J29/90 ,  B01J37/0045 ,  B01J38/30 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/1055 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/4093 ,  C10G2400/02 ,  C10G2400/06 ,  C10G2400/20

摘要： A catalytic conversion process which comprises catalytic cracking reaction of a hydrocarbon feedstock contacting with a medium pore size zeolite enriched catalyst in a reactor, characterized in that reaction temperature, weight hourly space velocity and catalyst/feedstock ratio by weight are sufficient to achieve a yield of fluid catalytic cracking gas oil between 12% and 60% by weight of said feedstock, wherein said weight hourly space velocity is between 25 h−1 and 100 h−1, said reaction temperature is between 450° C. and 600° C., and said catalyst/feedstock ratio by weight is between 1 and 30. This invention relates to a catalytic conversion process, especially for heavy feedstock oil to produce higher octane gasoline and an enhanced yield of propylene. More particularly, the invention relates to a process to utilize petroleum oil resources efficiently for decreasing the yield of dry gas and coke significantly.

摘要翻译： 催化转化方法，其包括在反应器中与中等孔径的沸石富集催化剂接触的烃原料的催化裂化反应，其特征在于反应温度，重量时空速和催化剂/原料重量比足以实现 流化催化裂化瓦斯油在所述原料的12重量％至60重量％之间，其中所述重时空速在25h -1和100h -1之间，所述反应温度在450℃和600℃之间， 并且所述催化剂/原料的重量比在1和30之间。本发明涉及催化转化方法，特别是用于重质原料油生产高辛烷值汽油和提高丙烯收率的方法。 更具体地说，本发明涉及一种利用石油资源有效降低干燥气体和焦炭产率的方法。

公开(公告)号：US20100213102A1

公开(公告)日：2010-08-26

申请号：US12672666

申请日：2008-08-07

申请人： Youhao Xu ,  Lishun Dai ,  Longsheng Tian ,  Shouye Cui ,  Jianhong Gong ,  Chaogang Xie ,  Jiushun Zhang ,  Jun Long ,  Zhijian Da ,  Hong Nie ,  Jinbiao Guo ,  Zhigang Zhang

发明人： Youhao Xu ,  Lishun Dai ,  Longsheng Tian ,  Shouye Cui ,  Jianhong Gong ,  Chaogang Xie ,  Jiushun Zhang ,  Jun Long ,  Zhijian Da ,  Hong Nie ,  Jinbiao Guo ,  Zhigang Zhang

IPC分类号： C10G57/00 ,  C10G11/05

CPC分类号： B01J29/084 ,  B01J29/46 ,  B01J29/80 ,  B01J29/90 ,  B01J37/0045 ,  B01J38/30 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/1055 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/4093 ,  C10G2400/02 ,  C10G2400/06 ,  C10G2400/20

摘要： A catalytic conversion process which comprises catalytic cracking reaction of a hydrocarbon feedstock contacting with a medium pore size zeolite enriched catalyst in a reactor, characterized in that reaction temperature, weight hourly space velocity and catalyst/feedstock ratio by weight are sufficient to achieve a yield of fluid catalytic cracking gas oil between 12% and 60% by weight of said feedstock, wherein said weight hourly space velocity is between 25 h−1 and 100 h−1, said reaction temperature is between 450° C. and 600° C., and said catalyst/feedstock ratio by weight is between 1 and 30. This invention relates to a catalytic conversion process, especially for heavy feedstock oil to produce higher octane gasoline and an enhanced yield of propylene. More particularly, the invention relates to a process to utilize petroleum oil resources efficiently for decreasing the yield of dry gas and coke significantly.

摘要翻译： 催化转化方法，其包括在反应器中与中等孔径的沸石富集催化剂接触的烃原料的催化裂化反应，其特征在于反应温度，重量时空速和催化剂/原料重量比足以实现 流化催化裂化瓦斯油在所述原料的12重量％至60重量％之间，其中所述重时空速在25h -1和100h -1之间，所述反应温度在450℃和600℃之间， 并且所述催化剂/原料的重量比在1和30之间。本发明涉及催化转化方法，特别是用于重质原料油生产高辛烷值汽油和提高丙烯收率的方法。 更具体地说，本发明涉及一种利用石油资源有效降低干燥气体和焦炭产率的方法。

公开(公告)号：US09611432B2

公开(公告)日：2017-04-04

申请号：US12822493

申请日：2010-06-24

申请人： Youhao Xu ,  Shouye Cui ,  Jun Long ,  Jianhong Gong ,  Zhijian Da ,  Jiushun Zhang ,  Yuxia Zhu ,  Yibin Luo ,  Jinlian Tang

发明人： Youhao Xu ,  Shouye Cui ,  Jun Long ,  Jianhong Gong ,  Zhijian Da ,  Jiushun Zhang ,  Yuxia Zhu ,  Yibin Luo ,  Jinlian Tang

IPC分类号： C10G11/18 ,  B01J29/06 ,  C10G11/05 ,  B01J29/08 ,  B01J35/00 ,  B01J37/04 ,  B01J37/10

CPC分类号： C10G11/05 ,  B01J29/06 ,  B01J29/084 ,  B01J29/088 ,  B01J29/90 ,  B01J35/002 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/10 ,  B01J38/30 ,  B01J2229/16 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  C10G11/18

摘要： The present invention provides a catalytic cracking catalyst, processing method and use thereof. When the catalyst is added into a commercial catalytic cracking unit, it has an initial activity of not higher than 80, preferably not higher than 75, more preferably not higher than 70, a self-balancing time of 0.1-50 h, and an equilibrium activity of 35-60. Said method enables the activity and selectivity of the catalyst in the catalytic cracking unit to be more homogeneous and notably improves the selectivity of the catalytic cracking catalyst, so as to obviously reduce the dry gas and coke yields, to sufficiently use steam and to reduce the energy consumption of the FCC unit.

公开(公告)号：US08529754B2

公开(公告)日：2013-09-10

申请号：US12888780

申请日：2010-09-23

申请人： Shouye Cui ,  Youhao Xu ,  Zhihai Hu ,  Jianhong Gong ,  Chaogang Xie ,  Yun Chen ,  Zhigang Zhang ,  Jianwei Dong

发明人： Shouye Cui ,  Youhao Xu ,  Zhihai Hu ,  Jianhong Gong ,  Chaogang Xie ,  Yun Chen ,  Zhigang Zhang ,  Jianwei Dong

IPC分类号： C10G11/00

CPC分类号： C10G11/18 ,  C10G11/05 ,  C10G55/06 ,  C10G69/04 ,  C10L1/08

摘要： The present invention relates to a catalytic conversion process for producing more diesel and propylene, comprising contacting the feedstock oil with a catalyst having a relatively homogeneous activity in a reactor, wherein the reaction temperature, weight hourly space velocity and weight ratio of the catalyst/feedstock oil are sufficient to obtain a reaction product containing from 12 to 60% by weight of a fluid catalytic cracking gas oil relative to the weight of the feedstock oil; the fluid catalytic cracking gas oil is fed into the fluid catalytic cracking gas oil treatment device for further processing. Catalytic cracking, hydrogenation, solvent extraction, hydrocracking and process for producing more diesel are organically combined together, and hydrocarbons such as alkanes, alkyl side chains in the feedstock for catalysis are selectively cracked and isomerized.

摘要翻译： 本发明涉及一种用于生产更多柴油和丙烯的催化转化方法，包括使原料油与反应器中具有相对均相活性的催化剂接触，其中反应温度，重量时空速和催化剂/原料的重量比 油足以获得相对于原料油的重量，含有12至60重量％流化催化裂化瓦斯油的反应产物; 将流化催化裂化瓦斯油送入流化催化裂化瓦斯油处理装置进行进一步处理。 催化裂化，氢化，溶剂萃取，加氢裂化和生产更多柴油的方法有机地结合在一起，烃类如烷烃，催化原料中的烷基侧链选择性裂化和异构化。

公开(公告)号：US20130001129A1

公开(公告)日：2013-01-03

申请号：US13503529

申请日：2010-10-20

申请人： Youhao Xu ,  Jianhong Gong ,  Congli Cheng ,  Shouye Cui ,  Zhihai Hu ,  Yun Chen

发明人： Youhao Xu ,  Jianhong Gong ,  Congli Cheng ,  Shouye Cui ,  Zhihai Hu ,  Yun Chen

IPC分类号： C10G11/05 ,  C10G69/04 ,  C10G51/06 ,  C10G51/04 ,  C10G57/00

CPC分类号： C10G11/05 ,  C10G11/18 ,  C10G45/08 ,  C10G45/12 ,  C10G51/026 ,  C10G69/00 ,  C10G69/04 ,  C10G2300/1037 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/307 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10L1/06 ,  C10L1/08

摘要： A catalytic conversion process for increasing the cetane number barrel of diesel, in which contacting the feedstock oil with a catalytic cracking catalyst having a relatively homogeneous activity containing mainly the large pore zeolites in a catalytic conversion reactor, wherein the reaction temperature, residence time of oil vapors and weight ratio of the catalyst/feedstock oil are sufficient to obtain a reaction product containing from about 12 to about 60% by weight of a fluid catalytic cracking gas oil relative to the weight of the feedstock oil and containing a diesel; the reaction temperature ranges from about 420° C. to about 550° C.; the residence time of oil vapors ranges from about 0.1 to about 5 seconds; the weight ratio of the catalytic cracking catalyst/feedstock oil is about 1-about 10. The fluid catalytic cracking gas oil is fed into other unit for further treatment or is fed back to the initial catalytic conversion reactor. The process allows the maximum production of high cetane number diesel, the cracking catalyst having a coarse particle size distribution can further improve the selectivity of dry gas and coke, and can reduce the breaking tendency of the catalyst and the consumption of the catalyst.

摘要翻译： 一种用于增加柴油的十六烷值桶的催化转化方法，其中催化转化反应器中原料油与主要含有大孔沸石的相对均相活性的催化裂化催化剂接触，其中反应温度，油的停留时间 催化剂/原料油的蒸气和重量比足以获得含有约12至约60重量％的流化催化裂化瓦斯油相对于原料油的重量并含有柴油的反应产物; 反应温度范围为约420℃至约550℃; 油蒸气的停留时间为约0.1至约5秒; 催化裂化催化剂/原料油的重量比为约1-约10.流化催化裂化瓦斯油进料到其他单元进行进一步处理或反馈到初始催化转化反应器。 该方法允许最大限度地生产高十六烷值柴油，具有粗粒度分布的裂化催化剂可以进一步提高干燥气体和焦炭的选择性，并且可以降低催化剂的破坏趋势和催化剂的消耗。

公开(公告)号：US08932457B2

公开(公告)日：2015-01-13

申请号：US13503529

申请日：2010-10-20

申请人： Youhao Xu ,  Jianhong Gong ,  Congli Cheng ,  Shouye Cui ,  Zhihai Hu ,  Yun Chen

发明人： Youhao Xu ,  Jianhong Gong ,  Congli Cheng ,  Shouye Cui ,  Zhihai Hu ,  Yun Chen

IPC分类号： C10G11/05 ,  C10G51/02 ,  C10G69/04 ,  C10L1/08 ,  C10G45/08 ,  C10G45/12 ,  C10G69/00 ,  C10L1/06 ,  C10G11/18

CPC分类号： C10G11/05 ,  C10G11/18 ,  C10G45/08 ,  C10G45/12 ,  C10G51/026 ,  C10G69/00 ,  C10G69/04 ,  C10G2300/1037 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/307 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10L1/06 ,  C10L1/08

摘要： A catalytic conversion process uses a catalytic cracking catalyst having a relatively homogeneous activity containing mainly large pore zeolites in a catalytic conversion reactor. The reaction temperature, residence time of oil vapors and weight ratio of the catalyst/feedstock oil are sufficient to obtain a reaction product containing from about 12 to about 60% by weight of a fluid catalytic cracking gas oil relative to the weight of the feed stock oil and containing a diesel. The reaction temperature ranges from about 420° C. to about 550° C. The residence time of oil vapors ranges from about 0.1 to about 5 seconds. The weight ratio of the catalytic cracking catalyst/feedstock is about 1-about 10.

摘要翻译： 催化转化方法使用在催化转化反应器中具有主要含有大孔沸石的相对均相活性的催化裂化催化剂。 油蒸气的反应温度，停留时间和催化剂/原料油的重量比足以获得含有约12至约60重量％的流化催化裂化瓦斯油相对于原料重量的反应产物 油和含柴油。 反应温度范围为约420℃至约550℃。油蒸气的停留时间为约0.1至约5秒。 催化裂化催化剂/原料的重量比为约1-约10。