公开(公告)号：US06303809B1

公开(公告)日：2001-10-16

申请号：US09458305

申请日：1999-12-10

申请人： Yun Chi ,  Feng Jen Lee ,  Chao-Shiuan Liu

发明人： Yun Chi ,  Feng Jen Lee ,  Chao-Shiuan Liu

IPC分类号： C07F1500

CPC分类号： C07F15/0053 ,  C07F15/0026

摘要： A series of organometallic complexes of the general formula [M(CO)2L2] was provided, wherein M is ruthenium or osmium metal, and L is a &bgr;-diketonate ligand RC(O)CHC(O)R1 where each of R and R1 is independently selected from the group consisting of atoms of the element, C, H, O and F. These ruthenium and osmium complexes possess enhanced volatility and thermal stability characteristics, and are very suitable for CVD applications. Also disclosed are CVD methods by using these ruthenium or osmium complexes as source reagents for deposition of Ru, Os, RuO2, OsO2, and other Ru- or Os-containing films such as mixed metal oxide materials BaRuO3, SrRuO3, Sr2RuO4 and Bi2Ru2O7 or bimetallic alloys Pt/Ru and Pd/Ru.

摘要翻译： 提供了一系列具有通式[M（CO）2 L 2]的有机金属络合物，其中M是钌或锇金属，L是β-二酮配体RC（O）CHC（O）R 1，其中R和R 1 独立地选自元素C，H，O和F的原子。这些钌和锇络合物具有增强的挥发性和热稳定性特征，并且非常适用于CVD应用。 还公开了通过使用这些钌或锇络合物作为沉积Ru，Os，RuO 2，OsO 2和其它含Ru或Os的膜，例如混合金属氧化物材料BaRuO 3，SrRuO 3，Sr 2 RuO 4和Bi 2 Ru 2 O 7或双金属 合金Pt / Ru和Pd / Ru。

公开(公告)号：US06369256B1

公开(公告)日：2002-04-09

申请号：US09589757

申请日：2000-06-09

申请人： Yun Chi ,  Peng-Fu Hsu ,  Tsung-Wu Lin ,  Chao-Shiuan Liu ,  Arthur J. Carty

发明人： Yun Chi ,  Peng-Fu Hsu ,  Tsung-Wu Lin ,  Chao-Shiuan Liu ,  Arthur J. Carty

IPC分类号： C07F108

CPC分类号： C23C16/18 ,  C07C215/08 ,  C07C217/08

摘要： Volatile low melting solid Cu(II) metal complexes are provided which are capable of depositing a copper film on various substrates under CVD conditions in the absence of reducing carrier gas H2. These CU(II) metal complexes are represented by the structure formula: Cu(OCCF3R1CH2NHR2)2 wherein R1 is selected from hydrogen, C1-C4 lower-alkyl or perfluorinated C1-C4 lower-alkyl groups, e.g., CH3, and CF3, etc., and wherein R2 is C1-C6 lower-alkyl or C1-C6 lower-alkene, which may be substituted by one or more fluorine atoms, by a C1-C6 lower-alkoxy group or by a C1-C6 di-lower-alkyl amino group, provided that when R1 is CF3, R2 is other than hydrogen or methyl. A process for depositing copper film using these Cu(II) metal complexes is also provided.

摘要翻译： 提供挥发性低熔点固体Cu（II）金属络合物，其能够在不存在还原载气H2的CVD条件下在各种基材上沉积铜膜。 这些CU（II）金属络合物由结构式表示：其中R1选自氢，C1-C4低级烷基或全氟化C1-C4低级烷基，例如CH3和CF3等，其中R2 是可被C1-C6低级烷氧基或C1-C6二低级烷基氨基取代的可被一个或多个氟原子取代的C 1 -C 6低级烷基或C 1 -C 6低级烯 当R1是CF3时，R2不是氢或甲基。 还提供了使用这些Cu（II）金属络合物沉积铜膜的方法。

公开(公告)号：US07112690B2

公开(公告)日：2006-09-26

申请号：US10495073

申请日：2002-11-08

申请人： Yun Chi ,  Yao-Lun Chen ,  Chao-Shiuan Liu ,  Yi-Hwa Song ,  Ying-Hui Lai ,  Arthur J. Carty

发明人： Yun Chi ,  Yao-Lun Chen ,  Chao-Shiuan Liu ,  Yi-Hwa Song ,  Ying-Hui Lai ,  Arthur J. Carty

IPC分类号： C07F15/00 ,  C23C16/00

CPC分类号： C07F15/004 ,  C07F15/002 ,  C07F15/0026 ,  C07F15/0033 ,  C07F15/0046 ,  C07F15/0053

摘要： A series of noble metal organometallic complexes of the general formula (I): MLaXb(FBC)c, wherein M is a noble metal such as iridium, ruthenium or osmium, and L is a neutral ligand such as carbonyl, alkene or diene; X is an anionic ligand such as chloride, bromide, iodide and trifluoroacetate group; and FBC is a fluorinated bidentate chelate ligand such as beta diketonate, beta-ketoiminate, amino-alcoholate and amino-alcoholate ligand, wherein a is an integer of from zero (0) to three (3), b is an integer of from zero (0) to one (1) and c is an 10 integer of from one (1) to three (3). The resulting noble metal complexes possess enhanced volatility and thermal stability characteristics, and are suitable for chemical vapor deposition(CVD) applications. The corresponding noble metal complex is formed by treatment of the FBC ligand with a less volatile metal halide. Also disclosed are CVD methods for using the noble metal complexes as source reagents for deposition of noble metal-containing films such as Ir, Ru and Os, or even metal oxide film materials IrO2, OsO2 and RuO2.

摘要翻译： 一系列通式（I）的贵金属有机金属络合物：其中M是贵金属（I） 金属如铱，钌或锇，L是中性配体如羰基，烯烃或二烯; X是阴离子配体，如氯化物，溴化物，碘化物和三氟乙酸盐基团; 并且FBC是氟化双齿螯合配体，例如β-二酮酸酯，β-酮亚胺酸酯，氨基醇化物和氨基醇化物配体，其中a是从零（0）到三（3）的整数，b是零的整数 （0）〜（1），c为1（3）的10个整数。 所得到的贵金属络合物具有增强的挥发性和热稳定性特性，并且适用于化学气相沉积（CVD）应用。 通过用不太易挥发的金属卤化物处理FBC配体形成相应的贵金属络合物。 还公开了使用贵金属络合物作为用于沉积含有贵金属的膜如Ir，Ru和Os，或甚至金属氧化物膜材料IrO 2，OsO 2， 2＆lt; 2＆gt;和RuO 2＆lt; 2＆gt ;.

公开(公告)号：US20050033075A1

公开(公告)日：2005-02-10

申请号：US10495073

申请日：2002-11-08

申请人： Yun Chi ,  Yao-Lun Chen ,  Chao-Shiuan Liu ,  Yi-Hwa Song ,  Ying-Hui Lai ,  Arthur Carty

发明人： Yun Chi ,  Yao-Lun Chen ,  Chao-Shiuan Liu ,  Yi-Hwa Song ,  Ying-Hui Lai ,  Arthur Carty

IPC分类号： C07F15/00 ,  C07F1/08 ,  C07F1/10 ,  C07F1/12

CPC分类号： C07F15/004 ,  C07F15/002 ,  C07F15/0026 ,  C07F15/0033 ,  C07F15/0046 ,  C07F15/0053

摘要： A series of noble metal organometallic complexes of the general formula (I): MLaXb(FBC)c, wherein M is a noble metal such as iridium, ruthenium or osmium, and L is a neutral ligand such as carbonyl, alkene or diene; X is an anionic ligand such as chloride, bromide, iodide and trifluoroacetate group; and FBC is a fluorinated bidentate chelate ligand such as beta diketonate, beta-ketoiminate, amino-alcoholate and amino-alcoholate ligand, wherein a is an integer of from zero (0) to three (3), b is an integer of from zero (0) to one (1) and c is an 10 integer of from one (1) to three (3). The resulting noble metal complexes possess enhanced volatility and thermal stability characteristics, and are suitable for chemical vapor deposition(CVD) applications. The corresponding noble metal complex is formed by treatment of the FBC ligand with a less volatile metal halide. Also disclosed are CVD methods for using the noble metal complexes as source reagents for deposition of noble metal-containing films such as Ir, Ru and Os, or even metal oxide film materials IrO2, OsO2 and RuO2.

摘要翻译： 一系列通式（I）的贵金属有机金属络合物：MLaXb（FBC）c，其中M是贵金属如铱，钌或锇，L是中性配体如羰基，烯烃或二烯; X是阴离子配体，如氯化物，溴化物，碘化物和三氟乙酸盐基团; 并且FBC是氟化双齿螯合配体，例如β-二酮酸酯，β-酮亚胺酸酯，氨基醇化物和氨基醇化物配体，其中a是从零（0）到三（3）的整数，b是零的整数 （0）〜（1），c为1（3）的10个整数。 所得到的贵金属络合物具有增强的挥发性和热稳定性特性，并且适用于化学气相沉积（CVD）应用。 通过用不太易挥发的金属卤化物处理FBC配体形成相应的贵金属络合物。 还公开了使用贵金属络合物作为用于沉积含有贵金属的膜如Ir，Ru和Os，或甚至金属氧化物膜材料IrO 2，OsO 2和RuO 2的源试剂的CVD方法。

公开(公告)号：US08822818B2

公开(公告)日：2014-09-02

申请号：US13306609

申请日：2011-11-29

申请人： Yun Chi ,  Cheng-Xuan Li ,  Shen-Han Yang ,  Hsin-Pei Wu ,  Kuan-Lin Wu ,  Chien-Wei Hsu ,  Shih-Han Chang

发明人： Yun Chi ,  Cheng-Xuan Li ,  Shen-Han Yang ,  Hsin-Pei Wu ,  Kuan-Lin Wu ,  Chien-Wei Hsu ,  Shih-Han Chang

IPC分类号： C07D401/14 ,  C07D409/14 ,  C07D495/04 ,  C07F15/00 ,  H01L51/00 ,  H01G9/20

CPC分类号： C07D401/14 ,  C07D409/14 ,  C07D495/04 ,  C07F15/0053 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0037 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549

摘要： Disclosed is a 4,4′-dicarboxy-2,2′-bipyridine derived tridentate ligand represented by formula (I): wherein definitions of Y1, Y2, and R are the same as those defined in the specification. Also disclosed are a metal complex containing the aforesaid tridentate ligand and a dye-sensitized solar cell containing the metal complex.

摘要翻译： 公开了由式（I）表示的4,4'-二羧基-2,2'-联吡啶衍生的三齿配体：其中Y1，Y2和R的定义与说明书中定义的相同。 还公开了含有上述三齿配体的金属络合物和含有金属络合物的染料敏化太阳能电池。

公开(公告)号：US08762323B2

公开(公告)日：2014-06-24

申请号：US13270218

申请日：2011-10-10

申请人： Hyun Jin Moon ,  Wang-Pin Hsiung ,  Vahit Hakan Hacigumus ,  Yun Chi

发明人： Hyun Jin Moon ,  Wang-Pin Hsiung ,  Vahit Hakan Hacigumus ,  Yun Chi

IPC分类号： G06F17/30

CPC分类号： G06F9/5083

摘要： A swap-based multitenant database load balancing (SWAT) invention finds an optimal swap set that eliminates hotspots, and finds a sequencing and parallelization of swap executions for the multitenant database.

摘要翻译： 基于交换的多租户数据库负载平衡（SWAT）发现找到一个消除热点的最佳交换集，并找到多租户数据库的交换执行的排序和并行化。

公开(公告)号：US08759521B2

公开(公告)日：2014-06-24

申请号：US13354010

申请日：2012-01-19

申请人： Yun Chi ,  Kellen Chen ,  Yi-Huan Hong ,  Pi-Tai Chou ,  Bo-So Chen

发明人： Yun Chi ,  Kellen Chen ,  Yi-Huan Hong ,  Pi-Tai Chou ,  Bo-So Chen

IPC分类号： C07F15/00 ,  H01L31/042

CPC分类号： C07F15/0046 ,  C07F15/0053 ,  C09B57/10 ,  C09B69/008 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0086 ,  H01M14/005 ,  Y02E10/542 ,  Y02E10/549

摘要： Panchromatic photosensitizers having a Formula of ML1L2X were synthesized, wherein M represents ruthenium atom; X represents a monodentate anion; L1 is heterocyclic bidentate ligand having one of formulae listed below: wherein G2 has one of formulae listed below: and L2 is a tridentate ligand having a formula listed below: Substituents R1, R2, R3 and R4 of L1 are the same or different and are selected from the group consisting of hydrogen, halogen, amino-group alkyl, alkoxy, alkylthio, alkylamino, halogenated alkyl, phenyl and substituted phenyl group. Substituents R5, R6 and R7 of L2 are the same or different and are selected from the group consisting of carboxylic, carboxylate, sulfonic acid, sulfonate, phosphoric acid and phosphate. The above-mentioned photosensitizers are suitable to use as sensitizers for fabrication of high efficiency dye-sensitized solar cell.

摘要翻译： 合成具有式ML1L2X的全色光敏剂，其中M表示钌原子; X表示单齿阴离子; L1是具有以下列出的下式之一的杂环二齿配位体：其中，G2具有以下列举的其中之一：L2是具有下式的三齿配体：L1的取代基R1，R2，R3和R4相同或不同， 选自氢，卤素，氨基 - 烷基，烷氧基，烷硫基，烷基氨基，卤代烷基，苯基和取代的苯基。 L2的取代基R5，R6和R7相同或不同，并且选自羧酸，羧酸酯，磺酸，磺酸酯，磷酸和磷酸酯。 上述光敏剂适用于制造高效染料敏化太阳能电池的敏化剂。

公开(公告)号：US08030490B2

公开(公告)日：2011-10-04

申请号：US12000035

申请日：2007-12-07

申请人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

发明人： Yun Chi ,  Pi-Tai Chou ,  Yi-Hwa Song ,  Yuan-Chieh Chiu ,  Chiung-Fang Chang

IPC分类号： C07F15/00

CPC分类号： C07F15/0033

摘要： The present invention discloses a phosphorescent tris-chelated transition metal complex comprising i) two identical non-conjugated cyclometalated ligands being incorporated into a coordination sphere thereof with a transition metal, and one ligated chromophore being incorporated into the coordination sphere; or ii) one non-conjugated cyclometalated ligand forming a coordination sphere thereof with a transition metal, and two ligated chromophores being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the ligated chromophore possesses a relatively lower energy gap in comparison with that of the non-conjugated cyclometalated ligand, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that a subsequent radiative decay from an excited state of these transition complexes will be confined to the single ligated chromophore. The architecture and energy gap of the ligated chromophore are suitable for generation of high efficiency blue, green and even red emissions.

摘要翻译： 本发明公开了一种磷光三螯合过渡金属络合物，其包括i）两个相同的非共轭环金属化配体与过渡金属掺入其配位球中，并将一个连接的发色团并入配位球; 或ii）一种非共轭环金属化配体与过渡金属形成配位球，并且将两个连接的发色团掺入配位球中，其中金属是铱，铂，锇或钌，并且连接的发色团具有相对较低的 能量间隙与非共轭环金属配体相比，后者为抑制配体 - 配体电荷转移过程提供了有效的屏障，使得随后从这些过渡配合物的激发态的辐射衰减将被限制在 单连结发色团。 连结发色团的结构和能隙适合于产生高效率的蓝，绿，甚红色发射。

公开(公告)号：US07868170B2

公开(公告)日：2011-01-11

申请号：US12003532

申请日：2007-12-28

申请人： Yun Chi ,  Pi-Tai Chou ,  Sheng-Yuan Chang

发明人： Yun Chi ,  Pi-Tai Chou ,  Sheng-Yuan Chang

IPC分类号： C07F15/00 ,  H05B33/10

CPC分类号： C07F15/0093 ,  H01L51/0081 ,  H01L51/0087 ,  H01L51/009 ,  H01L51/5016

摘要： The present invention relates to a platinum complex as the following formula (I): wherein X, n, R1, R2, R3,R4, R5, X1, X2, L1, and L2 are defined the same as the specification. The present invention also further provides an organic light-emitting device using the same. The complexes of the present invention exhibit enhanced emission quantum yields, and short phosphorescence radiative lifetimes in the range of several microseconds so as to be applied in high efficiency OLEDs.

摘要翻译： 本发明涉及如下式（I）的铂络合物：其中X，n，R1，R2，R3，R4，R5，X1，X2，L1和L2与本说明书相同。 本发明还提供一种使用其的有机发光装置。 本发明的配合物在几微秒的范围内表现出增强的发射量子产率和短的磷光辐射寿命，以便应用于高效OLED中。

公开(公告)号：US20100258175A1

公开(公告)日：2010-10-14

申请号：US12495044

申请日：2009-06-30

申请人： Yun Chi ,  Kellen Chen ,  Yi-Huan Hong ,  Pi-Tai Chou ,  Bo-So Chen ,  Hui-Chu Hsu

发明人： Yun Chi ,  Kellen Chen ,  Yi-Huan Hong ,  Pi-Tai Chou ,  Bo-So Chen ,  Hui-Chu Hsu

IPC分类号： H01L31/00 ,  C07F15/00

CPC分类号： C07F15/0053 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549

摘要： Panchromatic photosensitizers having a Formula of ML1L2X were synthesized, wherein M comprises ruthenium atom; X is a monodentate anion; L1 is heterocyclic bidentate ligand having one of formulae listed below: wherein G2 has one of formulae listed below: and L2 is a tridentate ligand having a formula listed below: The substituents R1, R2, R3, R4, R5, R6, R7 of L1 and L2 are the same or different, and represent alkyl, alkoxy, alkylthio, alkylamino, halogenated alkyl, phenyl or substituted phenyl group, carboxylic acid or counter anion thereof, sulfonic acid or counter anion thereof, phosphoric acid or counter anion thereof, amino-group, halogens, or hydrogen. The above-mentioned photosensitizers are suitable to use as sensitizers for fabrication of high efficiency dye-sensitized solar cell.

摘要翻译： 合成具有式ML1L2X的全色光敏剂，其中M包含钌原子; X是单齿阴离子; L1是具有下列通式之一的杂环二齿配位体：其中，G2具有以下列举的化学式：L2是具有下式的三齿配位体：L1的取代基R1，R2，R3，R4，R5，R6，R7 代表烷基，烷氧基，烷硫基，烷基氨基，卤代烷基，苯基或取代的苯基，羧酸或其抗衡阴离子，磺酸或其抗衡阴离子，磷酸或其抗衡阴离子， 基团，卤素或氢。 上述光敏剂适用于制造高效染料敏化太阳能电池的敏化剂。