公开(公告)号：US4043945A

公开(公告)日：1977-08-23

申请号：US630881

申请日：1975-11-11

申请人： Yutaka Fukui ,  Fumio Hataya ,  Ryoichi Sasaki ,  Fumito Nakajima ,  Shimpei Matsuda ,  Munehiko Tonami ,  Ryo Hiraga

发明人： Yutaka Fukui ,  Fumio Hataya ,  Ryoichi Sasaki ,  Fumito Nakajima ,  Shimpei Matsuda ,  Munehiko Tonami ,  Ryo Hiraga

IPC分类号： B01J8/02 ,  B01J19/00 ,  B01J19/24 ,  B01J25/02 ,  B01J35/02 ,  C07C1/00 ,  C07C1/04 ,  C07C9/02 ,  C07C9/04 ,  C07C67/00 ,  C10K3/04 ,  C23C10/52 ,  C25D7/00 ,  B01J21/04 ,  B01J23/74

CPC分类号： B01J35/02 ,  B01J19/0013 ,  B01J25/02 ,  C07C1/0445 ,  B01J2219/00085 ,  B01J2219/00159 ,  B01J2219/00177 ,  B01J2219/00186 ,  C07C2521/02 ,  C07C2521/04

摘要： A catalyst layer is formed on the metallic surface of a structure constructing a reactor by diffusing a developable metal into the structure by the pack cementation method and developing the diffused metal. The catalyst layer is metallurgically combined with the structure, so that it has excellent mechanical strength and heat conductivity. Thus, by using the structure having the catalyst layer as a heat exchanger type methanation reactor it is possible to obtain a methanation reactor enabling an extremely enhanced rate of reaction to be obtained with superior operability and at great savings.

摘要翻译： 在构成反应器的结构的金属表面上形成催化剂层，通过包装胶结法将可显影金属扩散到结构体中并显影扩散金属。 催化剂层与结构冶金结合，具有优异的机械强度和导热性。 因此，通过使用具有催化剂层的结构作为热交换器型甲烷化反应器，可以获得甲酸化反应器，能够以优异的可操作性和极大的节省获得极高的反应速度。

公开(公告)号：US4407905A

公开(公告)日：1983-10-04

申请号：US311179

申请日：1981-10-14

申请人： Seizi Takeuchi ,  Kenzo Ishii ,  Toshiki Kahara ,  Jinichi Imahashi ,  Masato Takeuchi ,  Hideo Okada ,  Sigeru Okabe ,  Shimpei Matsuda ,  Fumito Nakajima ,  Hirosi Tobita ,  Kohki Tamura

发明人： Seizi Takeuchi ,  Kenzo Ishii ,  Toshiki Kahara ,  Jinichi Imahashi ,  Masato Takeuchi ,  Hideo Okada ,  Sigeru Okabe ,  Shimpei Matsuda ,  Fumito Nakajima ,  Hirosi Tobita ,  Kohki Tamura

IPC分类号： H01M4/90 ,  B01J27/20 ,  H01M4/86 ,  H01M4/88 ,  H01M4/92

CPC分类号： H01M4/8821 ,  H01M4/8842 ,  H01M4/92 ,  H01M2004/8689 ,  H01M2300/0005 ,  H01M2300/0008 ,  H01M4/921

摘要： Fuel cell with improved and stabilized electrode performance having at least one gas diffusion electrode, where the gas diffusion electrode comprises an electronconductive, gas-permeable substrate and an electrode catalyst uniformly distributed on the substrate, the electrode catalyst comprising colonies each consisting of not more than 20 primary particles of noble metal each having a size of 10-30 A and being uniformly distributed and deposited on carrier powder.

摘要翻译： 具有改善且稳定的电极性能的燃料电池具有至少一个气体扩散电极，其中气体扩散电极包括均匀分布在基底上的导电气体透气性基底和电极催化剂，电极催化剂包括各自由不超过 20个贵金属的一次粒子，每个具有10-30A的尺寸，并均匀分布并沉积在载体粉末上。

公开(公告)号：US4085193A

公开(公告)日：1978-04-18

申请号：US531304

申请日：1974-12-10

申请人： Fumito Nakajima ,  Masato Takeuchi ,  Shimpei Matsuda ,  Shigeo Uno ,  Toshikatsu Mori ,  Yoshihisa Watanabe ,  Makoto Imanari

发明人： Fumito Nakajima ,  Masato Takeuchi ,  Shimpei Matsuda ,  Shigeo Uno ,  Toshikatsu Mori ,  Yoshihisa Watanabe ,  Makoto Imanari

IPC分类号： B01D53/94 ,  B01J23/12 ,  B01J23/22 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/84 ,  B01J8/00 ,  C01B21/00

CPC分类号： B01J23/84 ,  B01D53/9418 ,  B01J23/12 ,  B01J23/22 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/20784

摘要： A catalyst compositions for reducing nitrogen oxide comprising, as its chief ingredient, an intimate mixture ofA. titanium (Ti) as component A, withB. at least one metal selected from the group consisting of molybdenum (Mo), tungsten (W), iron (Fe), vanadium (V), nickel (Ni), cobalt (Co), copper (Cu), chromium (Cr), and uranium (U), as component B,in the form of their oxides, and a process for reducing nitrogen oxides to nitrogen, which comprises contacting a gaseous mixture containing nitrogen oxides and molecular oxygen and a reducing gas with aforesaid catalyst compositions at an elevated temperature.

摘要翻译： 用于还原氮氧化物的催化剂组合物，其包含作为组分A的A.TiO（Ti）与B的至少一种金属作为其主要成分，所述金属选自钼（Mo），钨（W） ，作为组分B的铁（Fe），钒（V），镍（Ni），钴（Co），铜（Cu），铬（Cr）和铀（U） 将氮氧化物还原成氮的方法，其包括在升高的温度下将含有氮氧化物和分子氧的气态混合物与还原气体与上述催化剂组合物接触。

公开(公告)号：US3976745A

公开(公告)日：1976-08-24

申请号：US531309

申请日：1974-12-10

申请人： Fumito Nakajima ,  Masato Tekeuchi ,  Shimpei Matsuda ,  Shigeo Uno ,  Toshikatsu Mori ,  Yoshihisa Watanabe ,  Makoto Imanari

发明人： Fumito Nakajima ,  Masato Tekeuchi ,  Shimpei Matsuda ,  Shigeo Uno ,  Toshikatsu Mori ,  Yoshihisa Watanabe ,  Makoto Imanari

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J23/14 ,  B01J23/24 ,  B01J23/835 ,  B01D53/34

CPC分类号： B01J23/835 ,  B01D53/9418 ,  B01J23/24 ,  B01D2255/20738 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/2094

摘要： A catalyst composition for reducing nitrogen oxides, which is characterized in that the same contains, as its chief ingredient,A. tin (Sn) as the component A, andB. at least one metal selected from the group consisting of molybdenum (Mo), tungsten (W), and iron (Fe), as the component (B).in the form of their oxides, and a process for reducing nitrogen oxides to nitrogen, which comprises contacting a gaseous mixture containing nitrogen oxides and molecular oxygen and a reducing gas with aforesaid catalyst composition at elevated temperatures.

摘要翻译： 一种还原氮氧化物的催化剂组合物，其特征在于，作为其成分的主要成分为含有作为成分A的锡锡（Sn），和B.选自钼（Mo） ，钨（W）和铁（Fe）作为组分（B）。

公开(公告)号：US4187282A

公开(公告)日：1980-02-05

申请号：US767962

申请日：1977-02-11

申请人： Shimpei Matsuda ,  Akira Kato ,  Shigeo Uno ,  Fumito Nakajima

发明人： Shimpei Matsuda ,  Akira Kato ,  Shigeo Uno ,  Fumito Nakajima

IPC分类号： B01D53/02 ,  B01D53/86 ,  B01J23/72 ,  B01J23/745 ,  C01B17/60 ,  C01B17/00 ,  B01J8/00 ,  C01B17/02 ,  C01B21/00

CPC分类号： B01J23/745 ,  B01D53/02 ,  B01D53/8637 ,  B01J23/72 ,  C01B17/60

摘要： A waste gas containing sulfur oxides is contacted with an adsorbent comprising an intimate mixture of an iron oxide and/or a copper oxide and a titanium oxide at a temperature of 250.degree.-500.degree. C. The sulfur oxides thus adsorbed are desorbed with a reducing gas and recovered as sulfur material.The efficiency of the adsorbent is not reduced even after many repetitions of the adsorption-desorption cycle. Since the adsorbent exhibits a high resistance to sulfuric acid mist (SO.sub.3) contained in the waste gas.

摘要翻译： 含有硫氧化物的废气在250-500℃的温度下与包含氧化铁和/或氧化铜和氧化钛的紧密混合物的吸附剂接触。如此吸附的硫氧化物被还原 气体并作为硫材料回收。 即使在多次重复吸附 - 脱附循环之后，吸附剂的效率也不会降低。 由于吸附剂对废气中所含的硫酸雾（SO 3）具有高的耐性，

公开(公告)号：US3977836A

公开(公告)日：1976-08-31

申请号：US631198

申请日：1975-11-12

申请人： Shimpei Matsuda ,  Fumito Nakajima ,  Masato Takeuchi ,  Shigeo Uno ,  Akira Kato ,  Makoto Imanari ,  Yoshihisa Watanabe

发明人： Shimpei Matsuda ,  Fumito Nakajima ,  Masato Takeuchi ,  Shigeo Uno ,  Akira Kato ,  Makoto Imanari ,  Yoshihisa Watanabe

IPC分类号： G01N31/00 ,  G01N33/00 ,  G01N25/22 ,  G01N21/12 ,  G01N21/58

CPC分类号： G01N33/0031 ,  G01N31/005 ,  G01N33/0013 ,  Y10T436/175383 ,  Y10T436/177692

摘要： An ammonia gas to be determined, and an oxidative gas containing nitrogen oxides in moles more than those of the ammonia are brought into contact with an analytical catalyst capable of forming nitrogen and water from ammonia and nitrogen oxides.Concentrations of nitrogen oxides of the gas before and after the contact with the analytical catalyst are determined, and an ammonia concentration of the gas is determined by converting the difference between the concentrations of nitrogen oxides to the ammonia concentration by calculation.

摘要翻译： 将要测定的氨气和含有多于氨的氮氧化物的氧化气体与能够从氨和氮氧化物形成氮和水的分析催化剂接触。

公开(公告)号：US4656735A

公开(公告)日：1987-04-14

申请号：US855103

申请日：1986-04-23

申请人： Hideo Okada ,  Masato Takeuchi ,  Sigeru Okabe ,  Hiroshi Tobita ,  Shimpei Matsuda ,  Kohki Tamura ,  Fumito Nakajima

发明人： Hideo Okada ,  Masato Takeuchi ,  Sigeru Okabe ,  Hiroshi Tobita ,  Shimpei Matsuda ,  Kohki Tamura ,  Fumito Nakajima

IPC分类号： H01M8/02 ,  H01M8/14 ,  H01M2/14

CPC分类号： H01M8/142 ,  H01M8/0289 ,  H01M2008/147 ,  H01M2300/0051 ,  H01M8/0293 ,  H01M8/0295 ,  Y02E60/526 ,  Y10T29/49108 ,  Y10T29/49115

摘要： A fuel cell provided with an electrolyte retaining plate made of electrical insulating long fibers such as lithium aluminate long fibers which have preferably a length of 100 to 400 .mu.m and a diameter of 1 to 4 .mu.m, are interlocked each other and have vacant spaces for filling an electrolyte can be constructed and operated safely without damaging the electrolyte retaining plate for a long period of time.

摘要翻译： 设置有电绝缘长纤维例如铝酸锂长纤维的优选长度为100〜400μm，直径为1〜4μm的电解质保持板的燃料电池彼此互锁并具有空位 用于填充电解质的电解质可以安全地构建和操作，而不会长期损坏电解质保持板。

公开(公告)号：US4350670A

公开(公告)日：1982-09-21

申请号：US179238

申请日：1980-08-18

申请人： Shimpei Matsuda ,  Akira Kato ,  Toshikatsu Mori ,  Teruo Kumagai ,  Yukio Hishinuma ,  Hidetoshi Akimoto ,  Fumito Nakajima

发明人： Shimpei Matsuda ,  Akira Kato ,  Toshikatsu Mori ,  Teruo Kumagai ,  Yukio Hishinuma ,  Hidetoshi Akimoto ,  Fumito Nakajima

IPC分类号： B01D53/86 ,  B01J23/40 ,  C01B17/78 ,  B01J8/00 ,  C01B17/00

CPC分类号： B01J23/40 ,  B01D53/8609 ,  C01B17/78

摘要： A coal or petroleum combustion flue gas containing sulfur oxides and dust is treated by contacting the flue gas with a sulfur dioxide-oxidizing catalyst, thereby converting sulfur dioxide to sulfur trioxide, allowing the resulting sulfur trioxide to react with components of dust, absorbing the trioxide into the dust as a sulfate, and removing the dust. Catalytic oxidation of sulfur dioxide can be efficiently carried out at a low temperature and sulfur oxides can be efficiently removed from the flue gas.

摘要翻译： 通过使烟道气与二氧化硫氧化催化剂接触来处理含有硫氧化物和粉尘的煤或石油燃烧烟气，从而将二氧化硫转化成三氧化硫，使得所得三氧化硫与粉尘成分反应，吸收三氧化二 作为硫酸盐进入灰尘，并除去灰尘。 可以在低温下有效地进行二氧化硫的催化氧化，并且可以有效地从烟道气中除去硫氧化物。

公开(公告)号：US4341753A

公开(公告)日：1982-07-27

申请号：US184759

申请日：1980-09-08

申请人： Toshikatsu Mori ,  Teruo Kumagai ,  Shimpei Matsuda ,  Fumito Nakajima

发明人： Toshikatsu Mori ,  Teruo Kumagai ,  Shimpei Matsuda ,  Fumito Nakajima

IPC分类号： C01B17/04

CPC分类号： C01B17/0473 ,  C01B17/0408 ,  Y10S423/05

摘要： There is provided a method for converting sulfur dioxide in an exhaust gas to sulfur, which comprises the reduction step of reducing sulfur dioxide in an exhaust gas containing water vapor to hydrogen sulfide in the presence of carbon, a part of the exhaust gas is caused to bypass the reduction step and the remainder of the exhaust gas is fed to the reduction step to convert sulfur dioxide in the exhaust gas to hydrogen sulfide; the gas from the reduction step is mixed with the exhaust gas bypassing the reduction step while controlling the amount of the bypassing exhaust gas so that the ratio of hydrogen sulfide to sulfur dioxide in the mixed gas is maintained at 2; the mixed gas is fed to the Claus reaction step; and the Claus reaction step of reacting hydrogen sulfide formed at the reduction step with sulfur dioxide to convert hydrogen sulfide to sulfur.

摘要翻译： 提供了一种将废气中的二氧化硫转化为硫的方法，其包括在碳存在下将含有水蒸汽的废气中的二氧化硫还原为硫化氢的还原步骤，将一部分废气引起 旁路还原步骤，将剩余的废气送入还原步骤，将废气中的二氧化硫转化为硫化氢; 来自还原步骤的气体与绕过还原步骤的排气混合，同时控制旁路废气的量，使得混合气体中的硫化氢与二氧化硫的比例保持在2; 将混合气体送入Claus反应步骤; 和在还原步骤中形成的硫化氢与二氧化硫反应以将硫化氢转化为硫的Claus反应步骤。

公开(公告)号：US4138469A

公开(公告)日：1979-02-06

申请号：US781980

申请日：1977-03-28

申请人： Akira Kato ,  Shimpei Matsuda ,  Shigeo Uno ,  Jinichi Imahashi ,  Yoshihisa Watanabe ,  Makoto Imanari ,  Fumito Nakajima

发明人： Akira Kato ,  Shimpei Matsuda ,  Shigeo Uno ,  Jinichi Imahashi ,  Yoshihisa Watanabe ,  Makoto Imanari ,  Fumito Nakajima

IPC分类号： B01D53/94 ,  B01D53/86 ,  B01J23/86 ,  B01J23/88 ,  B01D53/00

CPC分类号： B01D53/8628 ,  B01D53/8634

摘要： A process for treating an exhaust gas containing nitrogen oxides, oxygen and ammonia gas with a catalyst consisting essentially of titanium oxide, copper oxide in an amount of 0.02 to 0.3 mole and molybdenum oxide or tungsten oxide in an amount of 0.01 to 0.5 mole per one mole of the titanium oxide. Because the catalyst exhibits good properties for decomposition of ammonia as well as for decomposition of nitrogen oxides it is possible to avoid secondary pollution due to unreacted ammonia.

摘要翻译： 一种用基本上由氧化钛组成的催化剂，0.02-0.3摩尔的氧化铜和0.01-0.5摩尔的氧化钼或氧化钨的催化剂来处理含有氮氧化物，氧和氨气的废气的方法 摩尔的氧化钛。 因为催化剂表现出良好的氨分解性能以及氮氧化物的分解，因此可以避免由于未反应的氨引起的二次污染。