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公开(公告)号：US09169356B2
公开(公告)日：2015-10-27
申请号：US12091350
申请日：2006-09-26
CPC分类号： C08G73/0655 , C08J5/24 , C08J2379/04
摘要： Provided is a cyanate ester polymer having excellent flame retardance, low dielectric constant, low dielectric loss tangent and high heat resistance. Specifically provided is a cyanate ester polymer obtained by polymerizing a cyanate ester compound represented by the following general formula (1). (1) In the formula, X represents OCN or OH, and 10-100% by mol of X is composed of OCN.
摘要翻译： 提供了具有优异的阻燃性，低介电常数，低介电损耗角正切和高耐热性的氰酸酯聚合物。 具体提供的是通过聚合由以下通式（1）表示的氰酸酯化合物获得的氰酸酯聚合物。 （1）式中，X表示OCN或OH，X为10〜100摩尔％。
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2.发明申请Novel cyanate ester compound, flame-retardant resin composition, and cured product thereof 审中-公开新型氰酸酯化合物，阻燃性树脂组合物及其固化物公开(公告)号：US20050182203A1
公开(公告)日：2005-08-18
申请号：US11057182
申请日：2005-02-15
申请人： Yuuichi Sugano , Masayuki Katagiri , Daisuke Ohno , Seiji Kita , Yoshikazu Shima
发明人： Yuuichi Sugano , Masayuki Katagiri , Daisuke Ohno , Seiji Kita , Yoshikazu Shima
IPC分类号： C07C261/02 , C08G73/06 , C08K5/205 , C08K5/29 , C09D5/18 , C09K21/14 , G02F1/1339 , H05K1/03 , H05K3/38 , C08L63/00
CPC分类号： C08G73/0655 , C07C261/02 , C08K5/29 , C09D5/18 , C09K21/14 , G02F1/1339 , H05K1/0346 , H05K3/386 , Y10T428/31699
摘要： A cyanate ester compound represented by the formula (1), wherein Ar2 represents a phenylene group, a naphthylene group or a biphenylene group, Ar1 represents a naphthylene group or a biphenylene group when Ar2 is a phenylene group, or Ar1 represents a phenylene group, a naphthylene group or a biphenylene group when Ar2 is a naphthylene group or a biphenylene group, Rx represents all substituents of Ar1 each Rx is the same or different and represents hydrogen, an alkyl group or an aryl group, Ry represents all substituents of Ar2, each Ry is the same or different and represents hydrogen, an alkyl group or an aryl group, and n is an integer of 1 to 50.
摘要翻译： 由式（1）表示的氰酸酯化合物，其中Ar 2表示亚苯基，亚萘基或亚联苯基，Ar 1表示亚萘基或 当Ar 2 2是亚苯基时，亚联苯基或当Ar 2为Ar 2时，Ar 1代表亚苯基，亚萘基或亚联苯基 亚萘基或亚联苯基，R x表示Ar 1的全部取代基，每个R x x相同或不同，表示氢， 烷基或芳基，R y表示Ar 2的全部取代基，每个R y相同或不同，表示氢， 烷基或芳基，n为1〜50的整数。
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3.发明授权Process for production of nucleus-hydrogenated aromatic vinyl/(meth)acrylate copolymers 有权核 - 氢化芳族乙烯基/（甲基）丙烯酸酯共聚物的生产方法公开(公告)号：US08575277B2
公开(公告)日：2013-11-05
申请号：US12672152
申请日：2008-08-04
IPC分类号： C08F8/04
CPC分类号： G11B7/2533 , B01J21/06 , B01J21/066 , B01J23/44 , B01J35/0066 , B01J37/0203 , C08F8/04 , C08F212/08 , C08F220/18 , C08F2800/10 , C08F2810/50 , C08F220/14
摘要： A safe and stable production method of a hydrogenated polymer having high transparency, which is a production method of a hydrogenated polymer by hydrogenating aromatic rings of an aromatic vinyl compound-(meth)acrylate copolymer, in which (1) a solvent solution of the copolymer is added to a reactor, which has a solvent and a supported palladium catalyst charged therein, under a hydrogen atmosphere at a rate of from 0.01 to 15 g/hour in terms of the copolymer per unit mass (g) of the supported palladium catalyst, thereby performing hydrogenation reaction, and then such an operation is performed repeatedly that (2) a hydrogenated polymer is obtained from 30 to 90% by mass of the resulting reaction mixed solution, and a fresh solvent solution of the copolymer is added to the reactor, in which the residual reaction mixed solution is left, or to which the residual reaction mixed solution is returned, at a rate of from 0.01 to 15 g/hour in terms of the copolymer per unit mass (g) of the supported palladium catalyst, thereby performing hydrogenation reaction.
摘要翻译： 通过氢化芳香族乙烯基化合物 - （甲基）丙烯酸酯共聚物的芳香环，是氢化聚合物的制造方法的高透明性的安全稳定的制造方法，其中（1）共聚物的溶剂溶液 加入到反应器中，其中，在氢气氛下，以负载的钯催化剂的单位质量（g）的共聚物为0.01〜15g /小时，加入溶剂和负载的钯催化剂， 进行氢化反应，然后重复进行这样的操作：（2）得到的反应混合溶液的氢化聚合物的质量为30〜90质量％，将共聚物的新鲜溶剂溶液加入到反应器中， 残留的反应混合溶液返回残余反应混合溶液，以每单位质量（g）的共聚物计，为0.01〜15g /小时 报告钯催化剂，从而进行氢化反应。
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公开(公告)号：US07446152B2
公开(公告)日：2008-11-04
申请号：US11374068
申请日：2006-03-14
IPC分类号： C08F8/04
CPC分类号： C08F220/14 , B01J23/40 , B01J23/755 , C08F8/04 , C08F2800/10 , C08F2810/50 , G02B1/041 , G11B7/253 , C08F212/08 , C08L33/10
摘要： In the production of a nuclear-hydrogenated polymer, the hydrogenation of an aromatic vinyl compound—(meth)acrylate copolymer is conducted in a mixed solvent comprising an ester compound and an alcohol compound in the presence of a catalyst. By this method, a highly transparent nuclear-hydrogenated polymer is produced safely, stably and quickly, even when the degree of nuclear-hydrogenation is low.
摘要翻译： 在制备核氢化聚合物中，芳族乙烯基化合物 - （甲基）丙烯酸酯共聚物的氢化在包含酯化合物和醇化合物的混合溶剂中在催化剂存在下进行。 通过该方法，即使核氢化程度低，安全，稳定，快速地制造高度透明的核氢化聚合物。
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公开(公告)号：US20070185277A1
公开(公告)日：2007-08-09
申请号：US11679222
申请日：2007-02-27
IPC分类号： C08F265/04
CPC分类号： C08F8/04 , C08F212/08
摘要： A process for producing a hydrogenated polymer, which includes a step of hydrogenating aromatic rings of an aromatic vinyl compound—(meth)acrylate copolymer. In the process, the copolymer having a ratio, A/B, of from 0.25 to 4.0 (A is a molar number of constitutional units derived from the (meth)acrylate monomer, and B is a molar number of constitutional units derived from the aromatic vinyl monomer) is hydrogenated in a solvent in the presence of a catalyst which is composed of zirconium oxide supporting palladium. By the process, a highly transparent, hydrogenated polymer is stably and rapidly produced for a long period of time or repeatedly.
摘要翻译： 一种氢化聚合物的制造方法，其包括使芳香族乙烯基化合物 - （甲基）丙烯酸酯共聚物的芳香环氢化的工序。 在该方法中，A / B比为0.25〜4.0（A为来自（甲基）丙烯酸酯单体的结构单元的摩尔数），B为衍生自芳香族化合物的结构单元的摩尔数 乙烯基单体）在溶剂中在由氧化锆担载钯组成的催化剂存在下氢化。 通过该方法，高度透明的氢化聚合物长时间或重复地稳定且快速地生产。
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公开(公告)号：US07488782B2
公开(公告)日：2009-02-10
申请号：US11679222
申请日：2007-02-27
IPC分类号： C08C19/02 , C08F220/18 , C08F12/08
CPC分类号： C08F8/04 , C08F212/08
摘要： A process for producing a hydrogenated polymer, which includes a step of hydrogenating aromatic rings of an aromatic vinyl compound—(meth)acrylate copolymer. In the process, the copolymer having a ratio, A/B, of from 0.25 to 4.0 (A is a molar number of constitutional units derived from the (meth)acrylate monomer, and B is a molar number of constitutional units derived from the aromatic vinyl monomer) is hydrogenated in a solvent in the presence of a catalyst which is composed of zirconium oxide supporting palladium. By the process, a highly transparent, hydrogenated polymer is stably and rapidly produced for a long period of time or repeatedly.
摘要翻译： 一种氢化聚合物的制造方法，其包括使芳香族乙烯基化合物 - （甲基）丙烯酸酯共聚物的芳香环氢化的工序。 在该方法中，A / B比为0.25〜4.0（A为来自（甲基）丙烯酸酯单体的结构单元的摩尔数），B为衍生自芳香族化合物的结构单元的摩尔数 乙烯基单体）在溶剂中在由氧化锆担载钯组成的催化剂存在下氢化。 通过该方法，高度透明的氢化聚合物长时间或重复地稳定且快速地生产。
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公开(公告)号：US20060205886A1
公开(公告)日：2006-09-14
申请号：US11374068
申请日：2006-03-14
IPC分类号： C08F297/00
CPC分类号： C08F220/14 , B01J23/40 , B01J23/755 , C08F8/04 , C08F2800/10 , C08F2810/50 , G02B1/041 , G11B7/253 , C08F212/08 , C08L33/10
摘要： In the production of a nuclear-hydrogenated polymer, the hydrogenation of an aromatic vinyl compound—(meth)acrylate copolymer is conducted in a mixed solvent comprising an ester compound and an alcohol compound in the presence of a catalyst. By this method, a highly transparent nuclear-hydrogenated polymer is produced safely, stably and quickly, even when the degree of nuclear-hydrogenation is low.
摘要翻译： 在制备核氢化聚合物中，芳族乙烯基化合物 - （甲基）丙烯酸酯共聚物的氢化在包含酯化合物和醇化合物的混合溶剂中在催化剂存在下进行。 通过该方法，即使核氢化程度低，安全，稳定，快速地制造高度透明的核氢化聚合物。
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公开(公告)号：US08759566B2
公开(公告)日：2014-06-24
申请号：US13259156
申请日：2010-03-30
IPC分类号： C07C69/66
CPC分类号： C07C67/20 , B01J21/02 , B01J21/066 , B01J23/02 , B01J23/06 , B01J23/10 , B01J23/14 , B01J23/18 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/72 , B01J23/74 , B01J27/0576 , B01J37/08 , C07C69/68 , C07C69/675
摘要： Provided is a process for producing α-hydroxycarboxylic esters from α-hydroxycarboxylic amides and aliphatic alcohols, wherein it is a production process which is inhibited in a production cost and enhanced in a conversion rate and a selectivity and which is industrially advantageous. To be specific, it is a production process for α-hydroxycarboxylic ester characterized by subjecting α-hydroxycarboxylic amide and aliphatic alcohol to a gas phase reaction in the presence of a zirconium dioxide catalyst. A catalyst lifetime is improved to a large extent by using a zirconium dioxide catalyst containing a specific element.
摘要翻译： 本发明提供一种由α-羟基羧酸酰胺和脂肪族醇制造α-羟基羧酸酯的方法，其为生产成本抑制的生产方法，转化率和选择性提高，在工业上具有优势。 具体而言，是在二氧化锆催化剂存在下，使α-羟基羧酸酰胺和脂肪醇进行气相反应的α-羟基羧酸酯的制造方法。 通过使用含有特定元素的二氧化锆催化剂在很大程度上改善了催化剂寿命。
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公开(公告)号：US20120095253A1
公开(公告)日：2012-04-19
申请号：US13259156
申请日：2010-03-30
IPC分类号： C07C67/20
CPC分类号： C07C67/20 , B01J21/02 , B01J21/066 , B01J23/02 , B01J23/06 , B01J23/10 , B01J23/14 , B01J23/18 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/72 , B01J23/74 , B01J27/0576 , B01J37/08 , C07C69/68 , C07C69/675
摘要： Provided is a process for producing α-hydroxycarboxylic esters from α-hydroxycarboxylic amides and aliphatic alcohols, wherein it is a production process which is inhibited in a production cost and enhanced in a conversion rate and a selectivity and which is industrially advantageous. To be specific, it is a production process for α-hydroxycarboxylic ester characterized by subjecting α-hydroxycarboxylic amide and aliphatic alcohol to a gas phase reaction in the presence of a zirconium dioxide catalyst. A catalyst lifetime is improved to a large extent by using a zirconium dioxide catalyst containing a specific element.
摘要翻译： 本发明提供一种由α-羟基羧酸酰胺和脂肪族醇制造α-羟基羧酸酯的方法，其为生产成本抑制的生产方法，转化率和选择性提高，在工业上具有优势。 具体而言，是在二氧化锆催化剂存在下，使α-羟基羧酸酰胺和脂肪醇进行气相反应的α-羟基羧酸酯的制造方法。 通过使用含有特定元素的二氧化锆催化剂在很大程度上改善了催化剂寿命。
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10.发明申请PROCESS FOR PRODUCTION OF NUCLEUS-HYDROGENATED AROMATIC VINYL/(METH)ACRYLATE COPOLYMERS 有权生产氢化羟基乙酸/（甲基）丙烯酸酯共聚物的方法公开(公告)号：US20110269912A1
公开(公告)日：2011-11-03
申请号：US12672152
申请日：2008-08-04
IPC分类号： C08F8/04 , C08F220/18
CPC分类号： G11B7/2533 , B01J21/06 , B01J21/066 , B01J23/44 , B01J35/0066 , B01J37/0203 , C08F8/04 , C08F212/08 , C08F220/18 , C08F2800/10 , C08F2810/50 , C08F220/14
摘要： A safe and stable production method of a hydrogenated polymer having high transparency, which is a production method of a hydrogenated polymer by hydrogenating aromatic rings of an aromatic vinyl compound-(meth)acrylate copolymer, in which (1) a solvent solution of the copolymer is added to a reactor, which has a solvent and a supported palladium catalyst charged therein, under a hydrogen atmosphere at a rate of from 0.01 to 15 g/hour in terms of the copolymer per unit mass (g) of the supported palladium catalyst, thereby performing hydrogenation reaction, and then such an operation is performed repeatedly that (2) a hydrogenated polymer is obtained from 30 to 90% by mass of the resulting reaction mixed solution, and a fresh solvent solution of the copolymer is added to the reactor, in which the residual reaction mixed solution is left, or to which the residual reaction mixed solution is returned, at a rate of from 0.01 to 15 g/hour in terms of the copolymer per unit mass (g) of the supported palladium catalyst, thereby performing hydrogenation reaction.
摘要翻译： 通过氢化芳香族乙烯基化合物 - （甲基）丙烯酸酯共聚物的芳香环，是氢化聚合物的制造方法的高透明性的安全稳定的制造方法，其中（1）共聚物的溶剂溶液 加入到反应器中，其中，在氢气氛下，以负载的钯催化剂的单位质量（g）的共聚物为0.01〜15g /小时，加入溶剂和负载的钯催化剂， 进行氢化反应，然后重复进行这样的操作：（2）得到的反应混合溶液的氢化聚合物的质量为30〜90质量％，将共聚物的新鲜溶剂溶液加入到反应器中， 残留的反应混合溶液返回残余反应混合溶液，以每单位质量（g）的共聚物计，为0.01〜15g /小时 报告钯催化剂，从而进行氢化反应。
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