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    Process for producing catalyst for cyanhydrin hydration and product of the process
    5.
    发明授权
    Process for producing catalyst for cyanhydrin hydration and product of the process 有权
    用于生产氰醇水合催化剂的方法和该方法的产物

    公开(公告)号：US07704917B2

    公开(公告)日：2010-04-27

    申请号：US11994629

    申请日：2006-07-06

    申请人： Hideho Matsuda ,  Takako Uchiyama ,  Yoshikazu Shima ,  Masaki Takemoto

    发明人： Hideho Matsuda ,  Takako Uchiyama ,  Yoshikazu Shima ,  Masaki Takemoto

    IPC分类号： B01J23/32 ,  C01G45/12 ,  C07C231/00

    CPC分类号： B01J23/34 ,  B01J35/1014 ,  B01J35/1042 ,  B01J35/1066 ,  B01J37/0236 ,  B01J37/03 ,  C07C231/06 ,  C07C235/06

    摘要： A process for producing a catalyst for cyanhydrin hydration, which comprises a manganese oxide as a main component and is excellent in both physical strength and reaction activity, is provided, as well as a catalyst for cyanhydrin hydration obtained by the production process. Specifically, a process for producing a catalyst which is useful for cyanhydrin hydration and contains a manganese oxide as a main component, potassium, and one or more elements selected from the group consisting of bismuth, vanadium and tin, in which the above compounds are mixed together in an aqueous system; the resulting slurry precipitate is subjected to solid-liquid separation; and the resulting hydrous cake is dried in at least two separate stages comprising a predrying and a main drying, is provided, as well as a catalyst for cyanhydrin hydration obtained by the production process.

    摘要翻译： 本发明提供一种生产氰醇水合催化剂的方法，该方法包括以氧化锰为主要成分，并具有优异的物理强度和反应活性，以及​​通过制备方法获得的氰醇水合催化剂。 具体而言，可以使用用于氰醇水合并含有氧化锰作为主要成分的催化剂的方法，钾和选自铋，钒和锡中的一种或多种元素，其中混合上述化合物 一起在水系统中; 将所得浆料沉淀物进行固液分离; 并且将所得含水饼在包括预干燥和主干燥的至少两个分开的阶段中进行干燥，以及通过生产方法获得的用于氰醇水合的催化剂。

    Process for Producing Catalyst for Cyanhydrin Hydration and Product of the Process
    6.
    发明申请
    Process for Producing Catalyst for Cyanhydrin Hydration and Product of the Process 有权
    生产氰胺水合催化剂的方法和工艺的产物

    公开(公告)号：US20090036301A1

    公开(公告)日：2009-02-05

    申请号：US11994629

    申请日：2006-07-06

    申请人： Hideho Matsuda ,  Takako Uchiyama ,  Yoshikazu Shima ,  Masaki Takemoto

    发明人： Hideho Matsuda ,  Takako Uchiyama ,  Yoshikazu Shima ,  Masaki Takemoto

    IPC分类号： B01J23/32 ,  C01G45/00

    CPC分类号： B01J23/34 ,  B01J35/1014 ,  B01J35/1042 ,  B01J35/1066 ,  B01J37/0236 ,  B01J37/03 ,  C07C231/06 ,  C07C235/06

    摘要： A process for producing a catalyst for cyanhydrin hydration, which comprises a manganese oxide as a main component and is excellent in both physical strength and reaction activity, is provided, as well as a catalyst for cyanhydrin hydration obtained by the production process. Specifically, a process for producing a catalyst which is useful for cyanhydrin hydration and contains a manganese oxide as a main component, potassium, and one or more elements selected from the group consisting of bismuth, vanadium and tin, in which the above compounds are mixed together in an aqueous system; the resulting slurry precipitate is subjected to solid-liquid separation; and the resulting hydrous cake is dried in at least two separate stages comprising a predrying and a main drying, is provided, as well as a catalyst for cyanhydrin hydration obtained by the production process.

    摘要翻译： 本发明提供一种生产氰醇水合催化剂的方法，该方法包括以氧化锰为主要成分，并具有优异的物理强度和反应活性，以及​​通过制备方法获得的氰醇水合催化剂。 具体而言，可以使用用于氰醇水合并含有氧化锰作为主要成分的催化剂的方法，钾和选自铋，钒和锡中的一种或多种元素，其中混合上述化合物 一起在水系统中; 将所得浆料沉淀物进行固液分离; 并且将所得含水饼在包括预干燥和主干燥的至少两个分开的阶段中进行干燥，以及通过生产方法获得的用于氰醇水合的催化剂。

    Process for production of nucleus-hydrogenated aromatic vinyl/(meth)acrylate copolymers
    7.
    发明授权
    Process for production of nucleus-hydrogenated aromatic vinyl/(meth)acrylate copolymers 有权
    核 - 氢化芳族乙烯基/（甲基）丙烯酸酯共聚物的生产方法

    公开(公告)号：US08575277B2

    公开(公告)日：2013-11-05

    申请号：US12672152

    申请日：2008-08-04

    申请人： Yasuhiro Kushida ,  Yuuichi Sugano ,  Tatsuya Yamauchi ,  Hideyuki Sato ,  Yoshikazu Shima

    发明人： Yasuhiro Kushida ,  Yuuichi Sugano ,  Tatsuya Yamauchi ,  Hideyuki Sato ,  Yoshikazu Shima

    IPC分类号： C08F8/04

    CPC分类号： G11B7/2533 ,  B01J21/06 ,  B01J21/066 ,  B01J23/44 ,  B01J35/0066 ,  B01J37/0203 ,  C08F8/04 ,  C08F212/08 ,  C08F220/18 ,  C08F2800/10 ,  C08F2810/50 ,  C08F220/14

    摘要： A safe and stable production method of a hydrogenated polymer having high transparency, which is a production method of a hydrogenated polymer by hydrogenating aromatic rings of an aromatic vinyl compound-(meth)acrylate copolymer, in which (1) a solvent solution of the copolymer is added to a reactor, which has a solvent and a supported palladium catalyst charged therein, under a hydrogen atmosphere at a rate of from 0.01 to 15 g/hour in terms of the copolymer per unit mass (g) of the supported palladium catalyst, thereby performing hydrogenation reaction, and then such an operation is performed repeatedly that (2) a hydrogenated polymer is obtained from 30 to 90% by mass of the resulting reaction mixed solution, and a fresh solvent solution of the copolymer is added to the reactor, in which the residual reaction mixed solution is left, or to which the residual reaction mixed solution is returned, at a rate of from 0.01 to 15 g/hour in terms of the copolymer per unit mass (g) of the supported palladium catalyst, thereby performing hydrogenation reaction.

    摘要翻译： 通过氢化芳香族乙烯基化合物 - （甲基）丙烯酸酯共聚物的芳香环，是氢化聚合物的制造方法的高透明性的安全稳定的制造方法，其中（1）共聚物的溶剂溶液 加入到反应器中，其中，在氢气氛下，以负载的钯催化剂的单位质量（g）的共聚物为0.01〜15g /小时，加入溶剂和负载的钯催化剂， 进行氢化反应，然后重复进行这样的操作：（2）得到的反应混合溶液的氢化聚合物的质量为30〜90质量％，将共聚物的新鲜溶剂溶液加入到反应器中， 残留的反应混合溶液返回残余反应混合溶液，以每单位质量（g）的共聚物计，为0.01〜15g /小时 报告钯催化剂，从而进行氢化反应。

    PROCESS FOR PRODUCING HYDROGENATED POLYMERS
    9.
    发明申请
    PROCESS FOR PRODUCING HYDROGENATED POLYMERS 有权
    生产氢化聚合物的方法

    公开(公告)号：US20070185277A1

    公开(公告)日：2007-08-09

    申请号：US11679222

    申请日：2007-02-27

    申请人： Yuuichi Sugano ,  Yasuhiro Kushida ,  Tatsuya Yamauchi ,  Hideyuki Sato ,  Yoshikazu Shima

    发明人： Yuuichi Sugano ,  Yasuhiro Kushida ,  Tatsuya Yamauchi ,  Hideyuki Sato ,  Yoshikazu Shima

    IPC分类号： C08F265/04

    CPC分类号： C08F8/04 ,  C08F212/08

    摘要： A process for producing a hydrogenated polymer, which includes a step of hydrogenating aromatic rings of an aromatic vinyl compound—(meth)acrylate copolymer. In the process, the copolymer having a ratio, A/B, of from 0.25 to 4.0 (A is a molar number of constitutional units derived from the (meth)acrylate monomer, and B is a molar number of constitutional units derived from the aromatic vinyl monomer) is hydrogenated in a solvent in the presence of a catalyst which is composed of zirconium oxide supporting palladium. By the process, a highly transparent, hydrogenated polymer is stably and rapidly produced for a long period of time or repeatedly.

    摘要翻译： 一种氢化聚合物的制造方法，其包括使芳香族乙烯基化合物 - （甲基）丙烯酸酯共聚物的芳香环氢化的工序。 在该方法中，A / B比为0.25〜4.0（A为来自（甲基）丙烯酸酯单体的结构单元的摩尔数），B为衍生自芳香族化合物的结构单元的摩尔数 乙烯基单体）在溶剂中在由氧化锆担载钯组成的催化剂存在下氢化。 通过该方法，高度透明的氢化聚合物长时间或重复地稳定且快速地生产。