摘要:
Hydrogen-producing assemblies, fuel cell systems including the same, methods of producing hydrogen gas, and methods of powering an energy-consuming device. Hydrogen-producing assemblies may include a monolithic body that defines at least a reforming conduit, and in some embodiments a plurality of reforming conduits, in which a feed stream is catalyzed into a reformate gas stream containing hydrogen gas, and a burner conduit, in which a fuel-air stream is combusted. The monolithic body is constructed to conduct heat generated by the exothermic reaction of the combustion from the burner conduit to the reformer conduit. In some hydrogen-producing assemblies, the monolithic body further defines a vaporizing conduit, in which liquid portions of the feed stream are vaporized prior to being delivered to the reformer conduit, and the monolithic body may be constructed to conduct heat from the burner conduit to the vaporizing conduit.
摘要:
Hydrogen-producing assemblies, fuel cell systems including the same, methods of producing hydrogen gas, and methods of powering an energy-consuming device. Hydrogen-producing assemblies may include a monolithic body that defines at least a reforming conduit, and in some embodiments a plurality of reforming conduits, in which a feed stream is catalyzed into a reformate gas stream containing hydrogen gas, and a burner conduit, in which a fuel-air stream is combusted. The monolithic body is constructed to conduct heat generated by the exothermic reaction of the combustion from the burner conduit to the reformer conduit. In some hydrogen-producing assemblies, the monolithic body further defines a vaporizing conduit, in which liquid portions of the feed stream are vaporized prior to being delivered to the reformer conduit, and the monolithic body may be constructed to conduct heat from the burner conduit to the vaporizing conduit.
摘要:
Hydrogen-producing assemblies, fuel cell systems including the same, methods of producing hydrogen gas, and methods of powering an energy-consuming device. Hydrogen-producing assemblies may include a monolithic body that defines at least a reforming conduit, in which a feed stream is catalyzed into a reformate gas stream containing hydrogen gas, and a burner conduit, in which a fuel-air stream is combusted. The monolithic body is constructed to conduct heat generated by the exothermic reaction of the combustion from the burner conduit to the reformer conduit. In some hydrogen-producing assemblies, the monolithic body further defines a vaporizer conduit, in which liquid portions of the feed stream are vaporized prior to being delivered to the reformer conduit. In such embodiments, the monolithic body is constructed to conduct heat from the burner conduit to the vaporizer conduit. Hydrogen-producing assemblies may be incorporated into a fuel cell system that is configured to power an energy-consuming device.
摘要:
Methanol steam reforming catalysts, and steam reformers and fuel cell systems incorporating the same. In some embodiments, the methanol steam reforming catalyst includes zinc oxide as an active component. In some embodiments, the methanol steam reforming catalyst further includes at least one of chromium oxide and calcium aluminate. In some embodiments, the methanol steam reforming catalyst is not pyrophoric. Similarly, in some embodiments, steam reformers including a reforming catalyst according to the present disclosure may include an air-permeable or air-accessible reforming catalyst bed. In some embodiments, the methanol steam reforming catalyst is not reduced during use. In some embodiments, the methanol reforming catalysts are not active at temperatures below 275° C. In some embodiments, the methanol steam reforming catalyst includes a sulfur-absorbent material. Steam reformers, reforming systems, fuel cell systems and methods of using the reforming catalysts are also disclosed.
摘要:
Systems and methods for producing hydrogen gas with a fuel processing system that includes a hydrogen-producing region that produces hydrogen gas from a feed stream and a heating assembly that consumes a fuel stream to produce a heated exhaust stream for heating the hydrogen-producing region. In some embodiments, the heating assembly heats the hydrogen-producing region to at least a minimum hydrogen-producing temperature. In some embodiments, the rate at which an air stream is delivered to the heating assembly is controlled to selectively increase or decrease the temperature of the heated exhaust stream. In some embodiments, the feed stream and the fuel stream both contain a carbon-containing feedstock and at least 25 wt % water. In some embodiments, the feed and fuel streams have the same composition.
摘要:
Systems and methods for producing hydrogen gas with a fuel processing system that includes a hydrogen-producing region that produces hydrogen gas from a feed stream and a heating assembly that consumes a fuel stream to produce a heated exhaust stream for heating the hydrogen-producing region. In some embodiments, the heating assembly heats the hydrogen-producing region to at least a minimum hydrogen-producing temperature. In some embodiments, the feed stream and the fuel stream both contain a carbon-containing feedstock and at least 25 wt % water. In some embodiments, at least one of the feed and fuel streams contain at least one additional component. In some embodiments, the feed and fuel streams have the same composition. In some embodiments, the feed and fuel streams are drawn or obtained from a common source or supply, and in some embodiments as a liquid stream that is selectively apportioned to form the feed and fuel streams.
摘要:
Methanol steam reforming catalysts, and steam reformers and fuel cell systems incorporating the same. In some embodiments, the methanol steam reforming catalyst includes zinc oxide as an active component. In some embodiments, the methanol steam reforming catalyst further includes at least one of chromium oxide and calcium aluminate. In some embodiments, the methanol steam reforming catalyst is not pyrophoric. Similarly, in some embodiments, steam reformers including a reforming catalyst according to the present disclosure may include an air-permeable or air-accessible reforming catalyst bed. In some embodiments, the methanol steam reforming catalyst is not reduced during use. In some embodiments, the methanol reforming catalysts are not active at temperatures below 275° C. In some embodiments, the methanol steam reforming catalyst includes a sulfur-absorbent material. Steam reformers, reforming systems, fuel cell systems and methods of using the reforming catalysts are also disclosed.
摘要:
Systems and methods for producing hydrogen gas with a fuel processing system that includes a hydrogen-producing region that produces hydrogen gas from a feed stream and a heating assembly that consumes a fuel stream to produce a heated exhaust stream for heating the hydrogen-producing region. In some embodiments, the heating assembly heats the hydrogen-producing region to at least a minimum hydrogen-producing temperature. In some embodiments, the feed stream and the fuel stream both contain a carbon-containing feedstock and at least 25 wt % water. In some embodiments, at least one of the feed and fuel streams contain at least one additional component. In some embodiments, the feed and fuel streams have the same composition. In some embodiments, the feed and fuel streams are drawn or obtained from a common source or supply, and in some embodiments as a liquid stream that is selectively apportioned to form the feed and fuel streams.
摘要:
PSA assemblies with at least one energy recovery assembly, as well as hydrogen-generation assemblies and/or fuel cell systems containing the same, and methods of operating the same. The energy recovery assemblies are configured to recover mechanical energy from the product hydrogen stream and to apply the recovered mechanical energy to one or more components of the PSA assembly, the hydrogen-generation assembly, and/or the energy producing system. In some embodiments, the energy recovery assembly includes a gas motor configured to recover mechanical energy from the product hydrogen stream produced by the PSA assembly. In some embodiments, the gas motor operates among a plurality of operating states based, at least in part, on the pressure of the product hydrogen stream. In some embodiments, the energy recovery assembly is configured to apply the recovered mechanical energy to at least a vacuum pump.
摘要:
Pressure swing adsorption (PSA) assemblies with optimized startup times, as well as to hydrogen-generation assemblies and/or fuel cell systems containing the same, and methods of operating the same. Startup and shutdown methods for a PSA assembly, and optionally an associated fuel processing system, are disclosed to provide for shortened startup times. The PSA assemblies may be in fluid communication with a hydrogen source that may be used or otherwise configured or controlled to purge the PSA adsorbent columns of adsorbents during startup and/or shutdown procedures, the hydrogen source additionally or alternatively may be used or otherwise configured or controlled to charge the columns with hydrogen for idling in a pressurized state. The use of this hydrogen source, together with specific startup and shutdown methodologies, provides for reducing the startup time of the PSA assembly.