公开(公告)号：US08394263B2

公开(公告)日：2013-03-12

申请号：US12091327

申请日：2006-10-25

Applicant: Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Stuart Leon Soled ,  Sabato Miseo

Inventor： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Stuart Leon Soled ,  Sabato Miseo

IPC: B01J23/755

CPC classification number: B01J37/20 ,  B01J23/85 ,  B01J23/8885 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/10 ,  C10G45/08 ,  C10G2300/202

Abstract: The invention relates to a bulk catalyst having improved activity in hydrodesulphurization, in particular in relatively low Group VIII over Group VIB metal molar ratios. The bulk catalyst comprises metal oxidic particles comprising one or more Group VIB metals and one or more-Group VIII metals which metal oxidic particles are obtainable by a process comprising the steps of reacting the compounds comprising one or more Group VIB metals and compounds comprising one or more Group VIII metals in hydrothermal conditions at a reaction temperature above the boiling temperature of the protic liquid, preferably in an autoclave at a reaction pressure above atmospheric pressure and. The invention also relates to the corresponding sulphided catalyst, to a process for the manufacture of said bulk catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurization and hydrodenitrogenation of hydrocarbon feedstock.

Abstract translation: 本发明涉及具有改进的加氢脱硫活性的本体催化剂，特别是在VIB族金属摩尔比相对较低的第VIII族。 本体催化剂包含包含一种或多种VIB族金属和一种或多种VIII族金属的金属氧化物颗粒，该金属氧化物颗粒可通过包括以下步骤的方法获得，所述方法包括使包含一种或多种VIB族金属的化合物与包含一种或多种 反应温度高于质子液体沸点温度的水热条件下，优选在反应压力高于大气压的高压釜中。 本发明还涉及相应的硫化催化剂，制备所述本体催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。

公开(公告)号：US20100193399A1

公开(公告)日：2010-08-05

申请号：US12158982

申请日：2006-12-22

Applicant: Paul O'connor ,  King Yen Yung ,  Avelino Corma Canos ,  Elbert Arjan De Graaf ,  Erja Päivi Helena Rautiainen

Inventor： Paul O'connor ,  King Yen Yung ,  Avelino Corma Canos ,  Elbert Arjan De Graaf ,  Erja Päivi Helena Rautiainen

IPC: C10G11/04 ,  B01J21/06 ,  C10G51/00 ,  C10L1/04

CPC classification number: C10G11/04 ,  B01J21/16 ,  B01J23/007 ,  B01J27/16 ,  B01J27/1804 ,  B01J27/1808 ,  B01J27/236 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4093 ,  C10G2400/02

Abstract: Novel catalytic compositions for cracking of crude oil fractions are disclosed. The catalytic compositions comprise a basic material. When used in a cracking process, preferably a FCC process, the resulting LCO and HCO fractions have desirably low aromatics levels. Further disclosed is a one-stage FCC process using the catalytic composition of the invention. Also disclosed is a two-stage FCC process for maximizing the LCO yield.

Abstract translation: 公开了用于裂解原油馏分的新型催化组合物。 催化组合物包含基本材料。 当用于裂化过程，优选FCC方法时，所得到的LCO和HCO馏分具有期望的低芳烃含量。 进一步公开了使用本发明的催化剂组合物的一级FCC方法。 还公开了用于最大化LCO产率的两阶段FCC方法。

公开(公告)号：US20090050529A1

公开(公告)日：2009-02-26

申请号：US12135399

申请日：2008-06-09

Applicant: Darrell Ray Rainer ,  Jorge Alberto Gonzalez

Inventor： Darrell Ray Rainer ,  Jorge Alberto Gonzalez

IPC: C10G11/04 ,  B01J21/16

CPC classification number: C10G11/02 ,  C10G11/04 ,  C10G11/182

Abstract: Compositions suitable for use in FCC processes are provided that are capable of providing improved CO oxidation promotion activity along with NOx emission control. Generally, compositions are provided for promoting CO oxidation in FCC processes, wherein the compositions contain (i) a basic material support, (ii) at least one oxide of a lanthanide series element, (iii), optionally, at least one oxide of a transition metal selected from Groups Ib and IIb of the Periodic Table and (iv) at least one precious metal. The basic material support is preferably a hydrotalcite-like compound.

Abstract translation: 提供适用于FCC方法的组合物，其能够提供改进的CO氧化促进活性以及NOx排放控制。 通常，提供用于在FCC方法中促进CO氧化的组合物，其中组合物包含（i）碱性材料载体，（ii）镧系元素的至少一种氧化物，（iii）任选的至少一种氧化物 选自元素周期表Ib和IIb族的过渡金属和（iv）至少一种贵金属。 基本材料载体优选为类水滑石化合物。

公开(公告)号：US20090014356A1

公开(公告)日：2009-01-15

申请号：US12091362

申请日：2006-10-25

Applicant: Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Johannes Cornelis Sitters ,  Marinus Bruce Cerfontain ,  Bob Gerardus Oogjen

Inventor： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Johannes Cornelis Sitters ,  Marinus Bruce Cerfontain ,  Bob Gerardus Oogjen

IPC: C10G45/00

CPC classification number: B01J23/85 ,  B01J23/002 ,  B01J23/881 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0027 ,  B01J37/04 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/04 ,  C10G45/08 ,  C10G45/50 ,  C10G45/60 ,  C10G47/02 ,  C10G47/04 ,  C10G2300/202 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

Abstract: The invention relates to a process for the preparation of a shaped bulk catalyst comprising metal oxide particles comprising one or more Group VIII metals and two or more Group VIB metals which process comprises the steps of providing first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals, providing separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, combining the first and second metal oxidic particles before and/or during shaping and shaping the combined first and second metal oxide particles to form a shaped bulk catalyst. The invention further relates to the shaped bulk catalyst obtainable with the process In sulphided or unsulphided form and the use thereof in hydroprocessing.

Abstract translation: 本发明涉及一种制备成形体积催化剂的方法，其包括包含一种或多种第VIII族金属和两种或更多种VIB族金属的金属氧化物颗粒，其包括以下步骤：提供第一金属氧化物颗粒，其包含一个或多个第一VIII族 金属和一种或多种第一族VIB金属，提供单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属中的VIB族和第VIII族金属的组成 氧化颗粒是不同的，在第一和第二金属氧化物颗粒的成形和成形之前和/或之间组合第一和第二金属氧化物颗粒以形成成型的本体催化剂。 本发明还涉及通过硫化或未硫化形式的方法获得的成型体催化剂及其在加氢处理中的用途。

公开(公告)号：US20080146436A1

公开(公告)日：2008-06-19

申请号：US11939413

申请日：2007-11-13

Applicant: MONIQUE VAN DER ZON ,  Jan Hendrik Hilgers

Inventor： MONIQUE VAN DER ZON ,  Jan Hendrik Hilgers

IPC: B01J29/06

CPC classification number: B01J29/06 ,  B01J29/084 ,  B01J37/0045 ,  B01J2229/42 ,  C10G11/05

Abstract: This invention relates to a process for the preparation of a fluid catalytic cracking catalyst with improved attrition resistance. According to this preparation process, an aqueous slurry comprising a zeolite, day, and poly aluminum chloride is spray-dried and subsequently calcined, the poly aluminum chloride having the formula [Al2(OH)yCl6-y]x, wherein x is at least 1 and y is greater than 2 and smaller than 4.

Abstract translation: 本发明涉及一种制备具有改善的耐磨性的流化催化裂化催化剂的方法。 根据该制备方法，将包含沸石，天和聚氯化铝的含水浆料喷雾干燥并随后煅烧，具有式[Al 2（OH） 其中x至少为1且y大于2且小于4。

公开(公告)号：US07217400B2

公开(公告)日：2007-05-15

申请号：US10642893

申请日：2003-08-18

Applicant: Edgar Evert Steenwinkel ,  Johannes Petrus Jozef Verlaan ,  Marieke Paulyne Renate Spee ,  Erik Jeroen Laheij ,  Paul O'Connor ,  Dennis Stamires

Inventor： Edgar Evert Steenwinkel ,  Johannes Petrus Jozef Verlaan ,  Marieke Paulyne Renate Spee ,  Erik Jeroen Laheij ,  Paul O'Connor ,  Dennis Stamires

IPC: C01G1/00 ,  C01G49/00

CPC classification number: C01G49/0063 ,  C01G49/0018 ,  C01G49/0054 ,  C01G49/02 ,  C01G49/06 ,  C01P2002/54 ,  C01P2006/12

Abstract: An apparatus and continuous process for the conversion of one solid iron compound to another solid iron compound in a heterogeneous suspension wherein the suspension is formed by dispersing a solid starting iron compound in a liquid that is continuously fed through one or more agitated conversion vessels under hydrothermal conditions and converted to a solid product iron compound having different physical, chemical, or structural properties from the solid starting iron compound.

Abstract translation: 一种用于在非均相悬浮液中将一种固体铁化合物转化成另一种固体铁化合物的装置和连续方法，其中悬浮液通过将固体起始铁化合物分散在液体中而形成，该液体通过一个或多个搅拌转化容器在水热 转化成具有与固体起始铁化合物不同的物理，化学或结构特性的固体产物铁化合物。

公开(公告)号：US09534177B2

公开(公告)日：2017-01-03

申请号：US13172149

申请日：2011-06-29

Applicant: Scott Michael Babitz

Inventor： Scott Michael Babitz

IPC: B01J29/06 ,  B01J37/00 ,  C10G2/00 ,  B01D53/94 ,  B01J29/08 ,  C01B3/02 ,  C10G1/08 ,  C10G11/05 ,  C10G29/20 ,  C10G35/06 ,  C10G49/02 ,  B01J35/00

CPC classification number: C10G2/33 ,  B01D53/94 ,  B01J29/06 ,  B01J29/084 ,  B01J35/002 ,  B01J37/0045 ,  B01J2229/42 ,  C01B3/02 ,  C01B2203/1041 ,  C10G1/086 ,  C10G11/05 ,  C10G29/205 ,  C10G35/06 ,  C10G49/02

Abstract: Process for the preparation of a catalyst comprising the steps of (a) preparing a slurry comprising clay, zeolite, and quasi-crystalline boehmite, provided that the slurry does not comprise peptized quasi-crystalline boehmite, (b) adding a monovalent acid to the slurry, (c) adding a silicon source to the slurry, and (d) shaping the slurry to form particles. This process leads to a catalyst with high accessibility and high attrition resistance.

Abstract translation: 制备催化剂的方法包括以下步骤：（a）制备包含粘土，沸石和准结晶勃姆石的浆料，条件是浆料不包含胶溶的准晶勃姆石，（b）向 浆料，（c）向浆料中加入硅源，和（d）使浆料成形以形成颗粒。 该方法导致具有高可接近性和高抗磨性的催化剂。

公开(公告)号：US08884085B2

公开(公告)日：2014-11-11

申请号：US12064066

申请日：2006-08-16

Applicant: Franciscus Edwin Van Rooijen ,  Arie De Bruijn ,  Jelle Johan Nieuwland

Inventor： Franciscus Edwin Van Rooijen ,  Arie De Bruijn ,  Jelle Johan Nieuwland

IPC: C07C17/00 ,  B01J8/18 ,  B01J8/34 ,  C07C17/156 ,  B01J8/00 ,  B01J27/122 ,  B01J27/138 ,  B01J27/128 ,  B01J23/83

CPC classification number: B01J27/122 ,  B01J8/0055 ,  B01J8/1872 ,  B01J8/34 ,  B01J23/83 ,  B01J27/128 ,  B01J27/138 ,  B01J2208/00061 ,  B01J2208/00176 ,  B01J2208/00407 ,  B01J2208/00415 ,  B01J2208/0053 ,  B01J2208/00548 ,  B01J2208/00681 ,  B01J2208/0084 ,  C07C17/156 ,  C07C19/045

Abstract: A process is disclosed for the catalytic oxychlorination of an olefin. In the process a feed containing the olefin, O2 and HCl is contacted with an oxychlorination catalyst. The O2/2HCl ratio in the feed is in the range of from 0.50 to 0.58. Catalyst compositions for use in the oxychlorination reaction, in particular the oxychlorination of ethylene, are also disclosed. The catalyst compositions are in the form of particles suitable for use in fluid bed reactors, in particular baffled fluid bed reactors. Preferred catalyst materials comprise from 5.5 wt % to 14 wt % Cu. They may further comprise an earth alkali metal, such as Mg, and/or a rare earth metal. Preferred compositions contain less than 1 wt % of an alkali metal, which preferably is K.

Abstract translation: 公开了用于烯烃的催化氧氯化的方法。 在该方法中，将含有烯烃，O 2和HCl的进料与氧氯化催化剂接触。 进料中的O2 / 2HCl比在0.50至0.58的范围内。 还公开了用于氧氯化反应的催化剂组合物，特别是乙烯的氧氯化。 催化剂组合物是适用于流化床反应器，特别是挡板流化床反应器的颗粒形式。 优选的催化剂材料包含5.5重量％至14重量％的Cu。 它们还可以包含碱土金属如Mg和/或稀土金属。 优选的组合物含有少于1重量％的碱金属，其优选为K.

公开(公告)号：US08795392B2

公开(公告)日：2014-08-05

申请号：US11911168

申请日：2007-06-06

Applicant: Eelko Brevoord ,  Robertus Leliveld ,  Stephan Janbroers

Inventor： Eelko Brevoord ,  Robertus Leliveld ,  Stephan Janbroers

IPC: C10L1/188

CPC classification number: B01J23/85 ,  B01J23/883 ,  B01J35/0026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/1011 ,  C10G2300/207 ,  C10G2300/4018 ,  C11C3/123 ,  Y02P30/20

Abstract: A method for the hydrodeoxygenation of an oxygenate feedstock comprising contacting the feedstock with a sulphided catalyst composition under hydrodeoxygenation conditions, wherein the catalyst composition comprises: i) a porous carrier substantially comprised of alumina, the carrier comprising between about 0.001 and about 1 wt. % phosphorous and between about 0.001 and about 1 wt. % silicon (both calculated as oxides) and having a mean pore diameter in the range from about 5 nm to about 40 nm; and, ii) from about 1 to about 20 wt. % of an active metal component (calculated as oxides based on the weight of the composition) borne on said porous carrier and which comprises at least one Group VIB metal and at least one Group VIII metal.

Abstract translation: 一种用于含氧化合物原料的加氢脱氧的方法，包括在加氢脱氧条件下使原料与硫化催化剂组合物接触，其中催化剂组合物包含：i）基本上由氧化铝组成的多孔载体，载体包含约0.001至约1wt。 ％磷，约0.001至约1wt。 ％硅（均计算为氧化物），平均孔径在约5nm至约40nm的范围内; 和，ii）约1至约20wt。 ％的活性金属组分（以基于组合物重量的氧化物计算）承载在所述多孔载体上，并且包含至少一种VIB族金属和至少一种第Ⅷ族金属。

公开(公告)号：US20130337996A1

公开(公告)日：2013-12-19

申请号：US13911842

申请日：2013-06-06

Applicant: Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Paul Joseph Maria Lebens ,  Frans Lodewijk Plantenga ,  Bob Gerardus Oogjen ,  Henk Jan Tromp ,  Stuart Leon Soled ,  Sabato Miseo

Inventor： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Paul Joseph Maria Lebens ,  Frans Lodewijk Plantenga ,  Bob Gerardus Oogjen ,  Henk Jan Tromp ,  Stuart Leon Soled ,  Sabato Miseo

IPC: B01J23/888

CPC classification number: B01J23/8885 ,  B01J21/16 ,  B01J23/85 ,  B01J23/888 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/20 ,  C10G49/04

Abstract: The invention relates to a process for preparing bulk metal oxide particles comprising the steps of combining in a reaction mixture (i) dispersible nanoparticles having a dimension of less than about 1 μm upon being dispersed in a liquid, (ii) at least one Group VIII non-noble metal compound, (iii) at least one Group VIB metal compound, and (iv) a protic liquid; and reacting the at least one Group VIII non-noble metal compound and the at least one Group VIB metal in the presence of the nanoparticles. It also relates to bulk metal hydroprocessing catalysts obtainable by such method.

Abstract translation: 本发明涉及一种制备本体金属氧化物颗粒的方法，包括以下步骤：在反应混合物（i）分散在液体中时具有小于约1m的尺寸的可分散纳米颗粒，（ii）至少一种VIII族 非贵金属化合物，（iii）至少一种VIB族金属化合物，和（iv）质子液体; 并在所述纳米颗粒存在下使所述至少一种第VIII族非贵金属化合物和所述至少一种第ⅥB族金属反应。 它还涉及通过这种方法获得的散装金属加氢处理催化剂。