摘要:
A fluorescent mono-, di-, or tri- or tetramide between an amino acid of the formula ##STR1## and a carboxy containing tetrapyrrole of the formula: ##STR2## or the corresponding di or tetrahydrotetrapyrroles. The compounds herein are useful for the photodetection and phototreatment of tumors and/or cancerous tissues in animal hosts.
摘要:
A method for producing .alpha.-(p-isobutylphenyl)propionic acid or its alkyl esters which is characterized in that starting materials are inexpensive, processes are easy to be done and products are highly pure. The method comprises the steps of (I): catalytically cracking 1,1-bis(p-isobutylphenyl)ethane at temperatures in the range of 200.degree. to 650.degree. C. in the presence of a protonic acid catalyst and/or a solid acid catalyst to produce isobutylbenzene and p-isobutylstyrene; and (II): reacting said p-isobutylstyrene with carbon monoxide and water or alcohol at temperatures in the range of 40.degree. to 150.degree. C. in the presence of a metal complex carbonylation catalyst to produce .alpha.-(p-isobutylphenyl)propionic acid or its alkyl ester; or (III): reacting said p-isobutylstyrene with carbon monoxide and hydrogen at temperatures in the range of 40.degree. to 150.degree. C. in the presence of a metal complex carbonylation catalyst to produce .alpha.-(p-isobutylphenyl)propionaldehyde and then oxidizing said .alpha.-(p-isobutylphenyl)propionaldehyde to produce .alpha.-(p-isobutylphenyl)propionic acid. The recovered isobutylene is recycled to produce 1,1-bis(p-isobutylphenyl)ethane by reaction with acetaldehyde in the presence of sulfuric acid.
摘要:
A process for producing a solvent for use in microcapsules for pressure-sensitive copying paper which comprises hydrogenating a hydrocarbon mixture with a boiling range of 290.degree. - 400.degree. C, which is obtained as a by-product in the decomposition of petroleum etc. and is containing polycyclic aromatic hydrocarbon compounds, at a temperature within a range of 100.degree. - 400.degree. C and in the presence of a hydrogenating catalyst capable of catalyzing nuclear hydrogenation so as to hydrogenate the aromatic rings of the compounds which contain at least three aromatic rings and are principal components of said polycyclic hydrocarbon compounds, leaving at least two aromatic rings therein intact.
摘要:
A reinforced hydroentangled nonwoven fabric having small thickness and weight, draping characteristics and flexibility, and improved balance of longitudinal and transverse strength, and more particularly a thin, light-weight, reinforced, hydroentangled nonwoven fabric (9) obtained by entangling the fiber of a reinforcing support base (2) or the fiber of a fiber web laminated on the fiber of the support base (2) with the support base (2) and uniting them by ejecting high-pressure thin water jet streams (5a, 5b) against these materials, characterized in that the reinforcing support base (2) comprises a stretched unidirectionally oriented nonwoven fabric obtained by stretching a nonwoven fabric of long fiber, which is produced by spinning a thermoplastic resin, in the direction with the fiber oriented substantially in one direction, or stretched, crossed, laminated, nonwoven fabric obtained by cross-laminating the stretched unidirectionally oriented nonwoven fabric; and a method of producing the same.
摘要:
The invention provides a nonwoven fabric of stretched filaments of different kind polymers, having a strength equal to that of a woven fabric and features including an elongation, a uniformity, good feeling, a bulkiness and a thinness, characterized in that the nonwoven fabric is provided with stretched filament webs comprising long filaments formed out of a plural kinds of thermoplastic polymers of different properties, the long filaments as a whole being aligned in one direction, and a method for manufacturing the same. The invention provides also a nonwoven fabric of stretched filaments having a high strength as well as a high bulkiness and comprising different kind polymers which is provided with a first web layer of crimped filaments and a second web layer of substantially non-crimped, stretched long filaments, and a method for manufacturing the same.
摘要:
The invention provides a nonwoven fabric of stretched filaments of different kind polymers, having a strength equal to that of a woven fabric and features including an elongation, a uniformity, good feeling, a bulkiness and a thinness, characterized in that the nonwoven fabric is provided with stretched filament webs comprising long filaments formed out of a plural kinds of thermoplastic polymers of different properties, the long filaments as a whole being aligned in one direction, and a method for manufacturing the same. The invention provides also a nonwoven fabric of stretched filaments having a high strength as well as a high bulkiness and comprising different kind polymers which is provided with a first web layer of crimped filaments and a second web layer of substantially non-crimped, stretched long filaments, and a method for manufacturing the same.
摘要:
Disclosed herein is a fibrillated weatherproof web having a network structure, which can be produced with ease and is economical. The web comprises a multilayer composite film composed of at least two layers, one being a first layer (I) made of a first thermoplastic resin and the other a second layer (II) made of a second thermoplastic resin having a melting point lower than the first thermoplastic resin and containing at least 300 ppm of a light resistance imparting agent. A number of slits have been formed in a longitudinal or transverse direction. The web has been oriented at a draw ratio in a range of from 1.1 to 15 times. A nonwoven fabric making use of one or more fibrillated webs of the above sort and processes for the production of the web and nonwoven fabric are also disclosed.
摘要:
Novel compounds of 1,2-di(isobutylphenyl)ethane and 1,2-di(isobutylphenyl)ethylene, method for producing the same and method for preparing 4-isobutylstyrene and .alpha.-(4-isobutylphenyl)propionic acid from any of these compounds. In the preparation of 4-isobutylstyrene from the former two compounds by cracking or disproportionation, the components in the resultant reaction mixture can be separated without difficulty, the formation of by-product isobutylbenzene can be avoided, and the remaining unreacted starting material can be reused for the same reaction without causing any adverse effect on a catalyst.
摘要:
An improved electrical insulating oil and oil-filled electrical appliances impregnated therewith. The electrical insulating oil can be produced inexpensively but has excellent electrical characteristics and it comprises a fraction having boiling points in the range of 350.degree. to 450.degree. C. that is prepared by disproportionating diarylalkane or a hydrocarbon mixture mainly containing the same at temperatures in the range of 20.degree. to 500.degree. C. in the presence of a disproportionation catalyst, said diarylalkane having boiling points in the range of 260.degree. to 320.degree. C.
摘要:
An electrical insulating oil composition which is characterized in that said insulating oil composition contains 5 to 300 ppm (as sulfur) of sulfur compounds and exerts excellent deterioration resistance when the insulating oil composition is fed through or used in contact with a substance made of lead or a lead alloy.