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公开(公告)号：US08263517B2
公开(公告)日：2012-09-11
申请号：US12316978
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Madhav Acharya , Michael A. Daage , Darden Sinclair , Jocelyn A. Kowalski , Jose G. Santiesteban , Ajit B. Dandekar
发明人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Madhav Acharya , Michael A. Daage , Darden Sinclair , Jocelyn A. Kowalski , Jose G. Santiesteban , Ajit B. Dandekar
IPC分类号： B01J29/06
CPC分类号： B01J37/0009 , B01J21/04 , B01J21/063 , B01J21/066 , B01J21/08 , B01J29/068 , B01J29/7261 , B01J29/7292 , B01J29/7461 , B01J29/7492 , B01J29/7861 , B01J29/7892 , B01J35/1014 , B01J2229/20 , B01J2229/42 , C10G45/64 , C10G47/20
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.
摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。
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公开(公告)号：US20090186754A1
公开(公告)日：2009-07-23
申请号：US12316978
申请日：2008-12-18
申请人： Christine Elia , Mohan Kalyanaraman , Lei Zhang , Madhav Acharya , Michael A. Daage , Darden Sinclair , Jocelyn A. Kowalski , Jose G. Santiesteban , Ajit B. Dandekar
发明人： Christine Elia , Mohan Kalyanaraman , Lei Zhang , Madhav Acharya , Michael A. Daage , Darden Sinclair , Jocelyn A. Kowalski , Jose G. Santiesteban , Ajit B. Dandekar
CPC分类号： B01J37/0009 , B01J21/04 , B01J21/063 , B01J21/066 , B01J21/08 , B01J29/068 , B01J29/7261 , B01J29/7292 , B01J29/7461 , B01J29/7492 , B01J29/7861 , B01J29/7892 , B01J35/1014 , B01J2229/20 , B01J2229/42 , C10G45/64 , C10G47/20
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.
摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。
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公开(公告)号：US07498474B2
公开(公告)日：2009-03-03
申请号：US11362255
申请日：2006-02-27
IPC分类号： C07C2/66
CPC分类号： C10G29/205
摘要： A process for the production of high octane number gasoline from light refinery olefins and benzene-containing aromatic streams such as reformate. The process achieves good utilization of both the ethylene and the propylene present in the mixed olefin feed from the unsaturated gas plant while reducing gasoline benzene levels. The light olefins including ethylene and propylene are reacted with the light aromatic stream containing benzene and other single ring aromatic compounds to form a gasoline boiling range product containing akylaromatics. The reaction is carried out with a two-catalyst system which comprises a member of the MWW family of zeolites and an intermediate pore size zeolite such as ZSM-5 using a fixed catalyst bed in both stages. Use of the two catalyst system enables the conversion of the ethylene and propylene components of the olefin feed to be converted to alkylaromatics under favorable conditions.
摘要翻译： 一种从轻质炼油烯烃和含苯芳族物流如重整油生产高辛烷值汽油的方法。 该方法可以很好地利用来自不饱和气体装置的混合烯烃进料中存在的乙烯和丙烯，同时降低汽油苯的含量。 包括乙烯和丙烯的轻质烯烃与含有苯和其它单环芳族化合物的轻芳烃物流反应，形成含烷基芳族化合物的汽油沸程产品。 该反应用两催化剂体系进行，该双催化剂体系包括MWW沸石族的成员和中等孔径的沸石如ZSM-5，其使用两个阶段的固定催化剂床。 使用这两种催化剂体系可使烯烃进料的乙烯和丙烯成分转化成有利条件下的烷基芳族化合物。
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4.发明授权公开(公告)号：US08778171B2
公开(公告)日：2014-07-15
申请号：US13412945
申请日：2012-03-06
申请人： Christopher G. Oliveri , Wenyih Frank Lai , Ajit B. Dandekar , Scott J. Weigel , Jason Wu , Robert E. Kay
发明人： Christopher G. Oliveri , Wenyih Frank Lai , Ajit B. Dandekar , Scott J. Weigel , Jason Wu , Robert E. Kay
IPC分类号： B01J29/08 , B01J29/06 , B01J29/10 , B01J29/12 , C10G47/10 , C10G47/12 , C10G47/14 , C10G47/18
CPC分类号： B01J35/002 , B01J29/084 , B01J29/126 , B01J29/146 , B01J29/166 , B01J29/80 , B01J35/023 , B01J35/04 , B01J35/1019 , B01J35/1061 , B01J35/1066 , B01J35/1085 , B01J35/109 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C01B39/24 , C10G47/18 , C10G47/20
摘要： This invention relates to hydrocracking catalysts utilizing stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystallites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 μm. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4:1 or more. This invention also relates to the use of such catalysts in hydrocracking processes for the conversion of heavy oils into lighter fuel products. The invention is particularly suited for the selective production of diesel range products from gas oil range feedstock materials under hydrocracking conditions.
摘要翻译： 本发明涉及使用聚集成更大二次粒子的沸石Y的小初级晶体的稳定聚集体的加氢裂化催化剂。 至少80％的二次粒子可以包含至少5个初级微晶。 初级微晶的尺寸可以为至多约0.5微米，或至多约0.3微米，并且二次颗粒的尺寸可以为至少约0.8微米，或至少约1.0微米。 得到的稳定的聚集Y型沸石的二氧化硅与氧化铝的比例可以为4:1以上。 本发明还涉及这种催化剂在加氢裂化方法中用于将重油转化成较轻燃料产物的用途。 本发明特别适用于在加氢裂化条件下从瓦斯油原料中选择性生产柴油产品。
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公开(公告)号：US07951986B2
公开(公告)日：2011-05-31
申请号：US12846515
申请日：2010-07-29
CPC分类号： C07C2/66 , C07C6/126 , Y02P20/52 , C07C15/085 , C07C15/073
摘要： Disclosed herein is a process and catalyst for producing an ethylbenzene feed from a polyethylbenzene feed, comprising the step of contacting a benzene feed with a polyethylbenzene feed under at least partial liquid phase conditions in the presence of a zeolite beta catalyst having a phosphorus content in the range of 0.01 wt. % to 0.5 wt. % of said catalyst, to provide a product which comprises ethylbenzene.
摘要翻译： 本文公开了一种用于从聚乙苯进料生产乙苯进料的方法和催化剂，其包括在至少部分液相条件下，在具有磷含量的沸石β催化剂的存在下使苯进料与多乙基苯进料接触的步骤 范围0.01 wt。 ％至0.5wt。 ％的所述催化剂，以提供包含乙苯的产物。
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公开(公告)号：US20100298617A1
公开(公告)日：2010-11-25
申请号：US12846515
申请日：2010-07-29
IPC分类号： C07C4/24
CPC分类号： C07C2/66 , C07C6/126 , Y02P20/52 , C07C15/085 , C07C15/073
摘要： Disclosed herein is a process and catalyst for producing an ethylbenzene feed from a polyethylbenzene feed, comprising the step of contacting a benzene feed with a polyethylbenzene feed under at least partial liquid phase conditions in the presence of a zeolite beta catalyst having a phosphorus content in the range of 0.01 wt. % to 0.5 wt. % of said catalyst, to provide a product which comprises ethylbenzene.
摘要翻译： 本文公开了一种用于从聚乙苯进料生产乙苯进料的方法和催化剂，其包括在至少部分液相条件下，在具有磷含量的沸石β催化剂的存在下使苯进料与多乙基苯进料接触的步骤 范围0.01 wt。 ％至0.5wt。 ％的所述催化剂，以提供包含乙苯的产物。
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公开(公告)号：US07569739B2
公开(公告)日：2009-08-04
申请号：US11873865
申请日：2007-10-17
申请人： Ajit B. Dandekar , John P. McWilliams , Thomas Francis Degnan , Michael Hryniszak , Donald J. Klocke , Wieslaw Jerzy Roth
发明人： Ajit B. Dandekar , John P. McWilliams , Thomas Francis Degnan , Michael Hryniszak , Donald J. Klocke , Wieslaw Jerzy Roth
IPC分类号： C07C2/68
CPC分类号： C07C2/66 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/085
摘要： The present invention provides a process for producing an alkylaromatic compound comprising the step of contacting an alkylatable aromatic compound with an alkylating agent under alkylation conditions in the presence of a alkylation catalyst comprising phosphorus and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including the d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom.
摘要翻译： 本发明提供一种生产烷基芳族化合物的方法，包括使烷基化芳族化合物与烷基化剂在烷基化条件下在包含磷的烷基化催化剂和具有X射线衍射图的多孔结晶无机氧化物材料存在下接触的步骤 包括12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值。
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公开(公告)号：US07297829B2
公开(公告)日：2007-11-20
申请号：US11128721
申请日：2005-05-13
申请人： Ajit B. Dandekar , John P. McWilliams , Thomas Francis Degnan , Michael Hryniszak , Donald J. Klocke , Wieslaw Jerzy Roth
发明人： Ajit B. Dandekar , John P. McWilliams , Thomas Francis Degnan , Michael Hryniszak , Donald J. Klocke , Wieslaw Jerzy Roth
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/085
摘要： The present invention provides a process for producing an alkylaromatic compound comprising the step of contacting an alkylatable aromatic compound with an alkylating agent under alkylation conditions in the presence of a alkylation catalyst comprising phosphorus and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including the d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom.
摘要翻译： 本发明提供一种生产烷基芳族化合物的方法，包括使烷基化芳族化合物与烷基化剂在烷基化条件下在包含磷的烷基化催化剂和具有X射线衍射图的多孔结晶无机氧化物材料存在下接触的步骤 包括12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值。
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公开(公告)号：US06878654B2
公开(公告)日：2005-04-12
申请号：US10243572
申请日：2002-09-13
IPC分类号： B01J29/70 , B01J29/90 , B01J38/12 , B01J38/60 , B01J38/62 , B01J38/64 , B01J38/66 , C07B61/00 , C07C2/66 , C07C6/12 , C07C15/073 , C07C15/085 , B01J20/34 , B01J21/08
CPC分类号： C07C2/66 , B01J29/90 , B01J38/12 , B01J38/60 , B01J38/64 , B01J38/66 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/70 , Y02P20/52 , Y02P20/584 , C07C15/085 , C07C15/073 , C07C15/02
摘要： The present invention provides a process for regenerating a spent aromatics alkylation or transalkylation catalyst comprising a molecular sieve by contacting the spent catalyst with an oxygen-containing gas at a temperature of about 120 to about 600° C. and then contacting the catalyst with an aqueous medium, such as an ammonium nitrate solution, an ammonium carbonate solution or an acid solution.
摘要翻译： 本发明提供了一种通过在约120至约600℃的温度下使废催化剂与含氧气体接触而使含有分子筛的废芳烃烷基化或烷基转移催化剂再生的方法，然后使催化剂与水 介质，如硝酸铵溶液，碳酸铵溶液或酸溶液。
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公开(公告)号：US08834823B2
公开(公告)日：2014-09-16
申请号：US13938590
申请日：2013-07-10
CPC分类号： B01D53/565 , B01D53/8628 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/1026 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20761 , B01D2255/702 , B01D2258/01 , B01D2258/0283 , B01D2259/128 , Y02C20/10
摘要： Methods and systems for selective catalytic reduction of NOx with an activated-carbon-supported metal catalyst at an operating temperature of between about between about 500° C. and about 750° C. An exhaust stream including NOx is introduced to a catalytic reactor having the activated-carbon-supported metal catalyst for NOx reduction of at least 90%. A second catalyst reactor can be provided downstream to remove or convert nitrous oxide as desired.
摘要翻译： 在约500℃至约750℃的操作温度下用活性炭负载的金属催化剂选择性催化还原NOx的方法和系统。将包含NOx的排气流引入到具有 用于NOx还原的活性炭负载金属催化剂至少为90％。 可以向下游提供第二催化剂反应器以根据需要去除或转化一氧化二氮。
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