Method for recycling Li-ion batteries
    1.
    发明公开

    公开(公告)号:US20240347800A1

    公开(公告)日:2024-10-17

    申请号:US18579340

    申请日:2022-07-11

    申请人: SMS group GmbH

    摘要: Lithium-containing electrochemical energy storage devices a recycled by the following steps: i) The electrochemical energy storage devices are initially comminuted and a fraction comprising an active material is separated from the comminuted material. The fraction includes carbon (C), lithium (Li) and at least one of cobalt (Co), manganese (Mn), nickel (Ni), or iron (Fe). ii) The fraction comprising active material is subsequently fed to a melt-down unit and is melted down in the presence of slag-forming agents so that a molten slag phase and a molten metal phase are formed, iii) Then, the lithium (Li) contained in the molten slag phase and/or molten metal phase is converted into a gas phase by the addition of a fluorinating agent and the carbon (C) is converted into a gas phase by the addition of an oxygen-containing gas, and the lithium and carbon are withdrawn from the process as discharge gas.

    METHOD FOR EFFICIENT DISPOSAL OF DIOXIN AND HEAVY METALS BASED ON CALCIUM-BASED HEAT STORAGE OF MSWI FLY ASH

    公开(公告)号:US20240261835A1

    公开(公告)日:2024-08-08

    申请号:US18518418

    申请日:2023-11-22

    IPC分类号: B09B3/70 B09B3/35 B09B3/40

    摘要: A method for efficient disposal of dioxin and heavy metals based on calcium-based heat storage of MSWI fly ash is provided. According to the method, MSWI fly ash washed with water is treated with ammonia, and carbon dioxide is continuously introduced under stirring. The ammonia provides OH− for a carbonation reaction of the MSWI fly ash and promotes removal of sulfate ions. After centrifugation of a reaction solution, calcium carbonate obtained as a solid part is transported to a calcinator of a solar chemical heat reservoir and calcined into calcium oxide by means of solar energy obtained by a solar concentrator. CO2 produced in a calcination process is collected, cooled and liquefied, followed by a carbonation reaction with the calcium oxide in a carbonation radiator. After the operations above are repeated in cycles for several times, carbonated MSWI fly ash is obtained for use as an aggregate or a filler.

    BATTERY RECYCLING APPARATUS AND METHOD
    6.
    发明公开

    公开(公告)号:US20240162517A1

    公开(公告)日:2024-05-16

    申请号:US18389585

    申请日:2023-11-14

    发明人: Michael L. Perry

    IPC分类号: H01M10/54 B09B3/70

    摘要: Disclosed is a battery recycling process wherein an electrochemical flow cell reactor is used to regenerate a reducing agent in an efficient manner. The reactor is decoupled from a hydrometallurgical process in which the reducing agent is used to promote the leaching and reduction of used battery materials in a stirred-tank reactor, such that these two potentially continuous reactors can be operated at independent rates. Since the electrochemical reactor effectively employs forced convective flow, it enables operation at high conversion rates with minimal overpotential and can also be preferentially operated when electrical energy is readily available while the stirred-tank reactor can be operated essentially continuously at a relatively low rate, which enables this equipment to be sized for the desired average energy consumption rate. These features reduce the capital and operation costs relative to electrochemical-based hydrometallurgical process systems taught by others.

    Method and installation for gasification of heterogenic mixtures of organic substances and compounds

    公开(公告)号:US20240010941A1

    公开(公告)日:2024-01-11

    申请号:US18246249

    申请日:2021-04-04

    摘要: The present invention relates to a process and an installation for the continuous flow of gasification of heterogeneous mixtures of organic substances and compounds such as biomass waste, forestry, municipal solid and liquid waste, sludge from sewage treatment plants and other similar waste. Presentation Of The Invention: The process according to the invention has the following steps: a) the organic raw material in heterogeneous mixture is introduced into the pyrolysis reactor (2) where it is gradually heated, by forced convection and thermal radiation, to a temperature of 900 . . . 1000° C., being kept in contact with metal surfaces that transport thermal energy through conduction from the exothermic area of the gasification reactor. The metal surfaces are placed in fixed positions, different so that the contact surface changes after 5 . . . 20 cm traversed by the flow of organic raw material, each group of metal slats forming 2 . . . 8 separation planes, b) the results the pyrolysis process, respectively the solid, liquid and gaseous phases, are gravitationally transferred to the gasification reactor (1) where they are mixed with the gasification agent, respectively air/oxygen and steam in two successive enclosures, the first enclosure with vortex flow and the second with laminar flow, each stage having independent control of the process parameters. The installation according to the invention consists of one or more pyrolysis reactors (2) of cylindrical or prismatic shape, fixed in the enclosures (15) of the gasification reactor (1), a nozzle system (18) for the controlled introduction of air/oxygen and a lock system consisting of the valve (3) and the container (4) for slag removal.