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公开(公告)号:US20240347800A1
公开(公告)日:2024-10-17
申请号:US18579340
申请日:2022-07-11
申请人: SMS group GmbH
IPC分类号: H01M10/54 , B09B3/35 , B09B3/40 , B09B3/70 , B09B101/16
CPC分类号: H01M10/54 , B09B3/35 , B09B3/40 , B09B3/70 , B09B2101/16
摘要: Lithium-containing electrochemical energy storage devices a recycled by the following steps: i) The electrochemical energy storage devices are initially comminuted and a fraction comprising an active material is separated from the comminuted material. The fraction includes carbon (C), lithium (Li) and at least one of cobalt (Co), manganese (Mn), nickel (Ni), or iron (Fe). ii) The fraction comprising active material is subsequently fed to a melt-down unit and is melted down in the presence of slag-forming agents so that a molten slag phase and a molten metal phase are formed, iii) Then, the lithium (Li) contained in the molten slag phase and/or molten metal phase is converted into a gas phase by the addition of a fluorinating agent and the carbon (C) is converted into a gas phase by the addition of an oxygen-containing gas, and the lithium and carbon are withdrawn from the process as discharge gas.
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公开(公告)号:US20240339688A1
公开(公告)日:2024-10-10
申请号:US18681884
申请日:2022-12-09
申请人: GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. , HUNAN BRUNP RECYCLING TECHNOLOGY CO., LTD. , HUNAN BRUNP EV RECYCLING CO., LTD.
发明人: Haijun Yu , Yinghao Xie , Aixia Li , Xuemei Zhang , Changdong Li
IPC分类号: H01M10/54 , B09B3/40 , B09B3/70 , B09B101/16
CPC分类号: H01M10/54 , B09B3/40 , B09B3/70 , B09B2101/16
摘要: The present disclosure discloses a method for recovering active material from waste battery by desorption, comprising steps of: reacting wound cores of cathode and anode current collectors of waste battery with carbon tetrachloride and chlorine to obtain remaining wound cores, a solution of aluminum chloride in carbon tetrachloride and a first desorption powder of cathode; soaking the remaining wound cores and the first desorption powder of cathode in water to obtain soaked wound cores, a lithium salt solution and a second desorption powder of cathode; and reacting the soaked wound cores with nitric acid to obtain a copper nitrate solution and a desorption powder of anode. The waste lithium-ion battery only needs to be discharged and disassembled, and no shredding process is required, which avoids steps of shredding and sorting, reduces equipment investment. In addition, cathode and anode materials can be effectively recovered, and the product has high economic value.
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3.
公开(公告)号:US20240261835A1
公开(公告)日:2024-08-08
申请号:US18518418
申请日:2023-11-22
申请人: Zhejiang University
发明人: Xiaoqing Lin , Jie Chen , Hong Yu , Xiaodong Li , Jianhua Yan
CPC分类号: B09B3/70 , B09B3/35 , B09B3/40 , B09B2101/30
摘要: A method for efficient disposal of dioxin and heavy metals based on calcium-based heat storage of MSWI fly ash is provided. According to the method, MSWI fly ash washed with water is treated with ammonia, and carbon dioxide is continuously introduced under stirring. The ammonia provides OH− for a carbonation reaction of the MSWI fly ash and promotes removal of sulfate ions. After centrifugation of a reaction solution, calcium carbonate obtained as a solid part is transported to a calcinator of a solar chemical heat reservoir and calcined into calcium oxide by means of solar energy obtained by a solar concentrator. CO2 produced in a calcination process is collected, cooled and liquefied, followed by a carbonation reaction with the calcium oxide in a carbonation radiator. After the operations above are repeated in cycles for several times, carbonated MSWI fly ash is obtained for use as an aggregate or a filler.
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公开(公告)号:US12046727B2
公开(公告)日:2024-07-23
申请号:US18472372
申请日:2023-09-22
申请人: KOREA ZINC CO., LTD.
发明人: Heon Sik Choi , Tae Hoon Yoon
CPC分类号: H01M10/54 , B03B9/06 , B09B3/35 , B09B3/40 , B09B3/70 , C01D15/04 , B03B2009/066 , B09B2101/16
摘要: A method for recovering valuable metals from a spent secondary battery includes a pre-processing process of pre-processing the spent secondary battery, a melting process of heating the pre-processed spent secondary battery to generate a molten solution, and a recovery process of recovering the valuable metals from the molten solution. In the melting process, a chlorinating agent is added, and, in the recovery process, lithium is recovered in a form of lithium dust.
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公开(公告)号:US20240175100A1
公开(公告)日:2024-05-30
申请号:US18262973
申请日:2021-01-27
发明人: Veena Sahajwalla
CPC分类号: C21B13/0066 , B09B3/40 , B09B3/70 , C01B3/24 , C01B3/38 , C01B3/48 , C22C33/00 , B09B2101/70 , C01B2203/0233 , C01B2203/0266 , C01B2203/0283
摘要: The present disclosure broadly relates to processes for preparing iron and ferro-alloys using coffee as a source of carbon.
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公开(公告)号:US20240162517A1
公开(公告)日:2024-05-16
申请号:US18389585
申请日:2023-11-14
申请人: FLOW CELL TECH, LLC
发明人: Michael L. Perry
CPC分类号: H01M10/54 , B09B3/70 , B09B2101/16
摘要: Disclosed is a battery recycling process wherein an electrochemical flow cell reactor is used to regenerate a reducing agent in an efficient manner. The reactor is decoupled from a hydrometallurgical process in which the reducing agent is used to promote the leaching and reduction of used battery materials in a stirred-tank reactor, such that these two potentially continuous reactors can be operated at independent rates. Since the electrochemical reactor effectively employs forced convective flow, it enables operation at high conversion rates with minimal overpotential and can also be preferentially operated when electrical energy is readily available while the stirred-tank reactor can be operated essentially continuously at a relatively low rate, which enables this equipment to be sized for the desired average energy consumption rate. These features reduce the capital and operation costs relative to electrochemical-based hydrometallurgical process systems taught by others.
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公开(公告)号:US20240123480A1
公开(公告)日:2024-04-18
申请号:US18277856
申请日:2022-02-18
CPC分类号: B09B3/70 , B03C7/003 , B09B3/35 , C22B1/248 , C22B7/006 , H05K3/22 , B09B2101/17 , H05K2203/0783 , H05K2203/178
摘要: A method of delamination of a printed circuit board includes comminuting the printed circuit board, and soaking the comminuted PCB in a solvent system comprising at least two solvents. Once soaking has been completed the method includes separating solids, and electrostatically separating different specific solids from the separated solids.
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公开(公告)号:US20240100579A1
公开(公告)日:2024-03-28
申请号:US17766218
申请日:2019-12-03
申请人: ZHANGJIAGANG HONGCHANG STEEL PLATE CO., LTD. , JIANGSU SHAGANG GROUP CO., LTD. , INSTITUTE OF RESEARCH OF IRON AND STEEL, JIANGSU PROVINCE/SHA-STEEL, CO., LTD.
发明人: RUI MAO , SHENDONG MAO , FEI WANG , HANG SU
CPC分类号: B09B3/40 , B01D53/502 , B01D53/80 , B01D53/96 , B09B3/70 , C01B17/506 , C01F11/08 , C22B1/16 , B01D2251/404 , B01D2251/602 , B01D2251/604 , B01D2257/302 , B01D2258/0283 , B09B2101/30
摘要: The present invention discloses a resource recovery method and a resource recovery system of desulfurized ash. The resource recovery method comprises: washing desulfurized ash with water, and performing solid-liquid separation to obtain solid residues rich in calcium sulfite and calcium sulfate and a solution rich in calcium hydroxide; preparing the solution into desulfurized slurry; and roasting the solid residues under the action of a reducing agent to obtain flue gas rich in sulfur dioxide and residues rich in calcium oxide. Therefore, the recovery of sulfur and calcium in the desulfurized ash is realized, and no solid waste, liquid waste, gas waste, etc. are produced in the process.
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9.
公开(公告)号:US20240072686A1
公开(公告)日:2024-02-29
申请号:US17960992
申请日:2022-10-06
发明人: Chang-Mou Wu , Mohana Rani Gokana
摘要: A cigarette filter-triboelectric nanogenerator (CF-TENG) which generates triboelectric power. The cigarette filter-triboelectric nanogenerator (GF-TENG) includes a positive triboelectric material made from recycled cigarette filters (CFs) and a negative triboelectric material made from plastic waste, wherein the cigarette filters were mixed with conductive materials. The cigarette-filter triboelectric nanogenerator (CF-TENG) device exhibits excellent electrical output performance.
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10.
公开(公告)号:US20240010941A1
公开(公告)日:2024-01-11
申请号:US18246249
申请日:2021-04-04
CPC分类号: C10J3/723 , B09B3/40 , B09B3/70 , C01B3/22 , B01J6/008 , C10J2200/152 , C10J2200/39 , C10J2300/1246 , C01B2203/0272 , C01B2203/0833
摘要: The present invention relates to a process and an installation for the continuous flow of gasification of heterogeneous mixtures of organic substances and compounds such as biomass waste, forestry, municipal solid and liquid waste, sludge from sewage treatment plants and other similar waste. Presentation Of The Invention: The process according to the invention has the following steps: a) the organic raw material in heterogeneous mixture is introduced into the pyrolysis reactor (2) where it is gradually heated, by forced convection and thermal radiation, to a temperature of 900 . . . 1000° C., being kept in contact with metal surfaces that transport thermal energy through conduction from the exothermic area of the gasification reactor. The metal surfaces are placed in fixed positions, different so that the contact surface changes after 5 . . . 20 cm traversed by the flow of organic raw material, each group of metal slats forming 2 . . . 8 separation planes, b) the results the pyrolysis process, respectively the solid, liquid and gaseous phases, are gravitationally transferred to the gasification reactor (1) where they are mixed with the gasification agent, respectively air/oxygen and steam in two successive enclosures, the first enclosure with vortex flow and the second with laminar flow, each stage having independent control of the process parameters. The installation according to the invention consists of one or more pyrolysis reactors (2) of cylindrical or prismatic shape, fixed in the enclosures (15) of the gasification reactor (1), a nozzle system (18) for the controlled introduction of air/oxygen and a lock system consisting of the valve (3) and the container (4) for slag removal.
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