公开(公告)号：US20170275168A1

公开(公告)日：2017-09-28

申请号：US15496732

申请日：2017-04-25

申请人： KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

发明人： Fahad Ali RABBANI ,  Zuhair Omar Malaibari ,  Muataz Ali Atieh

IPC分类号： C01B31/04 ,  C23C16/448 ,  C01F7/30 ,  C23C16/40 ,  C23C16/455

CPC分类号： C01B32/162 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/0233 ,  C01B32/16 ,  C01B2202/06 ,  C01B2202/10 ,  C01B2202/32 ,  C01F7/304 ,  C04B41/4531 ,  C23C16/01 ,  C23C16/30 ,  C23C16/4417 ,  C23C16/4486 ,  C23C16/46 ,  C23C16/463 ,  Y10S977/744 ,  Y10S977/752 ,  Y10S977/843 ,  Y10S977/846

摘要： A vertical chemical vapor deposition (CVD) reactor and a method for synthesizing metal oxide impregnated carbon nanotubes. The CVD reactor includes a preheating zone portion and a reaction zone portion, and preferably an additional cooling zone portion and a product collector. The method includes (a) subjecting a liquid reactant solution comprising an organic solvent, a metallocene, and a metal alkoxide to atomization in the presence of a gas flow comprising a carrier gas and a support gas to form an atomized mixture, and (b) heating the atomized mixture to a temperature of 200° C.−1400° C., wherein the heating forms a metal oxide and at least one carbon source compound, wherein the metallocene catalyzes the formation of carbon nanotubes from the at least one carbon source compound and the metal oxide is incorporated into or on a surface of the carbon nanotubes to form the metal oxide impregnated carbon nanotubes.

公开(公告)号：US08119032B2

公开(公告)日：2012-02-21

申请号：US12157337

申请日：2008-06-10

申请人： Roy G. Gordon ,  Damon B. Farmer ,  Charles M. Marcus ,  James R. Williams

发明人： Roy G. Gordon ,  Damon B. Farmer ,  Charles M. Marcus ,  James R. Williams

IPC分类号： C23C16/00 ,  H01B1/00

CPC分类号： H01L51/0049 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01F7/304 ,  C01P2004/13 ,  H01L51/057 ,  H01L51/0595 ,  Y10S977/734 ,  Y10S977/755 ,  Y10S977/842 ,  Y10S977/847 ,  Y10S977/89 ,  Y10T428/2918

摘要： The invention provides methods functionalizing a planar surface of a graphene layer, a graphite surface, or microelectronic structure. The graphene layer, graphite surface, or planar microelectronic structure surface is exposed to at least one vapor including at least one functionalization species that non-covalently bonds to the graphene layer, a graphite surface, or planar microelectronic surface while providing a functionalization layer of chemically functional groups, to produce a functionalized graphene layer, graphite surface, or planar microelectronic surface.

摘要翻译： 本发明提供了使石墨烯层，石墨表面或微电子结构的平坦表面官能化的方法。 石墨烯层，石墨表面或平面微电子结构表面暴露于至少一种蒸气，其包括至少一种与石墨烯层，石墨表面或平面微电子表面非共价结合的官能化物质，同时提供化学上的官能化层 官能团，以产生功能化石墨烯层，石墨表面或平面微电子表面。

公开(公告)号：US20050227864A1

公开(公告)日：2005-10-13

申请号：US10503454

申请日：2003-02-19

申请人： Anthony Sutorik ,  Richard Laine ,  Julien Marchal ,  Tyrone Johns ,  Thomas Hinklin

发明人： Anthony Sutorik ,  Richard Laine ,  Julien Marchal ,  Tyrone Johns ,  Thomas Hinklin

IPC分类号： B01J21/04 ,  B01J21/06 ,  B01J23/00 ,  B01J23/10 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  B01J37/08 ,  B01J37/34 ,  C01B13/02 ,  C01B13/34 ,  C01F7/30 ,  C01F17/00 ,  C01G23/047 ,  C01G23/07 ,  C01G25/00 ,  C01G25/02

CPC分类号： B01J23/002 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J23/10 ,  B01J35/0013 ,  B01J35/004 ,  B01J35/023 ,  B01J37/0072 ,  B01J37/086 ,  B01J37/349 ,  B01J2523/00 ,  B82Y30/00 ,  C01B13/02 ,  C01B13/34 ,  C01F7/304 ,  C01F17/0025 ,  C01G23/047 ,  C01G23/07 ,  C01G25/006 ,  C01G25/02 ,  C01P2002/34 ,  C01P2002/52 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2004/84 ,  C01P2006/62 ,  C01P2006/64 ,  C04B35/6264 ,  C04B35/6267 ,  C04B35/62815 ,  C04B35/62821 ,  C04B2235/3217 ,  C04B2235/322 ,  C04B2235/3222 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3232 ,  C04B2235/3239 ,  C04B2235/3244 ,  C04B2235/3275 ,  C04B2235/3289 ,  C04B2235/44 ,  C04B2235/441 ,  C04B2235/449 ,  C04B2235/5409 ,  C04B2235/5445 ,  C04B2235/5454 ,  C04B2235/80 ,  Y10T428/2993 ,  B01J2523/31 ,  B01J2523/47 ,  B01J2523/3712 ,  B01J2523/48

摘要： Liquid feed flame spray pyrolysis of solutions of a metal oxide precursor which is an alkoxide or C1-6 carboxylate and at least one second metal oxide precursor and/or second metal compound dissolved in oxygenated solvent by combustion with oxygen lead to the formation of sub-micron mixed-metal oxide powders not accessible by other processes or by the pyrolysis of metal chlorides or nitrates. The powders have numerous uses in advanced materials applications including particulate solid state lasers, advanced ceramic materials, and as catalysts in organic synthesis and automobile exhaust systems.

摘要翻译： 液体进料火焰喷雾通过燃烧将溶解在氧化溶剂中的金属氧化物前体（其是醇盐或C 1-6 - 羧酸酯）和至少一种第二金属氧化物前体和/或第二金属化合物 氧气导致亚微米混合金属氧化物粉末的形成不能通过其它工艺或金属氯化物或硝酸盐的热解。 这些粉末在先进的材料应用中有许多用途，包括颗粒状固体激光器，先进的陶瓷材料，以及在有机合成和汽车排气系统中的催化剂。

公开(公告)号：US09425406B2

公开(公告)日：2016-08-23

申请号：US13344738

申请日：2012-01-06

申请人： Roy G. Gordon ,  Damon B. Farmer

发明人： Roy G. Gordon ,  Damon B. Farmer

IPC分类号： C23C16/00 ,  H01B1/00 ,  H01L51/00 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/02 ,  C01F7/30 ,  H01L51/05

CPC分类号： H01L51/0049 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01F7/304 ,  C01P2004/13 ,  H01L51/057 ,  H01L51/0595 ,  Y10S977/734 ,  Y10S977/755 ,  Y10S977/842 ,  Y10S977/847 ,  Y10S977/89 ,  Y10T428/2918

摘要： There are provided methods for functionalizing a planar surface of a microelectronic structure, by exposing the surface to at least one vapor including at least one functionalization species, such as NO2 or CH3ONO, that non-covalently bonds to the surface while providing a functionalization layer of chemically functional groups, to produce a functionalized surface. The functionalized surface is exposed to at least one vapor stabilization species that reacts with the functionalization layer to form a stabilization layer that stabilizes the functionalization layer against desorption from the planar microelectronic surface while providing chemically functional groups. The stabilized surface is exposed to at least one material layer precursor species that deposits a material layer on the stabilized planar microelectronic surface. The stabilized planar microelectronic surface can be annealed at a peak annealing temperature that is less than about 700° C.

摘要翻译： 提供了通过将表面暴露于至少一种包含非共价结合表面的官能化物质（例如NO 2或CH 3 ONO）的蒸气的表面而提供微电子结构的平坦表面的方法，同时提供 化学官能团，以产生官能化表面。 功能化表面暴露于与官能化层反应的至少一种汽相稳定物质，以形成稳定层，该稳定层使官能化层抵抗来自平面微电子表面的解吸，同时提供化学官能团。 稳定的表面暴露于在稳定的平面微电子表面上沉积材料层的至少一种材料层前体物质。 稳定的平面微电子表面可以在小于约700℃的峰值退火温度下退火

公开(公告)号：US20100260927A1

公开(公告)日：2010-10-14

申请号：US12820615

申请日：2010-06-22

申请人： Roy G. Gordon ,  Damon B. Farmer

发明人： Roy G. Gordon ,  Damon B. Farmer

IPC分类号： B05D5/12

CPC分类号： C01B31/0233 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/22 ,  C01F7/304 ,  C01P2004/13 ,  H01L51/0049 ,  H01L51/057 ,  Y10S977/70 ,  Y10S977/742 ,  Y10S977/745 ,  Y10S977/748 ,  Y10S977/75 ,  Y10S977/755 ,  Y10S977/842 ,  Y10S977/847 ,  Y10S977/878 ,  Y10S977/89 ,  Y10S977/891

摘要： In a method for functionalizing a carbon nanotube surface, the nanotube surface is exposed to at least one vapor including at least one functionalization species that non-covalently bonds to the nanotube surface, providing chemically functional groups at the nanotube surface, producing a functionalized nanotube surface. A functionalized nanotube surface can be exposed to at least one vapor stabilization species that reacts with the functionalization layer to form a stabilization layer that stabilizes the functionalization layer against desorption from the nanotube surface while providing chemically functional groups at the nanotube surface, producing a stabilized nanotube surface. The stabilized nanotube surface can be exposed to at least one material layer precursor species that deposits a material layer on the stabilized nanotube surface.

摘要翻译： 在用于官能化碳纳米管表面的方法中，纳米管表面暴露于至少一种包含至少一种与纳米管表面非共价结合的官能化物质的蒸气，在纳米管表面提供化学官能团，产生官能化的纳米管表面 。 功能化的纳米管表面可以暴露于与官能化层反应的至少一种汽相稳定物质，以形成稳定层，其使功能化层抵抗从纳米管表面解吸，同时在纳米管表面提供化学官能团，产生稳定的纳米管 表面。 稳定的纳米管表面可以暴露于在稳定的纳米管表面上沉积材料层的至少一种材料层前体物质。

公开(公告)号：US07767114B2

公开(公告)日：2010-08-03

申请号：US11703375

申请日：2007-02-07

申请人： Roy G. Gordon ,  Damon B. Farmer

发明人： Roy G. Gordon ,  Damon B. Farmer

IPC分类号： H01B1/00 ,  H01B1/04

CPC分类号： C01B31/0233 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/22 ,  C01F7/304 ,  C01P2004/13 ,  H01L51/0049 ,  H01L51/057 ,  Y10S977/70 ,  Y10S977/742 ,  Y10S977/745 ,  Y10S977/748 ,  Y10S977/75 ,  Y10S977/755 ,  Y10S977/842 ,  Y10S977/847 ,  Y10S977/878 ,  Y10S977/89 ,  Y10S977/891

摘要： In a method for functionalizing a carbon nanotube surface, the nanotube surface is exposed to at least one vapor including at least one functionalization species that non-covalently bonds to the nanotube surface, providing chemically functional groups at the nanotube surface, producing a functionalized nanotube surface. A functionalized nanotube surface can be exposed to at least one vapor stabilization species that reacts with the functionalization layer to form a stabilization layer that stabilizes the functionalization layer against desorption from the nanotube surface while providing chemically functional groups at the nanotube surface, producing a stabilized nanotube surface. The stabilized nanotube surface can be exposed to at least one material layer precursor species that deposits a material layer on the stabilized nanotube surface.

摘要翻译： 在用于官能化碳纳米管表面的方法中，纳米管表面暴露于至少一种包含至少一种与纳米管表面非共价结合的官能化物质的蒸气，在纳米管表面提供化学官能团，产生官能化的纳米管表面 。 功能化的纳米管表面可以暴露于与官能化层反应的至少一种汽相稳定物质，以形成稳定层，其使功能化层抵抗从纳米管表面解吸，同时在纳米管表面提供化学官能团，产生稳定的纳米管 表面。 稳定的纳米管表面可以暴露于在稳定的纳米管表面上沉积材料层的至少一种材料层前体物质。

公开(公告)号：US20070175362A1

公开(公告)日：2007-08-02

申请号：US11733998

申请日：2007-04-11

申请人： Andreas Gutsch ,  Thomas Hennig ,  Stipan Katusic ,  Michael Kramer ,  Gunther Michael ,  Geoffrey Varga

发明人： Andreas Gutsch ,  Thomas Hennig ,  Stipan Katusic ,  Michael Kramer ,  Gunther Michael ,  Geoffrey Varga

IPC分类号： C04B14/00 ,  C01B13/14

CPC分类号： B82Y30/00 ,  C01B13/20 ,  C01B13/34 ,  C01F7/304 ,  C01F7/306 ,  C01G1/02 ,  C01G23/07 ,  C01G25/02 ,  C01P2002/02 ,  C01P2002/76 ,  C01P2004/32 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/80 ,  C09K3/1409 ,  Y10T428/2982

摘要： Nanoscale, pyrogenically produced oxides and/or mixed oxides having a BET surface area of between 1 m2/g and 600 m2/g and a chloride content of less than 0.05 wt. % are produced by converting organometallic and/or organometalloid substances into the oxides at temperatures of above 200° C. The oxides may be used as a polishing agent in the electronics industry (CMP).

摘要翻译： 纳米尺度，热解产生的氧化物和/或混合氧化物，其BET表面积为1m 2 / g至600m 2 / g，氯化物含量小于0.05 重量 通过在高于200℃的温度下将有机金属和/或有机金属物质转化为氧化物来生产。氧化物可以用作电子工业（CMP）中的抛光剂。

公开(公告)号：US07220398B2

公开(公告)日：2007-05-22

申请号：US10503454

申请日：2003-02-19

申请人： Anthony C. Sutorik ,  Richard M. Laine ,  Julien Marchal ,  Tyrone Johns ,  Thomas Hinklin

发明人： Anthony C. Sutorik ,  Richard M. Laine ,  Julien Marchal ,  Tyrone Johns ,  Thomas Hinklin

IPC分类号： C01G1/02 ,  C01G23/04

CPC分类号： B01J23/002 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J23/10 ,  B01J35/0013 ,  B01J35/004 ,  B01J35/023 ,  B01J37/0072 ,  B01J37/086 ,  B01J37/349 ,  B01J2523/00 ,  B82Y30/00 ,  C01B13/02 ,  C01B13/34 ,  C01F7/304 ,  C01F17/0025 ,  C01G23/047 ,  C01G23/07 ,  C01G25/006 ,  C01G25/02 ,  C01P2002/34 ,  C01P2002/52 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2004/84 ,  C01P2006/62 ,  C01P2006/64 ,  C04B35/6264 ,  C04B35/6267 ,  C04B35/62815 ,  C04B35/62821 ,  C04B2235/3217 ,  C04B2235/322 ,  C04B2235/3222 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3232 ,  C04B2235/3239 ,  C04B2235/3244 ,  C04B2235/3275 ,  C04B2235/3289 ,  C04B2235/44 ,  C04B2235/441 ,  C04B2235/449 ,  C04B2235/5409 ,  C04B2235/5445 ,  C04B2235/5454 ,  C04B2235/80 ,  Y10T428/2993 ,  B01J2523/31 ,  B01J2523/47 ,  B01J2523/3712 ,  B01J2523/48

摘要： Liquid feed flame spray pyrolysis of solutions of a metal oxide precursor which is an alkoxide or C1-6 carboxylate and at least one second metal oxide precursor and/or second metal compound dissolved in oxygenated solvent by combustion with oxygen lead to the formation of sub-micron mixed-metal oxide powders not accessible by other processes or by the pyrolysis of metal chlorides or nitrates. The powders have numerous uses in advanced materials applications including particulate solid state lasers, advanced ceramic materials, and as catalysts in organic synthesis and automobile exhaust systems.

摘要翻译： 液体进料火焰喷雾通过燃烧将溶解在氧化溶剂中的金属氧化物前体（其是醇盐或C 1-6 - 羧酸酯）和至少一种第二金属氧化物前体和/或第二金属化合物 氧气导致亚微米混合金属氧化物粉末的形成不能通过其它工艺或金属氯化物或硝酸盐的热解。 这些粉末在先进的材料应用中有许多用途，包括颗粒状固体激光器，先进的陶瓷材料，以及在有机合成和汽车排气系统中的催化剂。

公开(公告)号：US09816185B2

公开(公告)日：2017-11-14

申请号：US15589400

申请日：2017-05-08

申请人： KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

发明人： Fahad Ali Rabbani ,  Zuhair Omar Malaibari ,  Muataz Ali Atieh

IPC分类号： C23C16/448 ,  C23C16/00 ,  B05D7/24 ,  C23C16/46 ,  C23C16/455

CPC分类号： C01B32/162 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/0233 ,  C01B32/16 ,  C01B2202/06 ,  C01B2202/10 ,  C01B2202/32 ,  C01F7/304 ,  C04B41/4531 ,  C23C16/01 ,  C23C16/30 ,  C23C16/4417 ,  C23C16/4486 ,  C23C16/46 ,  C23C16/463 ,  Y10S977/744 ,  Y10S977/752 ,  Y10S977/843 ,  Y10S977/846

摘要： A vertical chemical vapor deposition (CVD) reactor and a method for synthesizing metal oxide impregnated carbon nanotubes. The CVD reactor includes a preheating zone portion and a reaction zone portion, and preferably an additional cooling zone portion and a product collector. The method includes (a) subjecting a liquid reactant solution comprising an organic solvent, a metallocene, and a metal alkoxide to atomization in the presence of a gas flow comprising a carrier gas and a support gas to form an atomized mixture, and (b) heating the atomized mixture to a temperature of 200° C.-1400° C., wherein the heating forms a metal oxide and at least one carbon source compound, wherein the metallocene catalyzes the formation of carbon nanotubes from the at least one carbon source compound and the metal oxide is incorporated into or on a surface of the carbon nanotubes to form the metal oxide impregnated carbon nanotubes.

公开(公告)号：US09670103B1

公开(公告)日：2017-06-06

申请号：US15077600

申请日：2016-03-22

申请人： KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

发明人： Fahad Ali Rabbani ,  Zuhair Omar Malaibari ,  Muataz Ali Atieh

IPC分类号： C04B41/45 ,  C04B41/85 ,  C23C16/26 ,  C23C16/448 ,  C23C16/01 ,  C23C16/40 ,  C23C16/455

CPC分类号： C01B32/162 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/0233 ,  C01B32/16 ,  C01B2202/06 ,  C01B2202/10 ,  C01B2202/32 ,  C01F7/304 ,  C04B41/4531 ,  C23C16/01 ,  C23C16/30 ,  C23C16/4417 ,  C23C16/4486 ,  C23C16/46 ,  C23C16/463 ,  Y10S977/744 ,  Y10S977/752 ,  Y10S977/843 ,  Y10S977/846

摘要： A vertical chemical vapor deposition (CVD) reactor and a method for synthesizing metal oxide impregnated carbon nanotubes. The CVD reactor includes a preheating zone portion and a reaction zone portion, and preferably an additional cooling zone portion and a product collector. The method includes (a) subjecting a liquid reactant solution comprising an organic solvent, a metallocene, and a metal alkoxide to atomization in the presence of a gas flow comprising a carrier gas and a support gas to form an atomized mixture, and (b) heating the atomized mixture to a temperature of 200° C.-1400° C., wherein the heating forms a metal oxide and at least one carbon source compound, wherein the metallocene catalyzes the formation of carbon nanotubes from the at least one carbon source compound and the metal oxide is incorporated into or on a surface of the carbon nanotubes to form the metal oxide impregnated carbon nanotubes.