Abstract:
A new class of nanostructured RE-doped SiO2-base materials that display superior fluorescence properties is provided. In particular, high gain combined with a broad and flat spectral band width is observed in material composed of a high fraction of a nano-dispersed metastable silicate phase in a glassy SiO2 matrix, produced by partial devitrification (crystallization) of several glassy Al2O3/Er2O3- and Y2O3/Er2O3-doped SiO2 compositions. Also, a highly deconvoluted spectral emission, with several prominent peaks, is observed in completely devitrified material, consisting of a uniform nano-dispersion of an equilibrium silicate phase in a crystobalite SiO2 matrix. Such enhanced fluorescence properties were observed in heat treated nanopowders prepared by vapor-phase, solgel, rapid solidification, and spray-pyrolysis methods.
Abstract translation:提供了一类新型的具有优异荧光性能的纳米结构的RE掺杂SiO 2基体材料。 特别地,在通过部分失透反应产生的玻璃状SiO 2基体中的高分数纳米分散的亚稳态硅酸盐相组成的材料中观察到具有宽的和平坦的光谱带宽的高增益( 几个玻璃状的Al 2 O 3 / O 2 O 3 - 和Y 2的结晶, O 3组成的二氧化硅组合物。 此外,在完全失透的材料中观察到具有几个突出的峰的高度去卷积的光谱发射,由平底硅酸盐相在均匀的SiO 2基体中的均匀的纳米分散体组成。 在通过气相,溶胶凝胶,快速凝固和喷雾热解方法制备的热处理纳米粉末中观察到这种增强的荧光性质。
Abstract:
A quartz glass lamp vessel 1 or 21 is used in many types of lamps. Sometimes it is expedient to absorb a certain portion of the emission spectrum. In accordance with the prior art this is possible by including rare earth metal oxides in the quartz glass.The solubility of rare earth metal oxides in quartz glass is, however, limited.According to the invention, quartz glass is used which contains an alkali metal oxide and optionally, an alkaline earth metal oxide, in addition to a rare earth metal oxide. The alkali metal oxide increases the solubility of the rare earth metal oxide, so that rare earth metal oxides can be used in larger concentrations. This results in glasses which have a higher degree of absorption, from which lamp vessels can be produced.
Abstract:
Optical fiber composed of a glass doped with at least laser-active ions of an element from the rare earths. An optical fiber of glass, preferably a HMF glass, doped with Tm.sup.3+ is operated at 1.48 .mu.m as a fiber laser or amplifier on the laser transition .sup.3 F.sub.4 -.sup.3 H.sub.4. Since this thereby involves a self-saturating transition, the terminal level is emptied in accelerated fashion for a continuous wave mode by co-doping with de-activators, preferably Ho.sup.3+, Tb.sup.3+, Eu.sup.3+ and/or Pr.sup.3+ ions. The pump light wavelength can be selected from the wavelength range from 700 through 890 nm of GaAlAs emission. The optical fiber can be used in optical amplifiers or fiber amplifiers.
Abstract:
A novel method is proposed for the preparation of a transparent fused silica glass body co-doped with a rare earth element and aluminum each in a high uniformity of the dopant distribution. The method comprises the steps of: (a) flame-hydrolyzing a silicon compound and an aluminum compound in an oxyhydrogen flame to form a porous silicon oxide body containing aluminum; (b) soaking the porous body having a specified bulk density with a solution of a rare earth compound; (c) drying the solution-soaked porous body; and (d) sintering and vitrifying the dried porous body into a transparent glass body.
Abstract:
Provided is a wavelength conversion member that is less decreased in luminescence intensity with time by irradiation with light of an LED or LD and a light emitting device using the wavelength conversion member. A wavelength conversion member is formed of an inorganic phosphor dispersed in a glass matrix, wherein the glass matrix contains, in % by mole, 30 to 85% SiO2, 0 to 20% B2O3, 0 to 25% Al2O3, 0 to 3% Li2O, 0 to 3% Na2O, 0 to 3% K2O, 0 to 3% Li2O+Na2O+K2O, 0 to 35% MgO, 0 to 35% CaO, 0 to 35% SrO, 0 to 35% BaO, 0.1 to 45% MgO+CaO+SrO+BaO, and 0 to 4% ZnO, and the inorganic phosphor is at least one selected from the group consisting of an oxide phosphor, a nitride phosphor, an oxynitride phosphor, a chloride phosphor, an oxychloride phosphor, a halide phosphor, an aluminate phosphor, and a halophosphate phosphor.
Abstract:
A new class of nanostructured RE-doped SiO2-base materials that display superior fluorescence properties is provided. In particular, high gain combined with a broad and flat spectral band width is observed in material composed of a high fraction of a nano-dispersed metastable silicate phase in a glassy SiO2 matrix, produced by partial devitrification (crystallization) of several glassy Al2O3/Er2O3- and Y2O3/Er2O3-doped SiO2 compositions. Also, a highly deconvoluted spectral emission, with several prominent peaks, is observed in completely devitrified material, consisting of a uniform nano-dispersion of an equilibrium silicate phase in a crystobalite SiO2 matrix. Such enhanced fluorescence properties were observed in heat treated nanopowders prepared by vapor-phase, solgel, rapid solidification, and spray-pyrolysis methods.
Abstract translation:提供了一类新型的具有优异荧光性能的纳米结构的RE掺杂SiO 2基体材料。 特别地,在通过部分失透反应产生的玻璃状SiO 2基体中的高分数纳米分散的亚稳态硅酸盐相组成的材料中观察到具有宽的和平坦的光谱带宽的高增益( 几个玻璃状的Al 2 O 3 / O 2 O 3 - 和Y 2的结晶, O 3组成的二氧化硅组合物。 此外,在完全失透的材料中观察到具有几个突出的峰的高度去卷积的光谱发射,由平底硅酸盐相在均匀的SiO 2基体中的均匀的纳米分散体组成。 在通过气相,溶胶凝胶,快速凝固和喷雾热解方法制备的热处理纳米粉末中观察到这种增强的荧光性质。
Abstract:
Fused quartz containing europium oxide, titanium dioxide and cerium oxide has been found to be effective for absorbing UV radiation while transmitting visible light radiation. Uses for this material include lamp envelopes and shrouds for halogen-incandescent lamps and metal halide arc discharge lamps which emit both UV and visible light radiation.