Anti-alumina-buildup refractories for casting nozzles
    1.
    发明授权
    Anti-alumina-buildup refractories for casting nozzles 有权
    用于铸造喷嘴的抗氧化铝堆积耐火材料

    公开(公告)号:US08354354B2

    公开(公告)日:2013-01-15

    申请号:US13136850

    申请日:2011-08-12

    IPC分类号: C04B35/057

    摘要: Disclosed is anti-alumina-buildup refractories for casting nozzles, which comprises a refractory aggregate including 20 mass % or more of CaO component, and 10 mass % or more of clinker particles each containing CaO as a mineral phase, on the basis of 100 mass % of the entire composition. At least a part of the surfaces of the CaO exposed from the surfaces of the corresponding clinker particles is formed with a CaCO3 film. The CaCO3 film releases CO2 gas through thermal decomposition to smooth an operative surface of the nozzle so as to prevent the accretion of metal thereon, so that CaO is continuously supplied to alumina attached on the operative surface to prevent alumina buildup. In addition, the CaCO3 film effectively prevents the hydration of CaO due to a hydration reaction.

    摘要翻译: 公开了用于铸造喷嘴的抗氧化铝生成耐火材料,其包含基于100质量%的包含CaO组分的20质量%以上的耐火骨料和10质量%以上含有CaO作为矿物相的熟料颗粒 整个组成的百分比。 由相应的熟料颗粒的表面露出的至少一部分表面形成有CaCO 3膜。 CaCO 3膜通过热分解释放CO 2气体以使喷嘴的操作表面平滑,以防止其上的金属沉积,使得CaO连续地供应到附着在操作表面上的氧化铝以防止氧化铝堆积。 此外,CaCO3膜有效地防止了由于水合反应导致的CaO的水化。

    Anti-alumina-buildup refractories for casting nozzles
    2.
    发明申请
    Anti-alumina-buildup refractories for casting nozzles 审中-公开
    用于铸造喷嘴的抗氧化铝堆积耐火材料

    公开(公告)号:US20110003679A1

    公开(公告)日:2011-01-06

    申请号:US10524621

    申请日:2003-08-19

    IPC分类号: C04B35/057

    摘要: Disclosed is anti-alumina-buildup refractories for casting nozzles, which comprises a refractory aggregate including 20 mass % or more of CaO component, and 10 mass % or more of clinker particles each containing CaO as a mineral phase, on the basis of 100 mass % of the entire composition. At least a part of the surfaces of the CaO exposed from the surfaces of the corresponding clinker particles is formed with a CaCO3 film. The CaCO3 film releases CO2 gas through thermal decomposition to smooth an operative surface of the nozzle so as to prevent the accretion of metal thereon, so that CaO is continuously supplied to alumina attached on the operative surface to prevent alumina buildup. In addition, the CaCO3 film effectively prevents the hydration of CaO due to a hydration reaction.

    摘要翻译: 公开了用于铸造喷嘴的抗氧化铝生成耐火材料,其包含基于100质量%的包含CaO组分的20质量%以上的耐火骨料和10质量%以上含有CaO作为矿物相的熟料颗粒 整个组成的百分比。 由相应的熟料颗粒的表面露出的至少一部分表面形成有CaCO 3膜。 CaCO 3膜通过热分解释放CO 2气体以使喷嘴的操作表面平滑,以防止其上的金属沉积,使得CaO连续地供应到附着在操作表面上的氧化铝以防止氧化铝堆积。 此外,CaCO3膜有效地防止了由于水合反应导致的CaO的水合。

    Method for manufacturing immersion nozzle less susceptible to deposition of alumina for use in continuous casting
    5.
    发明申请
    Method for manufacturing immersion nozzle less susceptible to deposition of alumina for use in continuous casting 审中-公开
    用于制造浸入式喷嘴的方法不易于连续铸造中使用的氧化铝沉积

    公开(公告)号:US20050274486A1

    公开(公告)日:2005-12-15

    申请号:US10524622

    申请日:2003-08-19

    摘要: Disclosed is a method of producing an immersion nozzle for continuous casting, which comprises integrally molding a first zirconia-graphite compound applied to a powder-line portion of the nozzle, and a second compound applied to at least an inner hole portion of the nozzle. The second compound includes 10 mass % or more of clinker particles each containing CaO as a mineral phase, and the surface of at least a part of the clinker particles is subjected to an anti-hydration treatment, such as a heat treatment to be performed under a CO2 atmosphere to convert CaO to CaCO3. The method of the present invention can suppress volume expansion caused by the reaction between CaO and water released from resin added as binder, so as to prevent the occurrence of cracks during a burning process of the molded piece.

    摘要翻译: 公开了一种连续铸造用浸渍式喷嘴的制造方法,其特征在于,将施加于所述喷嘴的粉末部分的第一氧化锆 - 石墨化合物和施加在所述喷嘴的至少内部孔部分上的第二化合物一体成型。 第二化合物包含10质量%以上的各自含有CaO作为矿物相的熟料粒子,至少部分熟料粒子的表面进行防水处理,例如在 CO 2气氛以将CaO转化为CaCO 3。 本发明的方法可以抑制由作为粘合剂添加的树脂释放的CaO和水之间的反应引起的体积膨胀,以防止在模制件的燃烧过程中出现裂纹。

    Molten steel pouring nozzle
    6.
    发明授权
    Molten steel pouring nozzle 失效
    熔钢浇注嘴

    公开(公告)号:US5348203A

    公开(公告)日:1994-09-20

    申请号:US110088

    申请日:1993-08-20

    摘要: A molten steel pouring nozzle which comprises: a nozzle body comprising an alumina-graphite refractory, having, along the axis thereof, a bore through which molten steel flows; and an outer refractory layer arranged on an outside portion of the nozzle body so as to be integral with the nozzle body and to be flush with an outer surface thereof, the outer refractory layer being arranged on a portion of the outside portion of the nozzle body, which portion is in contact, when a lower portion of the molten steel pouring nozzle is immersed into molten steel, with the open air without being immersed into the molten steel, and the outer refractory layer consisting essentially of:______________________________________ alumina (Al.sub.2 O.sub.3) from 40 to 75 wt. %, carbon (C) from 10 to 30 wt. %, silica (SiO.sub.2) from 1 to 30 wt. %, silicon carbide (SiC) from 1 to 20 wt. %, and low-melting glass from 1 to 10 wt. %. ______________________________________

    摘要翻译: 一种钢水浇注嘴,其包括:喷嘴体,其包括氧化铝 - 石墨耐火材料,所述氧化铝 - 石墨耐火材料沿其轴线具有钢水流过的孔; 以及外部耐火层,其设置在所述喷嘴体的外侧部分上,以与所述喷嘴体一体形成并与其外表面齐平,所述外耐火层设置在所述喷嘴体外部的一部分上 当钢水浇注嘴的下部浸没在钢水中时,该部分接触,露出的空气不浸入钢水中,外部耐火层基本上由以下组成: - 氧化铝(Al 2 O 3) 40至75wt。 %, - 碳(C)10〜30wt。 %, - 硅酸(SiO 2)1〜30wt。 %,碳化硅(SiC)1〜20wt。 %,和 - 低熔点玻璃1至10wt。 %。 -

    Insulating tundish veneer composition useful in casting steel
    8.
    发明授权
    Insulating tundish veneer composition useful in casting steel 失效
    绝缘中间包单板组合物可用于铸钢

    公开(公告)号:US4226625A

    公开(公告)日:1980-10-07

    申请号:US45531

    申请日:1979-06-04

    摘要: A composition for insulating or coating tundish materials useful in casting steel which comprises two forms:______________________________________ Broad Medium Preferred (%) (%) (%) ______________________________________ (a) a troweling mix Celite 300 (diatomaceous earth) 5-50 5-25 10.0 200M Mullite (refractory silica-alumina filler) 5-50 10-30 27.0 M&D clay (refractory filler) 2-20 2-15 7.5 Goulac (wood glue) 0.2-5 0.2-2.5 0.5 Cerafiber 312 (silica- alumina fiber) 5-25 5-15 7.5 3216 Graphite (graphite) 1-25 5-20 10.0 Nalgun #2 Binder (colloidal silica binder) 1-30 5-15 7.5 Water 15-50 20-40 30.0 (b) a gunning mix Celite 300 (diatomaceous earth) 5-50 5-25 15.0 200M Mullite (refractory silica-alumina filler) 5-50 10-30 36.8 M&D clay (refractory filler) 2-20 5-15 10.0 Goulac (wood glue) 0.5-5 0.5-2.5 0.7 Cerafiber 312 (silica alumina fiber) 5-25 5-15 10.0 3216 Graphite (graphite) 1-25 5-20 15.0 Nalgun #2 Binder (colloidal silica binder) 1-30 5-15 10.0 Water 1-10 1-5 2.5 ______________________________________

    摘要翻译: 用于铸钢的中间包材料的绝缘或涂层组合物,包括两种形式:宽介质优选(%)(%)(%)(a)捣碎混合物硅藻土300(硅藻土)5-50 5-25 10.0 200M莫来石 (耐火二氧化硅 - 氧化铝填料)5-50 10-30 27.0 M&D粘土(耐火填料)2-20 2-15 7.5 Goulac(木胶)0.2-5 0.2-2.5 0.5 Cerafiber 312(二氧化硅 - 氧化铝纤维)5-25 5-15 7.5 3216石墨(石墨)1-25 5-20 10.0 Nalgun#2粘结剂(胶体二氧化硅粘合剂)1-30 5-15 7.5水15-50 20-40 30.0(b)喷射混合物Celite 300(硅藻土 土壤)5-50 5-25 15.0 200M莫来石(耐火二氧化硅 - 氧化铝填料)5-50 10-30 36.8 M&D粘土(耐火填料)2-20 5-15 10.0 Goulac(木胶)0.5-5 0.5-2.5 0.7 Cerafiber 312(二氧化硅氧化铝纤维)5-25 5-15 10.0 3216石墨(石墨)1-25 5-20 15.0 Nalgun#2粘合剂(胶体二氧化硅粘合剂)1-30 5-15 10.0水1-10 1-5 2.5