摘要:
Disclosed is anti-alumina-buildup refractories for casting nozzles, which comprises a refractory aggregate including 20 mass % or more of CaO component, and 10 mass % or more of clinker particles each containing CaO as a mineral phase, on the basis of 100 mass % of the entire composition. At least a part of the surfaces of the CaO exposed from the surfaces of the corresponding clinker particles is formed with a CaCO3 film. The CaCO3 film releases CO2 gas through thermal decomposition to smooth an operative surface of the nozzle so as to prevent the accretion of metal thereon, so that CaO is continuously supplied to alumina attached on the operative surface to prevent alumina buildup. In addition, the CaCO3 film effectively prevents the hydration of CaO due to a hydration reaction.
摘要:
Disclosed is anti-alumina-buildup refractories for casting nozzles, which comprises a refractory aggregate including 20 mass % or more of CaO component, and 10 mass % or more of clinker particles each containing CaO as a mineral phase, on the basis of 100 mass % of the entire composition. At least a part of the surfaces of the CaO exposed from the surfaces of the corresponding clinker particles is formed with a CaCO3 film. The CaCO3 film releases CO2 gas through thermal decomposition to smooth an operative surface of the nozzle so as to prevent the accretion of metal thereon, so that CaO is continuously supplied to alumina attached on the operative surface to prevent alumina buildup. In addition, the CaCO3 film effectively prevents the hydration of CaO due to a hydration reaction.
摘要:
Disclosed is a method of producing an immersion nozzle for continuous casting, which comprises integrally molding a first zirconia-graphite compound applied to a powder-line portion of the nozzle, and a second compound applied to at least an inner hole portion of the nozzle. The second compound includes 10 mass % or more of clinker particles each containing CaO as a mineral phase, and the surface of at least a part of the clinker particles is subjected to an anti-hydration treatment, such as a heat treatment to be performed under a CO2 atmosphere to convert CaO to CaCO3. The method of the present invention can suppress volume expansion caused by the reaction between CaO and water released from resin added as binder, so as to prevent the occurrence of cracks during a burning process of the molded piece.
摘要翻译:公开了一种连续铸造用浸渍式喷嘴的制造方法,其特征在于,将施加于所述喷嘴的粉末部分的第一氧化锆 - 石墨化合物和施加在所述喷嘴的至少内部孔部分上的第二化合物一体成型。 第二化合物包含10质量%以上的各自含有CaO作为矿物相的熟料粒子,至少部分熟料粒子的表面进行防水处理,例如在 CO 2气氛以将CaO转化为CaCO 3。 本发明的方法可以抑制由作为粘合剂添加的树脂释放的CaO和水之间的反应引起的体积膨胀,以防止在模制件的燃烧过程中出现裂纹。
摘要:
A molten steel pouring nozzle which comprises: a nozzle body comprising an alumina-graphite refractory, having, along the axis thereof, a bore through which molten steel flows; and an outer refractory layer arranged on an outside portion of the nozzle body so as to be integral with the nozzle body and to be flush with an outer surface thereof, the outer refractory layer being arranged on a portion of the outside portion of the nozzle body, which portion is in contact, when a lower portion of the molten steel pouring nozzle is immersed into molten steel, with the open air without being immersed into the molten steel, and the outer refractory layer consisting essentially of:______________________________________ alumina (Al.sub.2 O.sub.3) from 40 to 75 wt. %, carbon (C) from 10 to 30 wt. %, silica (SiO.sub.2) from 1 to 30 wt. %, silicon carbide (SiC) from 1 to 20 wt. %, and low-melting glass from 1 to 10 wt. %. ______________________________________
摘要:
A refractory material possessing excellent erosion, thermal shock and oxidation resistance, as well as resistance to oxide build up useful in continuous casting of steel for use in such articles as tundish shrouds, particularly for slagline sleeves, bore liners and upper seating areas in such shrouds, as well as for stopper rod noses. The material consists of the following by weight: (a) carbon, from about 4% to about 50%; (b) one or more members selected from the group consisting of zirconium di-boride and titanium di-boride in an amount of from about 10% to about 90%; and (c) one or more members selected from the group consisting of zirconia, SiAlON, clay, alumina, magnesia, silica, silicon carbide, silicon nitride, boron nitride, mullite and chromia in an mount of from about 10% to about 80%.
摘要:
A refractory lining repair material for steel making furnaces and the like, which consist essentially of an exothermic patching mix which may be either gunned in place or applied to furnace bottoms in the form of briquettes. Also relates to the process of furnace repair employing such mixes.