摘要:
Provided is a chiller and system that may be utilized in a supercritical fluid chromatography method, wherein a non-polar solvent may replace a portion or all of a polar solvent for the purpose of separating or extracting desired sample molecules from a combined sample/solvent stream. The system may reduce the amount of polar solvent necessary for chromatographic separation and/or extraction of desired samples. The system may incorporate a supercritical fluid chiller, a supercritical fluid pressure-equalizing vessel and a supercritical fluid cyclonic separator. The supercritical fluid chiller allows for efficient and consistent pumping of liquid-phase gases employing off-the-shelf HPLC pumps. The pressure equalizing vessel allows the use of off-the-shelf HPLC column cartridges. The system may further incorporate the use of one or more disposable cartridges containing silica gel or other suitable medium. The system may also utilize an open loop cooling circuit using fluids with a positive Joule-Thompson coefficient.
摘要:
The present invention relates to a method of refrigeration using refrigerant composition for multistage refrigeration systems, such as a pre-cooled mixed refrigeration system with one or more phase separators. The refrigerant composition can include nitrogen; methane; ethane, ethylene, or combinations thereof; propane, n-butane, iso-butane, or combinations thereof; and neon, helium, or combinations thereof.
摘要:
A shell and coil type heat exchanger evaporator provides cooling for industrial coolants characterized by high viscosity and a poor heat transfer coefficient. A large heat transfer surface area is provided within a limited volume, and without a high coolant pressure drop. A short initial cool down period is provided due to minimized heat exchanger mass and minimized volume of liquid coolant in the heat exchanger during initial cool down.
摘要:
Heating/defrost constructions of a very low temperature refrigeration system having a defrost supply circuit and a defrost return bypass circuit optimizing the heating/defrost cycle, preventing overload (excessive pressure) of its refrigeration process and protecting components from damaging temperatures. The defrost cycle operates continuously, when required, and provides a shorter recovery period between heating/defrost and cooling operating modes. The rate of the temperature change during cool down or warm up is controlled in an open loop fashion by controlled refrigerant flow in bypass circuits.
摘要:
A method for more efficiently liquefying industrial gas wherein refrigeration for the liquefaction is generated using a defined multicomponent refrigerant fluid and provided by a single flow circuit over a wide temperature range from ambient to cryogenic temperature.
摘要:
A method for liquefying an industrial gas wherein a portion of the requisite refrigeration is generated by a multicomponent refrigerant circuit and a portion is generated by turboexpansion of either a portion of the industrial gas or a portion of the multicomponent refrigerant.
摘要:
A method and device is disclosed for removing residual oil and other contaminants from the refrigerant stream flowing to low-temperature stages of a cryogenic refrigerator. A stream of vapor and liquid refrigerant is injected into a cyclone chamber �32! through the inlet tube �34!. While the liquid drains down a conical section �36! and out through a liquid line �38!, the vapor phase moves up into a packing of metal platelets �42! which is, in a particular embodiment, cooled by a returning stream of cold vapor passing through a tube �48! wrapped around the column. A portion of the vapor condenses on the platelets and is maintained in equilibrium with the vapor. Since high-molecular-weight contaminants are more soluble in the liquid phase, they are carried down the column with the drops of condensate and are swept out with the liquid fraction through the liquid line �38!. Consequently, the vapor sent out a vapor line �46! and into the low-temperature stages of the refrigeration system is cleansed of all oil residues and contaminants. A low-temperature refrigeration system with such a device can be operated continuously for many months with no signs of clogging. Moreover, the fractionating column is inexpensive, contains no moving parts, and does not add significant volume to the system.
摘要:
Mixed refrigerants provide refrigeration at cryogenic temperatures with throttling cycles operating with a one-stage compressor. The refrigerants include noncondensable gases such as helium, neon, or hydrogen to increase the overall cooling capacity of a refrigeration system at the same refrigeration temperature which is attainable without such noncondensable gases. More refrigeration can be produced with existing systems at temperatures above the normal boiling point of nitrogen or argon by adding, for example, helium, than for refrigerant blends without helium. By increasing the return pressure value of the refrigeration cycle in relation to the molar percent of helium present in the refrigerant, a constant refrigeration temperature may be maintained which exhibits greater stability than prior systems operating at the same temperature without helium enrichment.
摘要:
A refrigeration heat exchanger section useful in circulating a substantially non-CFC refrigerant mixture which comprises: a compressor means, an auxiliary condenser, a first condenser, a second condenser, a third condenser, a subcooler and a liquid/gas separator, wherein a subcooled refrigerant liquid mixture taken as bottoms from the liquid/gas separator is distributed and expanded by a first expansion means and a second expansion means to form first and second expanded streams, respectively, such that the first expanded stream is returned to the auxiliary condenser and compressor in order to avoid overheating of the compressor.
摘要:
Provided is a chiller and system that may be utilized in a supercritical fluid chromatography method, wherein a non-polar solvent may replace a portion or all of a polar solvent for the purpose of separating or extracting desired sample molecules from a combined sample/solvent stream. The system may reduce the amount of polar solvent necessary for chromatographic separation and/or extraction of desired samples. The system may incorporate a supercritical fluid chiller, a supercritical fluid pressure-equalizing vessel and a supercritical fluid cyclonic separator. The supercritical fluid chiller allows for efficient and consistent pumping of liquid-phase gases employing off-the-shelf HPLC pumps. The pressure equalizing vessel allows the use of off-the-shelf HPLC column cartridges. The system may further incorporate the use of one or more disposable cartridges containing silica gel or other suitable medium. The system may also utilize an open loop cooling circuit using fluids with a positive Joule-Thomson coefficient.