摘要:
A heat exchanger 32 comprises a first heat exchanger 40 for allowing heat to be exchanged between water and a reformed gas from a reforming reactor, a second heat exchanger 50 for spraying and vaporizing water in the reformed gas from the first heat exchanger 40, and a third heat exchanger 60 for vaporizing unvaporized or precipitated water. The reformed gas from the reforming reactor is cooled by the heating and vaporizing of water, and is mixed with the vaporized water and fed as mixed gas to a water gas shift reactor. The processes of cooling the reformed gas, heating and vaporizing of the water, and mixing the reformed gas and steam are completed in the heat exchanger 32, making it possible to design a smaller, simpler, and more efficient apparatus.
摘要:
A reactor for CO control having a reactor vessel having a water-gas shift catalyst zone, a mixed catalyst zone downstream of the water-gas shift catalyst zone, and a methanation catalyst zone disposed downstream of the mixed catalyst zone, at least one water-gas shift catalyst disposed in the water-gas shift catalyst zone, at least one methanation catalyst disposed in the methanation catalyst zone, and a mixture of the water-gas shift catalyst and the methanation disposed in the mixed catalyst zone.
摘要:
The invention relates to a method of combustion, in which waste, especially household and/or industrial waste, is subjected to a process (T) comprising at least one step in which the waste is pyrolysed and a gas mixture containing hydrocarbons is created, and then a step in which gaseous hydrocarbons are brought into contact with steam and with an oxidizing agent, and resulting in the production of a final gas mixture (FM) containing carbon monoxide and hydrogen, and then at least part of the carbon monoxide and of the hydrogen is used, as a mixture, as fuel, for example in a blast furnace (F) or in a cement kiln. The method can be used especially for manufacturing pig iron or cement.
摘要:
The present invention relates to controlled staged rich combustion throughout a fuel processing system in order to improve start up performance. Multiple stages of air injection are used to burn rich combustion products within each component to provide direct heating thereof. During the start up cycle, the fluid temperature entering each reactor is increased and each component is heated to its operating temperature in parallel. The controlled staged rich combustion eliminates the load imposed upon a combustor within the system during the start up cycle. Thus, each of the components within the fuel processing system may be optimized for an operational mode rather than a start up mode.
摘要:
The present invention provides a method of producing a CuZnAlZr oxide catalyst consisting of reacting an aqueous NaOH solution and aqueous NACO3 solution with a mixture of aqueous solutions of each nitrate of Cu, Zn, Al, and Zr, producing a precipitate by coprecipitation, aging, filtering, washing and drying this precipitate to prepare a catalyst precursor consisting of a CuZnAlZr layered double hydroxide, and then obtaining a CuZnAlZr oxide by calcining this precursor in an air ambient atmosphere, a CuZnAlZr oxide catalyst, a CuZnZrCe oxide catalyst, a CoCuZnAl oxide catalyst for producing hydrogen by oxidative steam reforming of methanol, and methods of producing hydrogen gas consisting of converting methanol to hydrogen gas by oxidative steam reforming in the presence of air and steam using these oxide catalysts.
摘要:
The invention provides a method for generating high pressure hydrogen at improved thermal efficiencies. First a synthesis gas stream at a first pressure is produced in a pressure swing reformer. Next the synthesis gas stream is subjected to a high temperature water gas shift process to produce a hydrogen enriched stream from which high pressure hydrogen is obtained. Specific embodiments of the invention involve: regenerating the reformer at a pressure lower than the synthesis gas generation; operating the synthesis gas generation step at conditions sufficient to provide a syn gas stream at a temperature in the range used in the water gas shift reaction; and using pressure swing adsorption to separate the hydrogen.
摘要:
The invention provides a process for the catalytic production of a hydrogen feed by exposing a hydrogen feed to a catalyst which promotes a base-catalyzed water-gas-shift reaction in a liquid phase. The hydrogen feed can be provided by any process known in the art of making hydrogen gas. It is preferably provided by a process that can produce a hydrogen feed for use in proton exchange membrane fuel cells. The step of exposing the hydrogen feed takes place preferably from about 80null C. to about 150null C.
摘要:
Process for the production of a hydrogen rich gas without formation of hydrocarbons comprising water gas shift conversion of a gas containing carbon monoxide and steam at a temperature of between 400null C. and 850null C. in the presence of a catalyst, which catalyst comprises one or more of the elements Mg, Mn, Al, Zr, La, Ce, Pr, and Nd, being able to form basic oxides, and mixtures thereof.