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    Promoted porous catalyst
    1.
    发明申请
    Promoted porous catalyst 有权
    促进多孔催化剂

    公开(公告)号：US20020006862A1

    公开(公告)日：2002-01-17

    申请号：US09899900

    申请日：2001-07-06

    Inventor： Stephen Raymond Schmidt

    IPC: B01J023/70 ,  C07C005/02 ,  C07C209/00

    CPC classification number: B01J25/00 ,  B01J25/02 ,  Y10T428/12042 ,  Y10T428/1209 ,  Y10T428/12181

    Abstract: A novel precious metal doped porous metal catalyst is disclosed. The precious metal is present in from 0.01 to 1.5 weight percent and distributed throughout the particles of porous metal to provide a surface to bulk ratio distribution of not greater than 60. The present invention is further directed to a process of forming said doped catalyst and to improved processes of catalytic hydrogenation of organic compounds.

    Abstract translation: 公开了一种新型的贵金属掺杂多孔金属催化剂。 贵金属以0.01至1.5重量％存在，并分布在整个多孔金属颗粒上，以提供不大于60的表面与体积比分布。本发明还涉及形成所述掺杂催化剂的方法， 有机化合物催化氢化的改进方法。

    Catalysts for oxidative steam reforming of methanol as a new and efficient method for the selective production of hydrogen for fuel cells and their synthesis method
    4.
    发明申请
    Catalysts for oxidative steam reforming of methanol as a new and efficient method for the selective production of hydrogen for fuel cells and their synthesis method 审中-公开
    用于甲醇氧化蒸汽重整的催化剂作为燃料电池选择性生产氢气的新型和有效方法及其合成方法

    公开(公告)号：US20020051747A1

    公开(公告)日：2002-05-02

    申请号：US09729103

    申请日：2000-12-05

    Applicant: Japan as represented by Secretary of Agency of Industrial Science and Techonlogy

    Inventor： Kenzi Suzuki ,  Velu Subramani ,  Toshihiko Osaki

    IPC: C01B003/16 ,  B01J023/02 ,  B01J023/70 ,  C01B003/12

    CPC classification number: B01J37/03 ,  B01J23/80 ,  B01J23/83 ,  C01B3/326 ,  C01B2203/1052 ,  C01B2203/1076 ,  Y02P20/52

    Abstract: The present invention provides a method of producing a CuZnAlZr oxide catalyst consisting of reacting an aqueous NaOH solution and aqueous NACO3 solution with a mixture of aqueous solutions of each nitrate of Cu, Zn, Al, and Zr, producing a precipitate by coprecipitation, aging, filtering, washing and drying this precipitate to prepare a catalyst precursor consisting of a CuZnAlZr layered double hydroxide, and then obtaining a CuZnAlZr oxide by calcining this precursor in an air ambient atmosphere, a CuZnAlZr oxide catalyst, a CuZnZrCe oxide catalyst, a CoCuZnAl oxide catalyst for producing hydrogen by oxidative steam reforming of methanol, and methods of producing hydrogen gas consisting of converting methanol to hydrogen gas by oxidative steam reforming in the presence of air and steam using these oxide catalysts.

    Abstract translation: 本发明提供一种CuZnAlZr氧化物催化剂的制造方法，该催化剂由NaOH水溶液和NACO3水溶液与Cu，Zn，Al和Zr的每种硝酸盐的水溶液的混合物反应，通过共沉淀，老化， 过滤，洗涤和干燥该沉淀物以制备由CuZnAlZr层状双氢氧化物组成的催化剂前体，然后通过在空气环境气氛中煅烧该前体获得CuZnAlZr氧化物，CuZnAlZr氧化物催化剂，CuZnZrCe氧化物催化剂，CoCuZnAl氧化物催化剂 用于通过甲醇的氧化蒸汽重整产生氢气，以及通过使用这些氧化物催化剂在空气和蒸汽的存在下通过氧化蒸汽重整将甲醇转化为氢气而制备氢气的方法。

    Selective carbon monoxide oxidation catalyst, method of making the same and systems using the same
    5.
    发明申请
    Selective carbon monoxide oxidation catalyst, method of making the same and systems using the same 失效
    选择性一氧化碳氧化催化剂，制备方法及使用方法

    公开(公告)号：US20030162656A1

    公开(公告)日：2003-08-28

    申请号：US10084281

    申请日：2002-02-25

    Inventor： Ming-Cheng Wu ,  Jeffrey G. Weissman

    IPC: B01J023/00 ,  B01J023/70 ,  B01J023/72

    CPC classification number: C01B3/583 ,  B01J23/56 ,  B01J23/628 ,  B01J37/0248 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  H01M8/0668 ,  Y02P70/56

    Abstract: A CO-selective catalyst comprises a catalytic material, wherein the catalytic material is selected from the group consisting of Pt, Pd, Rh, Ir, Os, Ru, Ta, Zr, Y, Ce, Ni, Cu, and oxides, alloys, compounds, and combinations comprising at least one of the foregoing; a modifying agent selected from the group consisting of Pb, Bi, Ge, Si, Sb, As, P, and combinations comprising at least one of the foregoing; and a support. In one embodiment, the method for forming the CO selective catalyst comprises combining a catalytic material and a support with about 2 to about 25 atomic percent of a modifying agent, based on the total surface atoms of the catalytic material, to form a modified catalyst-containing support and disposing the modified catalyst-containing support on or into a substrate.

    Abstract translation: CO选择性催化剂包括催化材料，其中催化材料选自Pt，Pd，Rh，Ir，Os，Ru，Ta，Zr，Y，Ce，Ni，Cu和氧化物，合金， 化合物和包含至少一种前述物质的组合; 选自Pb，Bi，Ge，Si，Sb，As，P的改性剂和包含至少一种上述物质的组合; 和支持。 在一个实施方案中，形成CO选择性催化剂的方法包括基于催化材料的总表面原子将催化材料和载体与约2至约25原子％的改性剂组合，以形成改性的催化剂 - 含有载体并将改性的含催化剂的载体置于基材上或其中。

    Structured catalysts for selective reduction of nitrogen oxides by ammonia using a compound that can be hydrolyzed to ammonia
    6.
    发明申请
    Structured catalysts for selective reduction of nitrogen oxides by ammonia using a compound that can be hydrolyzed to ammonia 有权
    使用可以水解成氨的化合物用氨选择性还原氮氧化物的结构化催化剂

    公开(公告)号：US20020025905A1

    公开(公告)日：2002-02-28

    申请号：US09851417

    申请日：2001-05-09

    Inventor： Michael Harris ,  Jurgen Leyrer ,  Yvonne Demel ,  Egbert Lox ,  Thomas Kreuzer

    IPC: B01J023/70 ,  B01J027/00

    CPC classification number: F01N3/2066 ,  B01D53/9431 ,  B01J21/063 ,  B01J21/066 ,  B01J23/20 ,  B01J23/30 ,  F01N3/2803 ,  F01N2240/40 ,  F01N2510/06 ,  F01N2610/02 ,  Y02A50/2325 ,  Y02T10/24

    Abstract: A structured catalyst for selective reduction of nitrogen oxides with ammonia using an ammonia-supplying compound. The catalyst is preferably used for exhaust gas treatment of diesel vehicles powered by diesel motors. The catalyst is characterized by the fact that it contains a reduction catalyst for selective reduction of nitrogen oxides with ammonia and a hydrolysis catalyst for the hydrolysis of urea, where the hydrolysis catalyst is applied in the form of a coating onto the reduction catalyst. By this arrangement of the two catalytic functions in one catalyst the exhaust gas system can be made very compactly and space saving. Moreover, advantageous synergistic effects result from the direct contact of the hydrolysis catalyst and the reduction catalyst.

    Abstract translation: 使用氨供应化合物用氨选择性还原氮氧化物的结构化催化剂。 该催化剂优选用于由柴油发动机驱动的柴油车辆的废气处理。 催化剂的特征在于它含有用氨选择性还原氮氧化物的还原催化剂和用于水解尿素的水解催化剂，其中水解催化剂以涂层的形式施加到还原催化剂上。 通过在一个催化剂中这两种催化功能的排列，可以使废气系统非常紧凑和节省空间。 此外，由于水解催化剂和还原催化剂的直接接触，有利的协同效应。

    Method for producing aldehydes
    8.
    发明申请
    Method for producing aldehydes 失效
    醛的生产方法

    公开(公告)号：US20040002620A1

    公开(公告)日：2004-01-01

    申请号：US10311838

    申请日：2003-07-11

    Inventor： Albrecht Schwerin ,  Gerrit Pelzer ,  Lothar Friesenhagen ,  Bernhard Gutsche

    IPC: C07C045/29 ,  B01J023/70 ,  B01J023/72

    CPC classification number: C07C45/002

    Abstract: A process for making aldehydes involving: (a) providing a fatty alcohol; (b) providing an oxidic copper/zinc catalyst; and (c) continuously dehydrogenating the fatty alcohol, in the presence of the oxidic copper/zinc catalyst, at a temperature of from about 200 to 280null C. and a pressure of from about 10 mbar to 1 bar.

    Abstract translation: 制备醛的方法，涉及：（a）提供脂肪醇; （b）提供氧化铜/锌催化剂; 和（c）在氧化铜/锌催化剂的存在下，在约200至280℃的温度和约10毫巴至1巴的压力下使脂肪醇连续脱氢。

    Desulfurization process and novel bimetallic sorbent systems for same
    9.
    发明申请
    Desulfurization process and novel bimetallic sorbent systems for same 有权
    脱硫工艺和新型双金属吸附剂体系相同

    公开(公告)号：US20030166465A1

    公开(公告)日：2003-09-04

    申请号：US10347915

    申请日：2003-01-21

    Inventor： Gyanesh P. Khare

    IPC: B01J023/00 ,  B01J023/72 ,  B01J023/74 ,  B01J023/70 ,  B01J023/06 ,  B01J023/48 ,  B01J023/50 ,  B01J020/02 ,  B01J020/10 ,  B01J020/06

    CPC classification number: C10G25/003 ,  Y10S502/517

    Abstract: Novel sorbent systems for the desulfurization of cracked-gasoline and diesel fuels are provided which are comprised of a bimetallic promotor on a particulate support such as that formed of zinc oxide and an inorganic or organic carrier. Such bimetallic promotors are formed of at least two metals of the group consisting of nickel, cobalt, iron, manganese, copper, zinc, molybdenum, tungsten, silver, tin, antimony and vanadium with the valence of same being reduced, preferably to zero. Processes for the production of such sorbents are provided wherein the sorbent is prepared from impregnated particulate supports or admixed to the support composite prior to particulation, drying, and calcination. Further disclosed is the use of such novel sorbents in the desulfurization of cracked-gasoline and diesel fuels whereby there is achieved not only removal of sulfur but also an increase in the olefin retention in the desulfurized product. Such sorbents can also be utilized for the treatment of other sulfur-containing streams such as diesel fuels.

    Abstract translation: 提供用于裂化汽油和柴油燃料脱硫的新型吸附剂系统，其由诸如由氧化锌和无机或有机载体形成的颗粒载体上的双金属促进剂组成。 这样的双金属促进剂由镍，钴，铁，锰，铜，锌，钼，钨，银，锡，锑和钒中的至少两种金属形成，其价态被还原，优选为零。 提供了用于生产这种吸附剂的方法，其中吸附剂由浸渍的颗粒载体制备，或在颗粒化，干燥和煅烧之前与载体复合材料混合。 进一步公开的是使用这种新型吸附剂在裂化汽油和柴油燃料的脱硫中，由此不仅实现硫的去除，而且脱硫产物中的烯烃保留量也增加。 这种吸附剂也可用于处理其它含硫物流如柴油燃料。

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