摘要:
Trivalent chromium, zinc, hexavalent chromate and molybdate can be removed from a fluid by contacting the fluid with an ion exchange resin bed comprising a mixture of a weak base anion exchange resin and a weak or strong acid cation exchange resin in hydrogen form to remove the metal values.
摘要:
The invention relates to a method for preparation of hydrophilic cation exchangers by a chemical modification of crosslinked copolymeric gels containing reactive hydroxyl groups and based on hydroxyalkyl, oligoglycol or polyglycol acrylates and methacrylates and hydroxyalkylacrylamides or hydroxyalkylmethacrylamides. The modification is carried out in reactions of hydroxyl groups with halogenalkane acids and their derivatives, anhydrides and halides of dicarboxylic acids or carbodiimides. If the modification agent contains several reactive groups, the remaining functional groups after modification may be allowed to react with dicarboxylic, polycarboxylic, hydroxycarboxylic or aminocarboxylic acids, or phosphoric or sulfuric acid, halogenoepoxides, diepoxides or polyepoxides. The hydroxyl groups can be also modified by oxidation to carboxylic groups by common oxidants. The gels used for modification may also contain alkoxide reactive groups and they have generally the homogeneous, semiheterogeneous or macroporous character. The ion-exchanging gels prepared in this way are suitable for sorption and chromatographic separations, especially for separation of sensitive biological materials.
摘要:
Aqueous liquids resulting from the condensation of vapours emitted by aqueous vegetable extracts are purified by treatment with an ion exchange resin. The purified condensates may be used for the extraction of the vegetable material.
摘要:
Metal ions, for example, heavy metal ions, alkaline earth metal ions and aluminium ions are eliminated by bringing a liquid containing the metal ions into contact with a special chelate resin in which chelating carboxylic anion groups are associated with basic amino acid cations, for example, lysine, ornithine, histidine, arginine, .alpha.,.beta.-diaminopropionic acid, .alpha.,.gamma.-diaminobutyric acid, L-citrulline and .delta.-oxylysine.
摘要:
A method and system combining filtration and ion-exchange structures for removing contaminants from liquids. In overall concept, contaminated liquid is passed through filtering mediums to remove particulate matter from the incoming contaminated liquid. Organics are removed from the liquid by passage through adsorbent non-ionic type resins. The liquid is then passed through strong acid cation exchange resins, weak base anion exchange resins, weak acid cation exchange resins, and strong base anion exchange resins arranged in a predetermined location in the liquid flow path to provide optimized contaminant removal. One of the optimization techniques is through the pH adjustment of the liquid at predetermined points in the flow path. Additionally, the liquid to be purified is passed through mixed bed polisher resins as well as chelation resins to provide a final substantially contaminant free liquid which is returned to use in a closed loop fashion.
摘要:
A METHOD AND SYSTEM FOR TREATING MIXED RINSE WATERS USED TO RINSE WORKPIECES REMOVED FROM CHROMIUM AND OTHER METAL TREATING BATHS PROVIDES FOR REDUCING HEXAVALENT CHROMIUM IONS CARRIED BY THE WORKPIECES PRIOR TO RINSING AND MIXING THE RINSE WATERS FROM A PLURALITY OF DIFFERENT RINSES PRIOR TO PASSAGE THEREOF THROUGH CATION
AND ANION EXCHANGERS. THE METHOD AND SYSTEM ALSO PROVIDE FOR THE IMMEDIATE REMOVAL OF CN FROM THE ANION REGENERANT WHILE IT HAS A HIGH PH VALUE AND THEN COMBINING THE CATION AND ANION REGENERANTS PRIOR TO NETRALIZATION.
摘要:
A new polyvinyl(dialkylthiocarbamoylthio)acetate resin expressed by the formula ##STR1## (wherein R.sub.1 and R.sub.2 each represent hydrogen atom or an alkyl group of C.sub.1 -C.sub.5) is provided.Said resin has a superior heavy metals-removing performance and is insoluble in organic solvents and hence very useful as an agent for removing heavy metals.Said resin is prepared by reacting a tetraalkylthiuramdisulfide expressed by a formula ##STR2## (wherein R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each represent hydrogen atom or an alkyl group of C.sub.1 -C.sub.5) with a vinyl acetate polymer on heating in a solvent.Said resin is used as an agent for removing heavy metals, alone or in admixture with an auxiliary agent such as active carbon.
摘要:
A process for the liquid phase oxidation of an organic substance-containing effluent which comprises subjecting said effluent to a liquid phase oxidation treatment in the presence of a copper catalyst at a copper ion concentration of 50-5000 ppm and also in presence of an ammonium ion concentration of five or more times the copper ion concentration thereby to oxidize the organic substances in the effluent, and recovering the copper catalyst from the treated effluent for reuse. The recovery of the copper catalyst may be effected either by a process in which the copper catalyst is separated as a precipitate or by a process using a resin adsorption.