Method for purifying waste saline waters without reagent waste
    4.
    发明申请
    Method for purifying waste saline waters without reagent waste 审中-公开
    无需试剂废物净化废盐水的方法

    公开(公告)号:US20100147767A1

    公开(公告)日:2010-06-17

    申请号:US12316725

    申请日:2008-12-15

    Inventor: Gerald J. Grott

    Abstract: Waste saline waters are purified by contacting with a cation exchange resin in hydrogen form, then with a WBA resin and, if desired, with a SBA resin. The cation exchange resin is regenerated with a strong acid reagent. The WBA resin is regenerated with ammonium hydroxide reagent. The SBA resin is regenerated with an alkali metal hydroxide. The residual reagent values in the spent regenerants are applied to the soil as amendments, fertilizer, for pH control, wind erosion control, deicing roadways and in Enhanced Oil Recovery.

    Abstract translation: 废盐水通过与氢形式的阳离子交换树脂接触,然后与WBA树脂和如果需要与SBA树脂接触来纯化。 阳离子交换树脂用强酸试剂再生。 WBA树脂用氢氧化铵试剂再生。 SBA树脂用碱金属氢氧化物再生。 废旧再生剂中的残留试剂值作为修改,肥料,pH控制,风蚀控制,除冰道路和增强采油应用于土壤。

    Selective fluoride and ammonia removal by chromatographic separation of wastewater
    6.
    发明申请
    Selective fluoride and ammonia removal by chromatographic separation of wastewater 审中-公开
    通过色谱分离废水选择性氟化物和氨

    公开(公告)号:US20060065602A1

    公开(公告)日:2006-03-30

    申请号:US11283080

    申请日:2005-11-18

    Abstract: A process for fluoride removal from wastewater streams produced during industrial operation for further industrial use or to comply with environmental regulations. The process segregates the removal of fluoride and fluorosilicate ions, from the totality of ions in the waste water stream, thus improving treatment efficiency and reducing costs. Ion-exchange chromatography is used to remove the fluoride and fluorosilicate ions by passing the wastewater stream through one or more columns that contain a charged resin which selectively binds cations/anions in the stream. The fluoride ions are washed from the column and then collected for removal or use in other processes.

    Abstract translation: 用于在工业运行期间产生的用于进一步工业用途或符合环境规定的废水流中氟化物除去的过程。 该方法从氟化物和氟硅酸盐离子的去除中排除了废水流中离子的总量,从而提高了处理效率并降低了成本。 离子交换色谱用于通过使废水流通过一个或多个含有带电树脂的柱,以选择性地结合物流中的阳离子/阴离子来除去氟化物和氟硅酸盐离子。 氟化物离子从柱中洗涤,然后收集用于除去或用于其它方法。

    Selective fluoride and ammonia removal by chromatographic separation of wastewater
    7.
    发明申请
    Selective fluoride and ammonia removal by chromatographic separation of wastewater 失效
    通过色谱分离废水选择性氟化物和氨

    公开(公告)号:US20050145572A1

    公开(公告)日:2005-07-07

    申请号:US10749954

    申请日:2003-12-31

    Abstract: A process for fluoride removal from wastewater streams produced during industrial operation for further industrial use or to comply with environmental regulations. The process segregates the removal of fluoride and fluorosilicate ions, from the totality of ions in the waste water stream, thus improving treatment efficiency and reducing costs. Ion-exchange chromatography is used to remove the fluoride and fluorosilicate ions by passing the wastewater stream through one or more columns that contain a charged resin which selectively binds cations/anions in the stream. The fluoride ions are washed from the column and then collected for removal or use in other processes.

    Abstract translation: 用于在工业运行期间产生的用于进一步工业用途或符合环境规定的废水流中氟化物除去的过程。 该方法从氟化物和氟硅酸盐离子的去除中排除了废水流中离子的总量,从而提高了处理效率并降低了成本。 离子交换色谱用于通过使废水流通过一个或多个含有带电树脂的柱,以选择性地结合物流中的阳离子/阴离子来除去氟化物和氟硅酸盐离子。 氟化物离子从柱中洗涤,然后收集用于除去或用于其它方法。

    Method for demineralizing condensate
    10.
    发明授权
    Method for demineralizing condensate 有权
    冷凝水脱矿方法

    公开(公告)号:US08007672B2

    公开(公告)日:2011-08-30

    申请号:US11543921

    申请日:2006-10-06

    CPC classification number: B01J49/08 B01J39/05 B01J41/04

    Abstract: The present invention provides a multiple bed-type condensate demineralization method and apparatus for the method that are able to provide an improved treated water quality in ammonia operation by substantially reducing the cross contamination ratio during resin regeneration from the current cross contamination ratio.In the method of condensate demineralization using ion-exchange resin in a multiple-bed regime, condensate is passed through a resin layer having a multiple-bed structure in which an anion resin layer and a layer of a uniform particle size strong acid gel-type cation resin with a 10% to 16% degree of crosslinking, divided by a partition in such a manner that they do not mix with each other, are combined in alternation. The uniform particle size strong acid gel-type cation resin with a 10% to 16% degree of crosslinking is an ion-exchange resin that has a uniform particle size of 500 to 800 μm for which at least 95% of the resin particles fall in the range defined by the average particle size ±100 μm and the uniformity coefficient is less than or equal to 1.2. Ion-exchange resin that has come to require chemical regeneration is separately withdrawn and subjected to chemical regeneration by type and is returned into the originating partition.

    Abstract translation: 本发明提供一种多床型冷凝物脱矿质化方法及其装置,其能够通过从目前的交叉污染率显着降低树脂再生期间的交叉污染率,从而能够在氨操作中提供改善的处理水质。 在多床方式中使用离子交换树脂的冷凝物脱矿质的方法中,冷凝物通过具有多层结构的树脂层,其中阴离子树脂层和均匀粒度的强酸凝胶型层 将交联度为10%至16%的阳离子树脂以不相互混合的方式除以隔板,交替组合。 具有10〜16%交联度的均匀粒径的强酸性凝胶型阳离子树脂是具有500〜800μm的均匀粒径的离子交换树脂,至少95%的树脂粒子落入 由平均粒径±100μm定义的范围和均匀度系数小于或等于1.2。 已经需要化学再生的离子交换树脂被单独取出并经过类型的化学再生并返回到起始分隔件中。

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