Manufacturing method for cellulose ether having high degree of
substitution
    2.
    发明授权
    Manufacturing method for cellulose ether having high degree of substitution 失效
    具有高取代度的纤维素醚的制造方法

    公开(公告)号:US4582899A

    公开(公告)日:1986-04-15

    申请号:US720927

    申请日:1985-04-08

    申请人: Hiroyuki Nakamura

    发明人: Hiroyuki Nakamura

    摘要: A manufacturing method for cellulose ether having a high degree of substitution characterized in that an etherifying agent represented by a general formula RCH.sub.2 X (where R is aromatic group, heterocyclic group, vinyl group or ethynyl group or the same group substituted and X is chlorine or bromine) is reacted with a uniform solution of cellulose acetate having a degree of substitution of 2.0 and over in an organic solvent in the presence of a base to manufacture a highly substituted cellulose ether having a degree of substitution of 2.0 and over per anhydrous glucose unit by a one stage reaction at a good yield.As a general method for manufacturing cellulose ether, a method for reacting an etherifying agent with alkali cellulose is now in use. For the general method, several improved methods have been proposed. However, it is difficult to manufacture cellulose ether having a degree of substitution of 2.5 and over by a one stage reaction using the general method. As manufacturing methods for cellulose ether other than the general method, a method for using a solvent-soluble cellulose derivative as the raw material and a method for using a special solvent in which cellulose is soluble were proposed. However, the former had a defect of a low yield and the latter had a defect of too long a reaction time.

    摘要翻译: 具有高取代度的纤维素醚的制造方法,其特征在于,由通式RCH2X(其中R是芳族基,杂环基,乙烯基或乙炔基或与之相同基团取代的醚化剂)和X是氯或溴 )与有机溶剂中的取代基为2.0以上的醋酸纤维素的均匀溶液在碱的存在下反应,以通过以下方式制备高度取代的取代度为2.0的纤维素醚 一个阶段的反应以良好的收益率。 作为制造纤维素醚的一般方法,现在使用醚化剂与碱纤维素反应的方法。 对于一般方法,已经提出了几种改进的方法。 然而,通过一般方法,难以通过一步反应制造取代度为2.5以上的纤维素醚。 作为除一般方法以外的纤维素醚的制造方法,提出了使用溶剂可溶性纤维素衍生物作为原料的方法和使用其中可溶解纤维素的特殊溶剂的方法。 然而,前者具有低产量的缺点,后者具有反应时间太长的缺点。

    ADHESIVE COMPOSITIONS COMPRISING TYPE-II CELLULOSE

    公开(公告)号:US20170275384A1

    公开(公告)日:2017-09-28

    申请号:US15511195

    申请日:2015-09-25

    申请人: RENMATIX, INC.

    摘要: Admixtures comprising an adhesive resin and cellulose are disclosed, in which at least a portion of the cellulose is type-II cellulose. Also disclosed are compositions comprising adhesive resins, in which the adhesive resins comprise a condensation product of formaldehyde and at least one phenolic compound, and the condensation product is formed in the presence of cellulose, wherein at least a portion of the cellulose is type-II cellulose. Articles of manufacture containing the admixtures and compositions, such as plywood and oriented strand board, are also disclosed. In addition, methods of preparing the compositions and articles of manufacture are disclosed.

    Hydrolytically stable, hydrophilic adhesion-promoting monomers and polymers made therefrom
    6.
    发明授权
    Hydrolytically stable, hydrophilic adhesion-promoting monomers and polymers made therefrom 有权
    水解稳定的亲水性粘合促进单体和由其制成的聚合物

    公开(公告)号:US09150666B2

    公开(公告)日:2015-10-06

    申请号:US12360421

    申请日:2009-01-27

    申请人: Rafael L. Bowen

    发明人: Rafael L. Bowen

    摘要: Disclosed are compositions that comprise vinylarylalkylene ethers of cyclodextrins optionally containing ether-linked adhesion-promoting groups, in combination with copolymerizable monomer or monomers. The copolymerizable monomer or monomers may include vinylarylalkylene ethers of oligohydroxy compounds (for example, sorbitol divinylbenzyl ether and others). The composition further may include stabilizers (for example, 1,3,5-trimethyl-2,4,6-tris(3,5-di-(tert)-butyl-4-hydroxybenzyl)benzene and others), and polymerization initiators (for example, phenylbis[2,4,6-trimethylbenzoyl]phosphine oxide and others) and reinforcing materials (for example, imogolite). Methods of preparing the compositions as well as the components of compositions and methods for their use in dental and other applications are also disclosed.

    摘要翻译: 公开了包含任选含有醚连接的粘附促进基团的环糊精的乙烯基芳基亚烷基醚与可共聚单体或单体组合的组合物。 可共聚的单体或单体可以包括低聚羟基化合物的乙烯基芳基亚烷基醚(例如,山梨醇二乙烯基苄基醚等)。 组合物还可以包括稳定剂(例如1,3,5-三甲基-2,4,6-三(3,5-二(叔)丁基-4-羟基苄基)苯等)和聚合引发剂 (例如苯基双[2,4,6-三甲基苯甲酰基]氧化膦等)和增强材料(例如,imogolite)。 还公开了制备组合物的方法以及其用于牙齿和其它应用的组合物和方法的组分。

    gebmany
    7.
    发明授权
    gebmany 失效

    公开(公告)号:US1682382A

    公开(公告)日:1928-08-28

    申请号:US1682382D

    IPC分类号: C08B11/18

    CPC分类号: C08B11/18

    Dialysis membrane made of polysaccharide ether
    10.
    发明授权
    Dialysis membrane made of polysaccharide ether 失效
    多糖醚的DIALYSIS膜

    公开(公告)号:US5171444A

    公开(公告)日:1992-12-15

    申请号:US708788

    申请日:1991-05-31

    摘要: Dialysis membrane for hemodialysis in the form of membrane films, tubular films, or hollow filaments made of polysaccharide ethers, are characterized by the fact that the polysaccharide ether has a structure shown by the formula ##STR1## in which Cell is the skeleton of the unmodified cellulose molecule or of the chitin molecule, without hydroxyl groups in each case, s is 3 in the unmodified cellulose molecule and 2 in the chitin molecule, and x corresponds to the degree of etherification, which is in the range from 0.08 to (s-0.4).

    摘要翻译: 用于由多糖醚制成的膜膜,管状膜或中空细丝形式的血液透析用透析膜的特征在于,多糖醚具有由式(IMAGE)所示的结构,其中Cell是未修饰的骨架 纤维素分子或几丁质分子,在每种情况下不含羟基,s在未修饰的纤维素分子中为3,在几丁质分子中为2,并且x对应于醚化度,其在0.08至(s- 0.4)。